Perturbation Independent Decay of the Loschmidt Echo in a Many-Body System.

When a qubit or spin interacts with others under a many-body Hamiltonian, the information it contains progressively scrambles. Here, nuclear spins of an adamantane crystal are used as a quantum simulator to monitor such dynamics through out-of-time-order correlators, while a Loschmidt echo (LE) asses how weak perturbations degrade the information encoded in these increasingly complex states. Both observables involve the implementation of a time-reversal procedure which, in practice, involves inverting the sign of the effective Hamiltonian. Our protocols use periodic radio frequency pulses to modulate the natural dipolar interaction implementing a Hamiltonian that can be scaled down at will. Meanwhile, experimental errors and strength of perturbative terms remain constant and can be quantified through the LE. For each scaling factor, information spreading occurs with a timescale, T_{2}, inversely proportional to the local second moment of the Hamiltonian. We find that, when the reversible interactions dominate over the perturbations, the information scrambled among up to 10^{2} spins can still be recovered. However, we find that the LE decay rate cannot become smaller than a critical value 1/T_{3}≈(0.15±0.02)/T_{2}, which only depends on the interactions themselves, and not on the perturbations. This result shows the emergence of a regime of intrinsic irreversibility in accordance to a central hypothesis of irreversibility, hinted from previous experiments.

Quantum dynamics of excitations and decoherence in many-spin systems detected with Loschmidt echoes: its relation to their spreading through the Hilbert space.

In this work, we overview time-reversal nuclear magnetic resonance (NMR) experiments in many-spin systems evolving under the dipolar Hamiltonian. The Loschmidt echo (LE) in NMR is the signal of excitations which, after evolving with a forward Hamiltonian, is recovered by means of a backward evolution. The presence of non-diagonal terms in the non-equilibrium density matrix of the many-body state is directly monitored experimentally by encoding the multiple quantum coherences. This enables a spin counting procedure, giving information on the spreading of an excitation through the Hilbert space and the formation of clusters of correlated spins. Two samples representing different spin systems with coupled networks were used in the experiments. Protons in polycrystalline ferrocene correspond to an 'infinite' network. By contrast, the liquid crystal N-(4-methoxybenzylidene)-4-butylaniline in the nematic mesophase represents a finite proton system with a hierarchical set of couplings. A close connection was established between the LE decay and the spin counting measurements, confirming the hypothesis that the complexity of the system is driven by the coherent dynamics.

Molecular dissociation in the presence of catalysts: interpreting bond breaking as a quantum dynamical phase transition.

In this work we show that molecular chemical bond formation and dissociation in the presence of the d-band of a metal catalyst can be described as a quantum dynamical phase transition (QDPT). This agrees with DFT calculations that predict sudden jumps in some observables as the molecule breaks. According to our model this phenomenon emerges because the catalyst provides for a non-Hermitian Hamiltonian. We show that when the molecule approaches the surface, as occurs in the Heyrovsky reaction of H2, the bonding H2 orbital has a smooth crossover into a bonding molecular orbital built with the closest H orbital and the surface metal d-states. The same occurs for the antibonding state. Meanwhile, two resonances appear within the continuous spectrum of the d-band, which are associated with bonding and antibonding orbitals between the furthest H atom and the d-states at the second metallic layer. These move toward the band center, where they collapse into a pure metallic resonance and an almost isolated H orbital. This phenomenon constitutes a striking example of the non-trivial physics enabled when one deals with non-Hermitian Hamiltonian beyond the usual wide band approximation.

Decay of the Loschmidt echo in a time-dependent environment.

We study the decay rate of the Loschmidt echo or fidelity in a chaotic system under a time-dependent perturbation V(q,t) with typical strength Planck's/tau(v) . The perturbation represents the action of an uncontrolled environment interacting with the system, and is characterized by a correlation length xi(0) and a correlation time tau(0). For small perturbation strengths or rapid fluctuating perturbations, the Loschmidt echo decays exponentially with a rate predicted by the Fermi "golden rule," 1/approximately tau =tau(c)/tau(v)(2), where tau(c) approximately min[tau(0), xi(0)/upsilon] and upsilon is the typical particle velocity. Whenever the rate 1/approximately tau is larger than the Lyapunov exponent of the system, a perturbation independent Lyapunov decay regime arises. We also find that by speeding up the fluctuations (while keeping the perturbation strength fixed) the fidelity decay becomes slower, and hence one can protect the system against decoherence.

Coherent versus sequential electron tunneling in quantum dots.

Manifestations of quantum coherence in the electronic conductance through nearly closed quantum dots in the Coulomb-blockade regime are addressed. We show that quantum coherent tunneling processes explain some puzzling statistical features of the conductance peak heights observed in recent experiments at low temperatures. We employ the constant interaction model and the random matrix theory to model the quantum dot electronic interactions and its single-particle statistical fluctuations, taking full account of the finite decay width of the quantum dot levels.

Decoherence as decay of the Loschmidt echo in a Lorentz gas.

Classical chaotic dynamics is characterized by exponential sensitivity to initial conditions. Quantum mechanics, however, does not show this feature. We consider instead the sensitivity of quantum evolution to perturbations in the Hamiltonian. This is observed as an attenuation of the Loschmidt echo M(t), i.e., the amount of the original state (wave packet of width sigma) which is recovered after a time reversed evolution, in the presence of a classically weak perturbation. By considering a Lorentz gas of size L, which for large L is a model for an unbounded classically chaotic system, we find numerical evidence that, if the perturbation is within a certain range, M(t) decays exponentially with a rate 1/tau(phi) determined by the Lyapunov exponent lambda of the corresponding classical dynamics. This exponential decay extends much beyond the Eherenfest time t(E) and saturates at a time t(s) approximately equal to lambda(-1)ln[N], where N approximately (L/sigma)(2) is the effective dimensionality of the Hilbert space. Since tau(phi) quantifies the increasing uncontrollability of the quantum phase (decoherence) its characterization and control has fundamental interest.

Measuring the Lyapunov exponent using quantum mechanics.

We study the time evolution of two wave packets prepared at the same initial state, but evolving under slightly different Hamiltonians. For chaotic systems, we determine the circumstances that lead to an exponential decay with time of the wave packet overlap function. We show that for sufficiently weak perturbations, the exponential decay follows a Fermi golden rule, while by making the difference between the two Hamiltonians larger, the characteristic exponential decay time becomes the Lyapunov exponent of the classical system. We illustrate our theoretical findings by investigating numerically the overlap decay function of a two-dimensional dynamical system.

Environment-independent decoherence rate in classically chaotic systems.

We study the decoherence of a one-particle system, whose classical correspondent is chaotic, when it evolves coupled to a weak quenched environment. This is done by analytical evaluation of the Loschmidt echo (i.e., the revival of a localized density excitation upon reversal of its time evolution), in the presence of the perturbation. We predict an exponential decay for the Loschmidt echo with a (decoherence) rate which is asymptotically given by the mean Lyapunov exponent of the classical system, and therefore independent of the perturbation strength, within a given range of strengths. Our results are consistent with recent experiments of polarization echoes in nuclear magnetic resonance and numerical simulations.