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1.
Macromol Rapid Commun ; 39(7): e1700743, 2018 Apr.
Article in English | MEDLINE | ID: mdl-29333693

ABSTRACT

Silicon wafers are decorated with photoamine generator 4,5-dimethoxy-2-nitrobenzyl 3-(triethoxysilyl)propyl carbamate. UV-irradiation in the presence of benzyl-l-glutamate N-carboxyanhydride is carried out, resulting in the release of the surface-bound primary amines, making them viable N-carboxyanhydride (NCA) polymerization initiators. Successful polypeptide grafting is confirmed by water contact angle measurements as well as by ellipsometry, revealing a poly(benzyl-l-glutamate) (PBLG) layer of ≈3 nm. X-ray photoelectron spectroscopy confirms the presence of amide groups in the grafted PBLG while time-of-flight secondary ion mass spectroscopy provides additional evidence for the presence of PBLG on the surface. Evaluation of negative control samples confirms successful UV surface grafting. The approach is thus established as a viable general method for light exposure directable polypeptide functionalization of silicon surfaces.


Subject(s)
Amino Acids/chemistry , Carbamates/chemical synthesis , Polyglutamic Acid/analogs & derivatives , Ultraviolet Rays , Mass Spectrometry , Photoelectron Spectroscopy , Polyglutamic Acid/chemical synthesis , Polyglutamic Acid/chemistry
2.
Adv Mater ; 27(34): 4958-62, 2015 Sep 09.
Article in English | MEDLINE | ID: mdl-26198714

ABSTRACT

A new, simple bi-phasic dip-coating method is developed. This method is considered as a great improvement of the technique for research, development and production, since expensive, rare, harmful, or time-evolving solutions can now be easily deposited on large surfaces and on a single side from very little amounts of solution.

3.
ACS Nano ; 9(7): 7572-82, 2015 Jul 28.
Article in English | MEDLINE | ID: mdl-26161962

ABSTRACT

Although gold nanoparticles stabilized by organic thiols are the building blocks in a wide range of applications, the role of the ligands on the plasmon resonance of the metal core has been mostly ignored until now. Herein, a methodology based on the combination of spectroscopic ellipsometry and UV-vis spectroscopy is applied to extract dielectric functions of the different components. It is shown that aromatic thiols allow a significant charge transfer at the hybrid interface with the s and d bands of the gold core that yields "giant" red shifts of the plasmon band, up to 40 nm for spherical particles in the size range of 3-5 nm. These results suggest that hybrid nanoplasmonic devices may be designed through the suitable choice of metal core and organic components for optimized charge exchange.

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