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Flavin-based [2]rotaxanes.
Cooke, Graeme; Garety, James F; Jordan, Brian; Kryvokhyzha, Nadiya; Parkin, Andy; Rabani, Gouher; Rotello, Vincent M.
Org Lett ; 8(11): 2297-300, 2006 May 25.
Article in English | MEDLINE | ID: mdl-16706510

ABSTRACT

[reaction: see text] We report the synthesis of flavin-stoppered hydrogen bonded [2]rotaxanes 1 and 2. We also report the electrochemically controllable properties of these systems in solution, and for derivative 2, as an electropolymerized thin film.


Subject(s)
Flavins/chemistry , Rotaxanes/chemistry , Rotaxanes/chemical synthesis , Crystallography, X-Ray , Electrochemistry/methods , Hydrogen Bonding , Molecular Conformation , Molecular Structure
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