ABSTRACT
Biological macromolecules are proven to be potential green corrosion inhibitors because of their outstanding structural features and eco-friendliness. This study is aimed at enhancing their corrosion mitigation capabilities by converting them into nanoparticles. This is the first work where nanoparticles of biological macromolecules are exploited for corrosion mitigation studies. Glycogen nanoparticles (GLY-Np) were synthesized by microwave-mediated nanoprecipitation method and characterized by ATR-FTIR, XRD, UV-Visible Spectroscopy, FESEM analysis, EDX, TEM, and Zeta potential measurements. They are used as an eco-friendly inhibitor for corrosion control of zinc in sulfamic acid (NH2SO3H). The electrochemical study was a primary experimental tool employed for corrosion rate measurement. Conditions were optimized to obtain maximum inhibition efficiency by varying concentrations of inhibitor and temperature. Activation and thermodynamic parameters were evaluated and discussed in detail. A suitable adsorption isotherm was proposed to fit the experimental results. Adsorption of the inhibitor was confirmed by SEM, EDX, and AFM techniques. The inhibition efficiency of 92% was obtained for 0.02 gL-1 GLY-Np. Thus, GLY-Np turned out to be an effective green inhibition with economic benefits.
Subject(s)
Glycogen/chemistry , Nanoparticles/chemistry , Adsorption , Corrosion , Dielectric Spectroscopy , Electrochemistry , Kinetics , Molecular Weight , Nanoparticles/ultrastructure , Spectrometry, X-Ray Emission , Spectrophotometry, Ultraviolet , Spectroscopy, Fourier Transform Infrared , Static Electricity , Surface Properties , Temperature , X-Ray Diffraction , Zinc/chemistryABSTRACT
Maltodextrin (MLD), a biopolymer was introduced as a novel green inhibitor to mitigate the corrosion of zinc in sulfamic acid medium by weight loss and by electrochemical methods. Conditions were optimized to obtain maximum inhibition efficiency. Thermodynamic parameters were evaluated. The surface morphology was studied by SEM, EDX, AFM analysis. Adsorption of inhibitor was re-affirmed by FT-IR spectroscopy, Atomic absorption spectroscopy (AAS), Raman spectroscopy and powder X-ray diffraction (XRD) analysis. Maximum efficiency of 72% was observed for the addition of 400â¯ppm of MLD. Surface morphology and spectroscopic studies confirmed the adsorption of MLD onto the surface of zinc. Results obtained by classical and electrochemical methods are in good agreement with one another. Maltodextrin emerged as an effective eco -friendly green inhibitor.
