Sustainable synthesis of multifunctional nanomaterials from rice wastes: a comprehensive review.

More than 60% of India's population relies on agriculture as their primary source of income, making it the nation's most important economic sector. Rice husk (often abbreviated as RH) is one of the most typical by-products of agricultural production. Every five tonnes of rice that is harvested results in the production of one tonne of husk. The concept of recycling and reusing waste from agricultural production has received interest from a variety of environmental and industrial perspectives. A wide variety of nanomaterials, including nano-zeolite, nanocarbon, and nano-silica, have been discovered in agro-waste. From rice cultivation to the finished product, there was a by-product consisting of husk that comprised 20% of the overall weight, or RH. The percentage of silica in RH ash ranges from 60 to 40%, with the remaining percentage consisting of various minerals. As a direct consequence of this, several distinct approaches to generating and extracting nanomaterial from rice husk have been developed. Because it contains a significant amount of cellulose and lignin, RH is an excellent and economical source of carbon precursor. The goal of this chapter is to produce carbon-based nanomaterials from RH.

Environmental assessment of wastewater management via hybrid nanocomposite matrix implications-an organized review.

Pollution of water is currently a significant worry for scientific communities all over the world, and it is imperative that this problem be solved as quickly as possible. It is today recognized to be one of the most important foci of research worldwide. The present dilemma of clean, fresh waste is being addressed by the subsequent ejection of impurities from polluted water following recycling. There are several effective solutions that have been promoted as a solution to this problem. Even if the present procedures for wastewater treatment degrade a wide variety of effluents efficiently, these protocols still have some kind of restrictions. The most cutting-edge research in this area is being done on the subject of nanotechnology, which has an astounding number of potential uses, one of which is the treatment of wastewater. One of the value-added alternatives utilized for water purification by eliminating the many types of pollutants found in wastewater is the green synthesis of nanocomposites in adsorbents, magnetic separation, photocatalysts, and other similar processes. Within the scope of this study, the most significant discoveries of nanocomposites to date that have been made towards the remediation of wastewater are highlighted.

Base mediated green synthesis of enantiopure 2-C-spiro-glycosyl-3-nitrochromenes.

A novel green synthetic methodology has been developed to obtain enantiopure (2S)-2-C-spiro-glycosyl-3-nitrochromenes following the oxa-Michael-aldol condensation reaction of sugar derived 3-C-vinyl nitro olefins with substituted salicylaldehydes using Et3N as a base under neat conditions at rt-40 °C. The stereochemistry of the product is confirmed by a single crystal X-ray study. Several advantages are associated with this protocol such as cost effectiveness, easy accessibility, short reaction time, high yields, wide substrate scope and high enantiopurity.

Diastereoselective synthesis of novel spiro indanone fused pyrano[3,2-c]chromene derivatives following hetero-Diels-Alder reaction and in vitro anticancer studies.

The development of concise methods for the synthesis of small functionalised spirocyclic molecules is important in the search of new bioactive molecules. To contribute this, here we represent a diastereoselective oxa-hetero-Diels-Alder reaction for the synthesis of novel spiro indanone fused pyrano[3,2-c]chromene derivatives and studied their in vitro anticancer activities. Using previously less explored cyclic ketone i.e. indane-1,3-dione and 3-vinyl-2H-chromene derivatives, we obtained novel spiro-heterocyclic frameworks at the interphase between "drug-like" molecules and natural products. Various spiro indanone fused pyrano[3,2-c]chromene derivatives were synthesized regiospecifically bearing a quaternary stereocenter in high yields (up to 85%) with excellent diastereoselectivity in toluene using 4 Å MS as additive under reflux condition at 120 °C. In vitro cytotoxic studies of these compounds against MCF-7 (breast cancer), HCT-116 (colon cancer), H-357 (oral cancer), MD-MB-231(Breast cancer) cell lines were evaluated by MTT {3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide} assay in vitro. The screening results revealed that many of the compounds are showing moderate to high levels of anticancer activities against the tested cancer cell lines and some displayed potent inhibitory activities in comparison to the commercial anticancer drug 5-fluorouracil (5-FU). Among the series, compound 3'c showed most potent cytotoxicity (15.0-27.5 µM) in three cancer cell lines (MCF-7, HCT-116 and MD-MB-231).