ABSTRACT
In the title compound, C38H28O6, the dihedral angles between the naphthalene ring system and its pendant benz-yloxy rings A and B are 88.05â (7) and 80.84â (7)°, respectively. The dihedral angles between the A and B rings and their attached phenyl rings are 49.15â (8) and 80.78â (8)°, respectively. In the extended structure, the mol-ecules are linked by weak C-Hâ¯O and C-Hâ¯π hydrogen bonds, and π-π stacking inter-actions, which variously generate C(11) chains and R 2 2(12) loops as part of a three-dimensional network. The Hirshfeld surface [fingerprint contributions = Hâ¯H (42.3%), Câ¯H/Hâ¯C (40.3%) and Oâ¯H/Hâ¯O (15.7%)] and inter-molecular inter-action energies are reported, with dispersion (E dis = -428.6â kJâ mol-1) being the major contributor.
ABSTRACT
The title compound, C35H22ClNO7, is a non-liquid crystal with a bent-shaped mol-ecule. The dihedral angles between adjacent aromatic rings in the mol-ecule (starting from the cyano-benzene ring) are 72.61â (2), 87.69â (4), 64.08â (2) and 88.23â (2)°, indicating that adjacent rings are close to perpendicular to each other. In the crystal, the mol-ecules are linked by weak C-Hâ¯N and C-Hâ¯π inter-actions, thereby forming a two-dimensional supra-molecular architecture in the ac plane. The most important contributions to the crystal packing arise from Hâ¯H (59.3%), Sâ¯H (27.4%) and Oâ¯H (7.5%) inter-actions, as determined by a Hirshfeld surface analysis.
ABSTRACT
In the title chiral mol-ecular salt, C4H12NO3S(+)·Cl(-), the cation is protonated at the N atom, producing [RNH3](+), where R is CH3SO2OCH2C(H)CH3. The N atom in the cation is sp (3)-hybridized. In the crystal, cations and anions are connected by strong N-Hâ¯Cl hydrogen bonds to generate edge-shared 12-membered rings of the form {â¯Clâ¯HNH}3. This pattern of hydrogen bonding gives rise to zigzag supra-molecular layers in the ab plane. The layers are connected into a three-dimensional architecture by C-Hâ¯O hydrogen bonds. The structure was refined as an inversion twin.
ABSTRACT
In the title compound, C16H17NO2S, the heterocyclic ring adopts a half-chair conformation and the bond-angle sum at the N atom is 354.6°. The dihedral angle between the planes of the aromatic rings is 74.15â (10)°. In the crystal, mol-ecules are linked by weak C-Hâ¯O hydrogen bonds, generating C(8) and C(4) chains propagating along [100] and [010], respectively, which together generate (001) sheets.
ABSTRACT
In the title mol-ecular salt, C10H15ClNS(+)·Cl(-), the cation is [R'R"NH2](+), where R' is 2-MeS-C6H4CH2- and R" is -CH2CH2Cl, and the anion is Cl(-). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra-hedral geometry. In the crystal, the anions are connected to the cations through two pairs of N-Hâ¯Cl hydrogen bonds, generating a four-centred inversion dimer with an R 4 (2)(8) ring motif.
ABSTRACT
The tetra-hydro-pyridine ring of the quinoline system in the title compound, C14H13ClN2O2S, adopts a half-chair conformation with the bond-angle sum at the N atom being 350.0°. The dihedral angle between the least-squares planes of the two aromatic rings is 50.13â (11)°. In the crystal, inversion dimers linked by pairs of C-Hâ¯O hydrogen bonds generate R 2 (2)(10) loops. Additional inter-molecular C-Hâ¯O hydrogen bonds generate C(7) chains along [100].
ABSTRACT
In the title compound, C17H12O5, the dihedral angle between the planes of the coumarin ring system (r.m.s. deviation = 0.015â Å) and the benzene ring is 48.04â (10)°. The central CO2 group subtends a dihedral angle of 27.15â (11)° with the coumarin ring system and 74.86â (13)° with the benzene ring. In the crystal, mol-ecules are linked by C-Hâ¯O inter-actions, which generate a three-dimensional network. Very weak C-Hâ¯π inter-actions are also observed.
ABSTRACT
In the title compound, C16H9BrO4, the coumarin ring system is approximately planar, with an r.m.s deviation of the ten fitted non-H atoms of 0.031â Å, and forms a dihedral angle of 25.85â (10)° with the bromo-benzene ring. The carbonyl atoms are syn. In the crystal, mol-ecules are connected along [001] via C-Hâ¯O inter-actions, forming C(6) chains. Neighbouring C(6) chains are connected via several π-π inter-actions [range of centroid-centroid distances = 3.7254â (15)-3.7716â (16)â Å], leading to sheets propagating in the bc plane.
ABSTRACT
The complete mol-ecule of the title compound, C17H16O6, is generated by crystallographic twofold symmetry, with the central methyl-ene C atom lying on the rotation axis. The carbonyl O atom is disordered over two adjacent positions in a 0.63â (3):0.37â (3) ratio and the dihedral angle between the benzene rings in the two halves of the mol-ecule is 79.31â (12)°. In the crystal, mol-ecules are connected by C-Hâ¯O hydrogen bonds, generating (110) sheets. Very weak intra-sheet C-Hâ¯π inter-actions are also observed.
ABSTRACT
In the title compound, C10H13NO2S, the heterocyclic ring adopts a half-chair conformation and the bond-angle sum at the N atom is 347.9°. In the crystal, inversion dimers linked by pairs of C-Hâ¯O hydrogen bonds generate R 2 (2)(8) loops.
ABSTRACT
In the title compound, C16H17NO2S, the heterocyclic ring adopts a half-chair conformation and the bond-angle sum at the N atom is 350.2°. The dihedral angle between the planes of the aromatic rings is 47.74â (10)°. In the crystal, mol-ecules are linked by C-Hâ¯O hydrogen bonds to generate [010] chains.
ABSTRACT
In the title compound, C18H18N2O4S, the dihedral angle between the aromatic rings is 33.71â (9)° and an intra-molecular C-Hâ¯O hydrogen bond closes an S(6) ring. In the crystal, mol-ecules are linked by C-Hâ¯O and C-Hâ¯N hydrogen bonds to generate a three-dimensional network. A very weak aromatic π-π stacking inter-ction is also observed [centroid-centroid separation = 3.9524â (10)â Å].
ABSTRACT
In the title compound, C15H15NO4S, the dihedral angle between the aromatic rings is 80.81â (1)° and the dihedral angle between the planes defined by the S-N-C=O fragment and the sulfonyl benzene ring is 86.34â (1)°. In the extended structure, dimers related by a crystallographic twofold axis are connected by pairs of both N-Hâ¯O hydrogen bonds and C-Hâ¯O inter-actions, which generate R 2 (2)(8) and R 2 (2)(14) loops, respectively. A weak aromatic π-π stacking inter-action is also observed [centroid-centroid separation = 3.7305â (3)â Å].
ABSTRACT
In the title compound, C14H12ClNO4S, the dihedral angle between the aromatic rings is 82.07â (1)° and the dihedral angle between the planes defined by the S-N-C=O fragment and the sulfonyl benzene ring is 82.46â (3)°. In the crystal, the mol-ecules are linked into C(4) chains running along [001] by strong N-Hâ¯O hydrogen bonds. A C-Hâ¯O intera-ction reinforces the [001] chains: its graph-set symbol is C(7). The chains are cross-linked into (100) sheets by further C-Hâ¯O inter-actions as C(6) chains along [001]. The structure also features weak π-π stacking inter-actions [centroid-centroid distances = 3.577â (1) and 3.8016â (1)â Å].
ABSTRACT
In the title compound, C14H21NO, the conformation across the N-C(O) bond is syn-periplanar, the C-N-C-C torsion being -5.9â (5)°. The atoms of the ethyl group attached to the N atom are disordered over two sets of sites with occupancy ratios of 0.65â (2):0.35â (2) (CH2) and 0.689â (14):0.311â (14) (CH3)are linked by very weak C-Hâ¯O inter-actions forming C(8) chains along [001]. C-Hâ¯π inter-actions link the mol-ecules along the c-axis direction.
ABSTRACT
In the title compound, C16H11FN4S, the dihedral angles between the triazole ring and the phenyl and fluoro-benzene rings are 23.22â (17) and 18.06â (17)°, respectively. The six-membered heterocyclic ring adopts a distorted envelope conformation, with the methyl-ene C atom as the flap. In the crystal, the mol-ecules are linked by two C-Hâ¯N and C-Hâ¯F inter-actions along [010], forming C(5), C(8) and C(13) chains repectively. C-Hâ¯π inter-actions involving the phenyl ring and π-π inter-actions [centroid-centroid separation for triazole rings = 3.5660â (18)â Å] are also observed.
ABSTRACT
In the title compound, C14H12ClNO4S, the dihedral angle between the chloro- and meth-oxy-substituted benzene rings is 87.40â (1)°. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-Hâ¯O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through two C-Hâ¯O inter-actions that form C(11) chains and R 2 (2)(14) loops. Aromatic π-π stacking inter-actions [centroid-centroid separation = 3.8574â (1)â Å] are also observed.
ABSTRACT
In the title compound, C15H15NO4S, the dihedral angle between the benzene rings is 88.87â (1)°. In the crystal, adjacent mol-ecules form inversion dimers through pairs of strong N-Hâ¯O hydrogen bonds, generating R 2 (2)(8) loops. Two C-Hâ¯π inter-actions and an aromatic π-π inter-action [centroid-centroid separation = 3.8191â (1)â Å] are also observed.
ABSTRACT
The title compound, C31H27F3O7, is a liquid crystal and exhibits enanti-otropic SmA and nematic phase transitions. In the crystal, the the 2H-chromene ring system makes dihedral angles of 54.46â (17) and 7.79â (16)°, respectively, with the central benzene ring and 4-(hept-yloxy)benzene ring. The three F atoms of the -CF3 group are disordered over two sets of sites, with an occupancy ratio of 0.62â (3):0.38â (3). The crystal structre features two pairs of C-Hâ¯O hydrogen bonds, which form inversion dimers and generate R 2 (2)(10) and R 2 (2)(30) ring patterns. C-Hâ¯O inter-actions along [100] and C-Hâ¯π inter-actions futher consolidate the packing, leading to a three-dimensional network.
ABSTRACT
In the title compound, C7H6F3NO2, all the non-H atoms except for one of the F atoms lie on a crystallographic mirror plane. In the crystal, the mol-ecules are linked into inversion dimers by pairs of C-Hâ¯F inter-actions, forming R 2 (2)(10) loops. These dimers are connected into C(6) chains along [001] through N-Hâ¯O hydrogen bonds. Aromatic π-π stacking inter-actions [centroid-centroid separation = 3.8416â (10) A°] connect the mol-ecules into a three-dimensional network.