Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 3 de 3
Filter
Add more filters










Database
Language
Publication year range
1.
Mater Horiz ; 10(6): 2013-2023, 2023 Jun 06.
Article in English | MEDLINE | ID: mdl-37222107

ABSTRACT

Owing to the rise in global population and living standards, waste treatment has inevitably become a critical issue for a sustainable environment. In particular, for an effective recycling process, it is vital to disassemble different types of materials by removing adhesives used in the packaging. However, this removal process requires harsh solvents (acidic and organic) that are unfriendly to nature and may cause additional pollution. To address this issue, functional adhesive materials that can be removed without the use of harsh solvents have drawn significant attention. One promising approach is to utilize the stimuli-responsive polymers to synthesize pressure sensitive adhesives (PSAs); however, it is technically challenging to simultaneously satisfy (i) strong initial adhesion (without stimulus), (ii) stimuli-responsive sufficient reduction of adhesion, and (iii) reversibility. In this study, thermo-switchable PSAs were synthesized by copolymerizing N-isopropylacrylamide (NIPAM), which possesses thermal-responsive properties; acrylic acid, which endows adhesive properties; and 2-ethylhexyl acrylate, which has a low glass transition temperature to attain sufficient flexibility. The synthesized NIPAM-based thermo-switchable PSAs exhibited significantly high peel strength at room temperature (∼15.41 N/25 mm at 20 °C), which decreased by ∼97% upon heating (∼0.46 N/25 mm at 80 °C). Importantly, no residues remained due to the cohesive nature of NIPAM at high temperature. The reversible adhesion behaviour of the thermo-switchable PSAs was retained during repeated heating and cooling cycles. Therefore, the developed thermo-switchable PSA can enhance the reusability and recyclability of valuable materials and minimize the use of toxic chemicals for adhesive removal, contributing to a more sustainable future.

2.
Nanomaterials (Basel) ; 12(16)2022 Aug 16.
Article in English | MEDLINE | ID: mdl-36014679

ABSTRACT

As electronics become more portable and compact, the demand for high-performance thermally conductive composites is increasing. Given that the thermal conductivity correlates with the content of thermally conductive fillers, it is important to fabricate composites with high filler loading. However, the increased viscosity of the composites upon the addition of these fillers impedes the fabrication of filler-reinforced composites through conventional methods. In this study, hexagonal-boron-nitride (h-BN)-pattern-embedded aluminum oxide (Al2O3) composites (Al/h-BN/Al composites) were fabricated by coating a solution of h-BN onto a silicone-based Al2O3 composite through a metal mask with square open areas. Because this method does not require the dispersion of h-BN into the Al2O3 composite, composites with high filler loading could be fabricated without the expected problems arising from increased viscosity. Based on the coatability and thixotropic rheological behaviors, a composite with 85 wt.% Al2O3 was chosen to fabricate Al/h-BN/Al composites. The content of the Al2O3 and the h-BN of the Al/h-BN/Al-1 composite was 74.1 wt.% and 12.8 wt.%, respectively. In addition to the increased filler content, the h-BN of the composite was aligned in a parallel direction by hot pressing. The in-plane (kx) and through-plane (kz) thermal conductivity of the composite was measured as 4.99 ± 0.15 Wm-1 K-1 and 1.68 ± 0.2 Wm-1 K-1, respectively. These results indicated that the method used in this study is practical not only for increasing the filler loading but also for achieving a high kx through the parallel alignment of h-BN fillers.

3.
Polymers (Basel) ; 11(1)2019 Jan 11.
Article in English | MEDLINE | ID: mdl-30960101

ABSTRACT

Owing to their natural abundance and exceptional mechanical properties, cellulose fibers (CFs) have been used for reinforcing polymers. Despite these merits, dispersing hydrophilic CFs in a hydrophobic polymer matrix is challenging. To address this, an amphiphilic ammonium salt was employed as the dispersant for CFs in this study. The hydrophobic CFs were mixed with a healable polymer to produce CF-reinforced composites. As the thermosetting polymer was crosslinked with Diels⁻Alder (DA) adducts, it was mended and recycled via a retro DA reaction at 120 °C. Interestingly, the CF-reinforced polymer composites were mended and recycled as well. When 5 wt % of the hydrophobic CFs was added to the polymer, maximum tensile strength, elongation at break, Young's modulus, and toughness increased by 70%, 183%, 75%, and 420%, respectively. After recycling, the CF-reinforced composites still featured better mechanical properties than recycled polymer.

SELECTION OF CITATIONS
SEARCH DETAIL
...