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1.
Inorg Chem ; 50(18): 9147-52, 2011 Sep 19.
Article in English | MEDLINE | ID: mdl-21842896

ABSTRACT

The concept and occurrence of isoreticular (same topology) series of metal-organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu(3)(4,4',4''-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate)(2), MOF-399) and pto topologies (Cu(3)(4,4',4''-(benzene-1,3,5-triyl-tribenzoate)(2), MOF-143; Cu(3)(4,4',4''-(triazine-2,4,6-triyl-tris(benzene-4,1-diyl))tribenzoate)(2), MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm(-3)) of any MOFs reported to date.


Subject(s)
Copper/chemistry , Organometallic Compounds/chemistry , Crystallography, X-Ray , Models, Molecular , Porosity
2.
Chem Commun (Camb) ; 46(18): 3086-8, 2010 May 14.
Article in English | MEDLINE | ID: mdl-20379607

ABSTRACT

Ni nanoparticles embedded in the pores of a mesoporous MOF (MesMOF-1) act as a catalyst for hydrogenolysis of nitrobenzene or hydrogenation of styrene.

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