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1.
Materials (Basel) ; 11(3)2018 Feb 28.
Article in English | MEDLINE | ID: mdl-29495571

ABSTRACT

An innovative recycling process for thermoset polymer composites developed by Connora Technologies (Hayward, CA, USA) was studied. The process efficacy has already been tested, and it is currently working at the plant level. The main aspect investigated in the present paper was the environmental impact by means of the Life Cycle Assessment (LCA) method. Because of the need to recycle and recover materials at their end of life, the Connora process creates a great innovation in the market of epoxy composites, as they are notoriously not recyclable. Connora Technologies developed a relatively gentle chemical recycling process that induces the conversion of thermosets into thermoplastics. The LCA demonstrated that low environmental burdens are associated with the process itself and, furthermore, impacts are avoided due to the recovery of the epoxy-composite constituents (fibres and matrix). A carbon fibre (CF) epoxy-composite panel was produced through Vacuum Resin Transfer Moulding (VRTM) and afterwards treated using the Connora recycling process. The LCA results of both the production and the recycling phases are reported.

2.
Chem Commun (Camb) ; 47(2): 665-7, 2011 Jan 14.
Article in English | MEDLINE | ID: mdl-21113530

ABSTRACT

Acid-degradable microcapsules were prepared via an interfacial polymerization. Degradation of the thin wall of the capsules leads to all-or-nothing cargo release. The only byproducts of degradation are acetone, and a non-toxic triamide. Proof-of-concept experiments showed that cargo can be delivered to and released in cells.


Subject(s)
Acids/chemistry , Capsules/chemistry , Drug Carriers/chemistry , Biocompatible Materials/chemistry , Cell Line, Tumor , Humans , Hydrogen-Ion Concentration , Kinetics , Paclitaxel/administration & dosage
3.
J Am Chem Soc ; 132(20): 6890-1, 2010 May 26.
Article in English | MEDLINE | ID: mdl-20438114

ABSTRACT

The patterning of a surface with more than one type of functionality in spatially resolved fashion is described. A scanning probe was used to create patterns composed of two orthogonal types of functionality within a dense, electrochemically active mixed monolayer via a simple modulation of the applied surface bias. One reductive pathway produces surface-bound amine moieties while the other creates an oxidized surface. The two newly created surface functionalities can each be used independently to locally deposit complementary materials such as electron- or hole-transporting molecules via self-assembly.


Subject(s)
Nanotechnology/methods , Amines/chemistry , Benzoquinones/chemistry , Electrochemistry , Microscopy, Atomic Force , Oxidation-Reduction , Oxygen/chemistry , Silanes/chemistry , Surface Properties
4.
J Am Chem Soc ; 131(38): 13586-7, 2009 Sep 30.
Article in English | MEDLINE | ID: mdl-19736938

ABSTRACT

We report the development of phototriggerable microcapsules and demonstrate the concept of protection and remote release of chemical species. Light-rupturable, liquid-filled microcapsules were prepared by coencapsulation of carbon nanotubes using a simple and robust interfacial polymerization technique. The incorporation of carbon nanotubes endows the microcapsules with the ability to respond to an external optical event. The triggered release of the liquid contents for the microcapsules may be achieved either in air or within a liquid medium via irradiation with a near-IR laser. Rupture of the impermeable shell-wall under irradiation is presumed to be due to an increase in internal pressure due to optothermal heating of the CNTs. The storage and triggered release of reactive small molecules and catalysts was demonstrated in the context of remotely initiated "click" reaction and ring-opening metathesis polymerization.


Subject(s)
Capsules/chemistry , Light , Nanotubes, Carbon/chemistry , Lasers , Microscopy, Electron, Scanning , Nylons/chemistry , Photochemical Processes , Toluene/chemistry
5.
J Am Chem Soc ; 131(15): 5396-8, 2009 Apr 22.
Article in English | MEDLINE | ID: mdl-20560635

ABSTRACT

As energy demands increase, new, more direct, energy collection and utilization processes must be explored. We present a system that intrinsically combines the absorption of sunlight with the production of useful work in the form of locomotion of objects on liquids. Focused sunlight is locally absorbed by a nanostructured composite, creating a thermal surface tension gradient and, subsequently, motion. Controlled linear motion and rotational motion are demonstrated. The system is scale independent, with remotely powered and controlled motion shown for objects in the milligram to tens of grams range.


Subject(s)
Energy-Generating Resources , Motion , Sunlight , Surface Tension , Nanocomposites/radiation effects , Physical Phenomena , Rotation , Solar Energy
6.
J Am Chem Soc ; 130(13): 4238-9, 2008 Apr 02.
Article in English | MEDLINE | ID: mdl-18331043

ABSTRACT

A facile patterning method for the functionalization of vertically aligned carbon nanotubes is described. Modification of the surface of nanotube forests with hydrophilic, hydrophobic, or polymerizable small molecules was achieved via UV-triggered attachment of perfluoroarylazides. Multiple functionalizations of the tube surface can be achieved. Macro- and micropatterning of forest substrates were demonstrated. Superhydrophobic surfaces containing superhydrophilic regions were prepared.


Subject(s)
Azides/chemistry , Nanotubes, Carbon/chemistry , Azides/radiation effects , Hydrophobic and Hydrophilic Interactions , Nanotubes, Carbon/radiation effects , Particle Size , Surface Properties , Ultraviolet Rays , Wettability
7.
J Am Chem Soc ; 129(38): 11750-5, 2007 Sep 26.
Article in English | MEDLINE | ID: mdl-17803274

ABSTRACT

This paper describes the development of a new catalytic transformation, the ruthenium-catalyzed decarbonylative arylation of cyclic 2-amino esters, which replaces the ester group with an aryl ring at the sp3 carbon center. For example, proline ester amidine 1 is converted to 2-arylpyrrolidine 3 in the presence of arylboronic acids or esters as arene donors and Ru(3)(CO)(12) as the catalyst. This process provides a rapid access to a variety of 2-arylpyrrolidines and piperidines from commercially available proline, hydroxyproline, and pipecolinate esters. The examination of the substrate scope also showed that many arene boronic acids and boronate esters serve as coupling partners. The high chemoselectivity of this process was demonstrated and ascribed to the significant rate difference between the decarbonylative arylation and the C-H arylation. The decarbonylative arylation complements the C-H arylation, since the latter process lacks control over the extent of functionalization, affording a mixture of mono- and bis-arylpyrrolidines. When applied in tandem, these two processes provide 2,5-diarylpyrrolidines in two steps from the corresponding proline esters. It was also demonstrated that the required amidine or iminocarbamate directing group fulfills two major functions: first, it is essential for the ester activation step, which occurs via the coordination-assisted metal insertion into the acyl C-O bond; second, it facilitates the decarbonylation, via the stabilization of a metallacycle intermediate, assuring the formation of the 2-arylated products instead of the corresponding ketones observed before by others.


Subject(s)
Carbon/chemistry , Esters/chemical synthesis , Hydrocarbons, Aromatic/chemistry , Ketones/chemistry , Piperidines/chemical synthesis , Pyrrolidines/chemical synthesis , Ruthenium/chemistry , Boronic Acids/chemistry , Catalysis , Esters/chemistry , Hydroxyproline/chemistry , Models, Chemical , Proline/chemistry , Stereoisomerism
8.
J Am Chem Soc ; 128(44): 14220-1, 2006 Nov 08.
Article in English | MEDLINE | ID: mdl-17076471

ABSTRACT

A new ruthenium-catalyzed direct sp3 C-H to C-C bond transformation is disclosed. Specifically, a method for the alpha-arylation of cyclic amines, containing either permanent (pyridine, pyrimidine) or removable (amidine) directing groups, is described. This cross-coupling reaction involves heating amine substrates with arylboronate ester at 150 degrees C in a ketone solvent with a catalytic amount of ruthenium carbonyl [Ru3(CO)12]. Arylboronate esters containing either electron-withdrawing or electron-donating substituents could be efficiently coupled. Heteroarene boronates were also effective donors.


Subject(s)
Amidines/chemistry , Carbon/chemistry , Hydrocarbons, Aromatic/chemistry , Hydrogen/chemistry , Piperidines/chemistry , Pyrrolidines/chemistry , Molecular Structure , Stereoisomerism
9.
Org Lett ; 7(24): 5429-31, 2005 Nov 24.
Article in English | MEDLINE | ID: mdl-16288523

ABSTRACT

[reaction: see text] The scope and limitations of intramolecular hydro-O-alkylation of aldehyde substrates leading to spiroketals and bicyclic ketals and aminals is reported. The direct transformation of tertiary and sterically hindered secondary sp(3) C-H bonds into C-O bonds under the action of a catalytic amount of a variety of Lewis acids is described. The mechanism of these transformations is proposed to involve a tandem hydride transfer/cyclization sequence.


Subject(s)
Aldehydes/chemistry , Alkylation , Catalysis , Cyclization , Indicators and Reagents , Molecular Structure , Temperature
10.
J Am Chem Soc ; 127(35): 12180-1, 2005 Sep 07.
Article in English | MEDLINE | ID: mdl-16131169

ABSTRACT

A practical method for the intramolecular hydroalkylation of electron-deficient olefins has been developed. The direct transformation of benzylic, tertiary, and sterically hindered secondary sp3 C-H bonds into C-C bonds under the action of a catalytic amount of a variety of Lewis acids is described. The mechanism of these transformations is proposed to involve a tandem hydride transfer/cyclization sequence.


Subject(s)
Acids/chemistry , Alkenes/chemistry , Carbon/chemistry , Hydrogen/chemistry , Alkylation , Catalysis , Electrons , Models, Chemical , Oxidation-Reduction , Temperature
11.
J Am Chem Soc ; 126(21): 6556-7, 2004 Jun 02.
Article in English | MEDLINE | ID: mdl-15161275

ABSTRACT

We herein present a new oxidative cyclization of alkene-amide substrates under neutral and catalytic conditions. This overall transformation requires tandem sp3 C-H activation (at the position adjacent to the amide nitrogen) and C-C bond formation. Specifically, pyrrolidine 1 was converted to pyrrolizidinone 3 and indolizidinone 4 in 66% and 17% yield, respectively, in the presence of [Ir(coe)2Cl]2, the carbene ligand IPr (1:1 metal/ligand ratio, 5-10 mol % of Ir), and the hydrogen acceptor (NBE or TBE, 3-10 equiv). The results presented in this study suggest that complex 10 [IPr-Ir(Cl)(substrate)] is the key intermediate in the catalytic cycle. On the mechanistic front, the key advance was the ability to facilitate C-H activation and alkene insertion in tandem, and in preference to beta-hydride elimination, in the context of amide substrates. With respect to complex synthesis, catalytic and neutral conditions of this method unlock new exciting opportunities as illustrated by regioselective cyclization of the proline-derived substrate 16.


Subject(s)
Alkenes/chemistry , Amides/chemistry , Bridged Bicyclo Compounds, Heterocyclic/chemical synthesis , Catalysis , Cyclization , Indoles/chemistry , Molecular Structure , Organometallic Compounds/chemistry , Oxidation-Reduction , Pyrroles/chemistry , Ruthenium/chemistry
12.
Org Lett ; 6(4): 581-4, 2004 Feb 19.
Article in English | MEDLINE | ID: mdl-14961628

ABSTRACT

[reaction: see text] We herein report that RuCl(3)/AgOTf has proven to be a hydroarylation catalyst with an efficiency and scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-ene substrates of diverse structural features, providing good to excellent yields of cyclization products (chromanes, tetralins, terpenoids, dihydrocoumarins).


Subject(s)
Alkenes/chemical synthesis , Chromans/chemical synthesis , Coumarins/chemical synthesis , Ruthenium/chemistry , Terpenes/chemical synthesis , Tetrahydronaphthalenes/chemical synthesis , Catalysis , Cyclization , Indicators and Reagents
13.
Org Lett ; 5(22): 4053-5, 2003 Oct 30.
Article in English | MEDLINE | ID: mdl-14572247

ABSTRACT

[reaction: see text]. A concise total synthesis of (+/-)-deguelin was achieved with a longest linear sequence of six steps in 68% yield. A key step was the platinum-catalyzed 6-endo hydroarylation of an alkynone intermediate.


Subject(s)
Rotenone/analogs & derivatives , Rotenone/chemical synthesis , Bridged-Ring Compounds/chemistry , Catalysis , Cyclization , Molecular Structure , Platinum Compounds/chemistry , Rotenone/chemistry
14.
Org Lett ; 5(7): 1055-8, 2003 Apr 03.
Article in English | MEDLINE | ID: mdl-12659572

ABSTRACT

[reaction: see text] We herein report that PtCl(4) has proven to be a hydroarylation catalyst with an efficiency and substrate scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-yne substrates of diverse structural features, including propargyl ethers, propargylamines, and alkynoate esters, providing good to excellent yields of the 6-endo products (chromenes, dihydroquinolines, and coumarins). In contrast, Pt(II), Pd(II), and Ga(III) salts were shown to be sensitive to the substitution on the alkyne moiety.

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