SMILEY-assistive application to support social and emotional skills in SPCD individuals.

According to the available studies, mobile applications have provided significant support in improving the diverse skills of special individuals with social pragmatic communication disorder (SPCD). Over the last decade, SPCD has affected 8 to 11% of individuals, and therapy sessions cost between $50 and $150 per hour. This preliminary study aims to develop an interactive, user-friendly intervention to enhance social and emotional interaction skills in individuals with SPCD. The proposed intervention is an Android application that enhances social and emotional interaction skills. This pilot study involved 29 human subjects aged 7-13 years with pragmatic communication deficits. In a randomized controlled trial, the intervention was developed and implemented with consideration of caregiver and professional requirements. The improvement was analyzed using standard scales, including the Social Communication Questionnaire (SCQ) and the Social Communication Disorder Scale (SCDS). Moreover, the outcomes were examined through statistical parameters (mean, standard deviation) and tests (t-test). The intervention significantly improved the social and emotional skills of individuals with deficits. Before using the intervention, the identified statistical values for SCQ (mean = 6.48 and standard deviation = 3.37) and SCDS (mean = 8.17 and standard deviation = 4.79). However, after using the intervention, values for SCQ (mean = 8.24 and standard deviation = 3.95) and SCDS (mean = 9.48 and standard deviation = 4.72) were improved in comparison to the before-intervention outcome. The evaluation of the t-scores and p-values indicates that there has been significant improvement in the performance of individuals after the successful completion of the intervention. The proposed and applied intervention resulted in a significant impact in terms of improvement in social and emotional skills. The study concluded that it allows individuals to practice social and emotional interaction skills in a structured, controlled, and interactive environment. The proposed intervention has been found acceptable as per the reviews of caregivers and professionals, based on essential criteria including user experience, usability, interactive nature, reliability, and creditability.

Ferromagnetic Ni1-xVxO1-y Nano-Clusters for NO Detection at Room Temperature: A Case of Magnetic Field-Induced Chemiresistive Sensing.

Surface modulation of functional nanostructures is an efficient way of improving gas sensing properties in chemiresistive materials. However, synthesis methods employed so far in achieving desired performances are cumbersome and energy intensive. Moreover, nano-engineering-induced magnetic properties of these materials which are expected to enhance sensing responses have not been utilized until now in improving their interaction with target gases. In particular for gasses with paramagnetic nature such as NO or NO2, the inherent magnetic property of the chemiresistor might assist in enabling superior sensing performance. In this work, vanadium-doped NiO nano-clusters with ferromagnetic behavior at room temperature have been synthesized by a simple and effective combination of soft chemical routes and employed in efficient and selective detection of paramagnetic NO gas. While NiO is typically anti-ferromagnetic, the nanoscale engineering of NiO- and V-doped NiO samples have been found to tune the inherent anti-ferromagnetic behavior into room-temperature ferromagnetism. Surface modification in terms of formation of nano-clusters led to an increased Brunauer-Emmett-Teller surface area of ∼120 m2/g. The sample Ni0.636V0.364O has been observed to exhibit a selective and high response of ∼98% to 1 ppm NO at room temperature with fast response (14 s) and recovery (95 s). The improved sensing response of this sample compared to other doped NiO variants could be explained in terms of lower remnant magnetic moment of the sample accompanied with higher excess negative charge at the surface. The sensing response of this sample was increased by 30% in the presence of an external magnetic field of 280 gauss, highlighting the importance of magnetic ordering in chemiresistive gas sensing between the magnetic sensor material and target analyte. This material stands as a potential gas sensor with excellent NO detection properties.

Magnetic Configuration Driven Femtosecond Spin Dynamics in Synthetic Antiferromagnets.

Ultrafast demagnetization in diverse materials has sparked immense research activities due to its captivating richness and contested underlying mechanisms. Among these, the two most celebrated mechanisms have been the spin-flip scattering (SFS) and spin transport (ST) of optically excited carriers. In this work, we have investigated femtosecond laser-induced ultrafast demagnetization in perpendicular magnetic anisotropy-based synthetic antiferromagnets (p-SAFs) where [Co/Pt]n-1/Co multilayer blocks are separated by Ru or Ir spacers. Our investigation conclusively shows that the ST of optically excited carriers can have a significant contribution to the ultrafast demagnetization in addition to SFS processes. Moreover, we have also achieved an active control over the individual mechanisms by specially designing the SAF samples and altering the external magnetic field and excitation fluence. Our study provides a vital understanding of the underlying mechanism of ultrafast demagnetization in synthetic antiferromagnets, which will be crucial in future research and applications of antiferromagnetic spintronics.

Femtosecond laser-induced spin dynamics in single-layer graphene/CoFeB thin films.

Graphene/ferromagnet hybrid heterostructures are important building blocks of spintronics due to the unique ability of graphene to transport spin current over unprecedented distances and possible increase in its spin-orbit coupling due to proximity and hybridization. Here, we present magnetization dynamics over a femtosecond to nanosecond timescale by employing an all-optical time-resolved magneto-optical Kerr effect technique in single-layer graphene (SLG)/CoFeB thin films with varying CoFeB thickness and compared them with reference CoFeB thin films without an SLG underlayer. Gilbert damping variation with CoFeB thickness is modelled to extract spin-mixing conductance for the SLG/CoFeB interface and isolate the two-magnon scattering contribution from spin pumping. In SLG/CoFeB, we have established an inverse relationship between ultrafast demagnetization time (τm) and the Gilbert damping parameter (α) induced by interfacial spin accumulation and pure spin-current transport via a spin pumping mechanism. This systematic study of ultrafast demagnetization in SLG/CoFeB heterostructures and its connection with magnetic damping can help to design graphene-based ultrahigh-speed spintronic devices.

Structural Phase-Dependent Giant Interfacial Spin Transparency in W/CoFeB Thin-Film Heterostructures.

Pure spin current has transformed the research field of conventional spintronics due to its various advantages, including energy efficiency. An efficient mechanism for generation of pure spin current is spin pumping, and high effective spin-mixing conductance (Geff) and interfacial spin transparency (T) are essential for its higher efficiency. By employing the time-resolved magneto-optical Kerr effect technique, we report here a giant value of T in substrate/W (t)/Co20Fe60B20 (d)/SiO2 (2 nm) thin-film heterostructures in the beta-tungsten (ß-W) phase. We extract the spin diffusion length of W and spin-mixing conductance of the W/CoFeB interface from the variation of damping as a function of W and CoFeB thickness. This leads to a value of T = 0.81 ± 0.03 for the ß-W/CoFeB interface. A stark variation of Geff and T with the thickness of the W layer is obtained in accordance with the structural phase transition and resistivity variation of W with its thickness. Effects such as spin memory loss and two-magnon scattering are found to have minor contributions to damping modulation in comparison to the spin pumping effect which is reconfirmed from the unchanged damping constant with the variation of Cu spacer layer thickness inserted between W and CoFeB. The giant interfacial spin transparency and its strong dependence on crystal structures of W will be important for future spin-orbitronic devices based on pure spin current.