Coagulation in combination with anaerobic digestion for enhancement of resource recovery from faecal sludge.

Poorly managed faecal sludge (FS) poses significant challenges to public health and the environment. Anaerobic digestion (AD) of FS provides an effective method for energy recovery while reducing FS associated threats. Recognizing the critical role of the dewatering process before AD, this study investigates the synergistic application of chemical coagulation and mesophilic AD for synthetic FS treatment. FeCl3, AlCl3, Fe2(SO4)3, poly ferric sulfate (PFS) and poly aluminium ferric chloride (PAFC) were utilized at varying dosages to examine their impact on FS properties and subsequent biogas production from the dewatered FS. It was found that coagulation enhances sedimentation efficiencies and dewaterability through mechanisms such as charge neutralization, charge patching and bridging, thereby improving the FS feasibility for AD. Notably, polymer coagulant PFS showed good performance in balancing pollutant removal and methane recovery, contributing to facilitating the hydrolysis and acidogenesis microorganisms involved in the AD process. Optimal dosage was identified at 150 mg/g TS (1.7 g/L FS), achieving prominent removal efficiencies for total COD (67%), turbidity (85%), and total phosphorus (60%), while simultaneously enhancing AD performance with specific CH4 production reaching 517 ml CH4/g VS or 24.8 ml CH4/g AD wet feedstock compared to 309 ml CH4/g VS or 2.7 ml CH4/g AD wet feedstock in untreated FS.

Electrocoagulation flotation as a municipal wastewater (pre-)treatment technology: Effect of weather conditions and current density.

Electrocoagulation (EC) is a promising compact alternative technology, despite its viability in municipal wastewater treatment (MWWT) is currently challenged by its energy-intensive and batch-mode operation. This study introduces an innovative continuous electrocoagulation flotation (ECF) design for MWWT. ECF shows promising pollutant removal efficiencies, with identical results using both iron (Fe) and aluminum (Al) anodes. At a current density (CD) of 120 A/m2, it achieved significant removals: 90% tCOD, 98% TP, 94% TSS, 60% BOD5, and 40% TN. Designed ECF is proposed as a pre-treatment step due to limited TN removal. The study investigated optimal ECF performance under varying weather conditions using CD ranges of 40, 80, and 120 A/m2. Both Fe and Al ECF outperformed in treating rainy weather (RW) and dry weather (DW) municipal wastewater (MWW). However, Al anode's super-faradaic behavior resulted in higher residual concentrations in effluent, (i.e., an average of 6.53-33.7 mg/L), and operational costs compared to Fe ECF. Optimized Fe ECF setting needs to be changed depending in the weather variation. Fe ECF achieved high removal rates for tCOD (94%) and TP (95%) in RW MWW at a low CD of 40 A/m2. Comparative to this, the optimum CD for treated DW MWW was between 40 and 80 A/m2, removing tCOD (71-73%) and TP (85-95%). Specifically, at these conditions, the operational expenses were respectively 0.47 ± 0.03 €/m3 (RW MWW), and 0.37 ± 0.02 €/m3 to 0.81 ± 0.04 €/m3 (DW MWW). Moreover, ECF enables resource recovery and a circular economy through anaerobic sludge digestion, with Fe ECF generating more biogas than Al.

Removal of alkali and transition metal ions from water with hydrophobic deep eutectic solvents.

Hydrophobic deep eutectic solvents were used for the first time for the removal of metal ions from non-buffered water. It was shown that the extraction occurs via an ion exchange mechanism in which all transition metal ions could be extracted with high distribution coefficients, even for high Co2+ concentrations and low DES/water mass ratios. Maximum extraction efficiency could be reached within 5 s and regeneration was possible.

A mechanism for solvent extraction of first row transition metals from chloride media with the ionic liquid tetraoctylammonium oleate.

Aqueous waste streams of the metallurgical industry often contain considerable concentrations of metal salts. Previous research showed that the metal chloride salts of zinc(ii), manganese(ii) and iron(iii) can be recovered by solvent extraction using a sustainable and renewable fatty acid based ionic liquid as the extractant. In this paper, the extraction mechanism of Zn(ii), Co(ii) and Ni(ii) from chloride media has been studied systematically. The metal extraction performances of the precursors, sodium oleate and tetraoctylammonium chloride, were compared to the extraction performance of the ionic liquid tetraoctylammonium oleate. Slope analysis experiments were performed to determine the number of ionic liquid molecules involved in the extraction. The experimental data showed that Co(ii) and Ni(ii) were extracted in the pH range from 6 to 8 by the formation of negatively charged metal carboxylate complexes with tetraalkylammonium counter ions. In contrast, Zn(ii) gets extracted as a mixed metal chloride carboxylate anionic complex with tetraalkylammonium counter ions. This extraction mechanism was supported by EXAFS measurements.