ABSTRACT
BACKGROUND: The purpose of the data paper was to introduce into scientific literature the results of scientific work carried out for the third edition of the 'Red Data Book of the Komi Republic'. The article reflects methodological approaches to the formation of a list of rare and in need of protection species and describes the corresponding datasets published in GBIF. NEW INFORMATION: Information about 7,187 occurrences of 438 rare species and infraspecies included in the third edition of the 'Red Data Book of the Komi Republic' have been published.
ABSTRACT
Here we report a new approach to predisposal processing of spent resorcinol-formaldehyde resins (RFR) selective to cesium radionuclides via dissolution and hydrothermal oxidation (HTO) with the mineralization efficiency above 85%. Using a combination of potentiometric and colloid titration, we have shown that dissolution of RFR by consecutive treatment with nitric acid and sodium hydroxide solutions at optimal concentrations of 3-5 mol/L and 1 mol/L, respectively, yields colloid solutions of partially depolymerized and oxidized RFR. The efficiency of HTO of resorcinol and RFR solutions with hydrogen peroxide was investigated in a flow-type stainless steel reactor in the temperature range 165-250 °Ð¡ and at linear flow rates of 1-3 cm/min. It was demonstrated that HTO allowed efficient resorcinol mineralization using hydrogen peroxide at H2O2: resorcinol molar ratios above 10 at 195 °Ð¡ and a linear flow rate of 2 cm/min. Due to the colloidal nature of organics in RFR solution, its efficient decomposition occurred at higher temperature or molar excess of the oxidizer as compared to resorcinol, but in both cases HTO was the most efficient in acidic media yielding acetic acid as the main oxidation resistant product.
ABSTRACT
The feasibility of several approaches to the fabrication of monolith composite cryogels containing transition-metal ferrocyanides for Cs+ ion uptake has been evaluated. Although in the series of investigated metal ion precursors (Cu(II), Zn(II), Ni(II), and Co(II)), in situ formation of the sorption active phase in polyethyleneimine (PEI) cryogel was feasible only in the case of Zn(II) ferrocyanide, this approach has shown significant advantages over the immobilization of ex situ synthesized ferrocyanide nanoparticles. Nanoparticles of the mixed ferrocyanide Zn1.85K0.33[Fe(CN)6] formed in situ had an average size of 516 ± 146 nm and were homogeneously distributed in the monolith located at the polymer surface rather than embedded in the matrix. The Young modulus of the PEI cryogel increased after modification from 25 to 57 kPa, but composites maintained high permeability to the flow. Sorption of Cs+ ions has been investigated at superficial velocity up to 8 m/h. Steep breakthrough profiles and uptake efficiency of >99.5% until breakthrough point confirmed that a supermacroporous structure of the monolith composite assured good mass transfer, so that intraparticle diffusion was not the limiting stage of sorption kinetics. Application of the rate-constant distribution model (RCD model) to analyze the breakthrough curves of Cs+ sorption allowed the identification of two types of sorption sites with a difference in sorption rate constants of ~1 log unit. Most likely, sorption on "fast" sorption sites was governed by ion exchange between Cs+ ions in solution and K+ ions in the ferrocyanide lattice. Cs-137 radionuclide removal was investigated using the monolith composite columns of various geometries at superficial velocity up to the 6.6 m/h; specific gamma activity was reduced from 265 kBq/L to the background level, showing high potential of these materials for POU application.
ABSTRACT
Hydrothermal oxidation, a promising method for removal of cobalt radionuclides from EDTA-containing liquid radioactive waste streams, is in the focus of the present study. It has been demonstrated that Co(III)-EDTA complexes, which are very stable under normal conditions, undergo oxidation as a result of the electron transfer from the EDTA carboxyl group to Co(III) ions under elevated temperature. The electron transfer reaction follows the first-order rate law with an activation energy of 91.8 kJ/mol at ÑH 12 and time of Co(III) ions half-conversion of 0.2 s at 200 °C. The rate of EDTA oxidation is proportional to the concentration of Co(III) ions and solution pH. Based on quantum chemistry simulations, possible intermediate structures formed upon the electron transfer from EDTA to Co(III) ions have been suggested. It has been shown that the introduction of hydrogen peroxide provides a continuous generation of Co(III) ions and a sequential decarboxylation of the EDTA until complete degradation of the chelate structure. The pathways of cobalt immobilization have been clarified.
ABSTRACT
The origin of the emergence of radioactive contamination not removable in the process of acid-base regeneration of ion-exchange resins used in treatment of technological media and liquid radioactive waste streams has been determined. It has been shown that a majority of cesium radionuclides not removable by regeneration are bound to inorganic deposits on the surface and inside the ion-exchange resin beads. The nature of the above inorganic inclusions has been investigated by means of the methods of electron microscopy, IR spectrometry and X-ray diffraction. The method of decontamination of spent ion-exchange resins and zeolites contaminated with cesium radionuclides employing selective resorcinol-formaldehyde resins has been suggested. Good prospects of such an approach in deep decontamination of spent ion exchangers have been demonstrated.
