ABSTRACT
The use of reduced graphene oxide (RGO) and graphene nanoribbons (GNRs) as infrared photodetectors is explored, based on recent results dealing with solar cells, light-emitting devices, photodetectors, and ultrafast lasers. IR detection is demonstrated by both RGO and GNRs in terms of the time-resolved photocurrent and photoresponse. The responsivity of the detectors and their functioning are presented.
Subject(s)
Graphite/chemistry , Infrared Rays , Nanotubes, Carbon/chemistry , Oxides/chemistry , Dimethylformamide , Formamides/chemistry , Nanotechnology , Oxidation-ReductionABSTRACT
We report the effect of carboxyl functionalization of graphene in pacifying its strong hydrophobic interaction with cells and associated toxic effects. Pristine graphene was found to accumulate on the cell membrane causing high oxidative stress leading to apoptosis, whereas carboxyl functionalized hydrophilic graphene was internalized by the cells without causing any toxicity.
Subject(s)
Cell Survival/drug effects , Graphite/chemistry , Graphite/toxicity , Nanostructures/chemistry , Nanostructures/toxicity , Animals , Chlorocebus aethiops , Flow Cytometry , Hydrophobic and Hydrophilic Interactions , Materials Testing , Microscopy, Confocal , Oxidative Stress/drug effects , Toxicity Tests , Vero CellsABSTRACT
Temperature effects on the various features in the Raman spectra of several graphene samples and graphene nanoribbons have been investigated over the temperature range 77-573 K. The temperature coefficient of the G and 2D band frequencies are found to depend on the number of layers, the former decreasing with the increase in the number of layers. The number of layers also affects the temperature coefficients of the FWHMs of these bands. Doping of graphene affects these Raman features significantly. The defect-related bands D and D(') bands are not sensitive to the number of layers or doping. We can understand the observed temperature effects on the basis of electron-phonon coupling, thermal expansion and anharmonic phonon-phonon interactions.
ABSTRACT
Irradiation of undoped and doped multi-walled carbon nanotubes by an excimer laser (energy â¼200-350 mJ) yields graphene nanoribbons (GNRs). The GNRs so obtained have been characterized by transmission electron microscopy, atomic force microscopy and Raman spectroscopy.
Subject(s)
Graphite/radiation effects , Lasers , Nanotubes, Carbon/chemistry , Nanotubes, Carbon/ultrastructure , Materials Testing , Molecular Conformation , Nanotubes, Carbon/radiation effects , Particle Size , Radiation Dosage , Surface Properties/radiation effectsABSTRACT
ZnO nanoparticles exhibit a broad band centred around 530 nm in the photoluminescence (PL) spectrum due to the presence of oxygen vacancies. Composites of ZnO nanoparticles with graphenes show marked changes in the PL spectrum with broad bands covering the entire visible region, making them candidates for solid state lighting, while graphene prepared by arc discharge of graphite in a hydrogen atmosphere (HG) containing 2-3 layers as well as boron-doped (BHG) and nitrogen-doped (NHG) samples of HG give white light when admixed with ZnO nanoparticles; excellent results are obtained with the addition of just 7 wt% of BHG to the ZnO nanoparticles. Mixtures of ZnO and GaN nanoparticles also exhibit white light emission. The quantum yields of these ZnO nanoparticle based white light sources are in the 4-6% range. Photoconductivity characteristics of ZnO nanoparticles are affected by the addition of even a small amount of graphene (<0.5 wt%).
ABSTRACT
The occurrence of ferromagnetism in nanoparticles of otherwise non-magnetic oxides seems to be well established. It is, however, necessary to understand the origin of ferromagnetism in these materials. Herein, we present a combined study of the magnetic properties and photoluminescence (PL) behavior of nanoparticles of ZnO, ZrO(2), and MgO annealed at different temperatures (and therefore of different sizes). We find that the magnetization and the intensity of the bands due to defects vary parallel in all these materials. The adsorption of ethanol leads to a decrease in the magnetization and to a reduced intensity of the defect PL band of ZnO nanoparticles whereas UV irradiation has the opposite effect. We have also examined the effect of the morphology of the ZnO on the properties.
ABSTRACT
Double-walled carbon nanotubes (DWNTs) doped with nitrogen and boron have been prepared by the decomposition of a CH(4) + Ar mixture along with pyridine (or NH(3)) and diborane, respectively, over a Mo(0.1)Fe(0.9)Mg(13)O catalyst, prepared by the combustion route. The doped DWNTs bave been characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy, electron energy loss spectroscopy, and Raman spectroscopy. The dopant concentration is around 1 atom % for both boron and nitrogen. The radial breathing modes in the Raman spectra have been employed along with TEM to obtain the inner and outer diameters of the DWNTs. The diameter ranges for the undoped, N-doped (pyridine), N-doped (NH(3)), and B-doped DWNTs are 0.73-2.20, 0.74-2.30, 0.73-2.32, and 0.74-2.36 nm, respectively, the boron-doped DWNTs giving rise to a high proportion of the large diameter DWNTs. Besides affecting the G-band in the Raman spectra, N- and B-doping affect the proportion of semiconducting nanotubes.
