Impact of cell wall non-cellulosic and cellulosic polymers on the mechanical properties of flax fibre bundles.

Fibre bundles are groups of elementary fibres glued together thanks to the middle lamella, and are the main fraction in plant fibre composites. In this study, relationship between the mechanical properties of flax fibre bundles, chemical composition and cellulose structure were investigated. To do so, a sequential biopolymer extraction was implemented. Fibre bundles were first depectinated by oxalate extraction, and then the hemicelluloses were extracted by LiCl/dimethyl sulfoxide (DMSO) and KOH. The oxalate extract consisted of homogalacturonans and type I rhamnogalacturonans, while the LiCl extract was composed mainly of glucomannans and the KOH extract of xyloglucans. The KOH stage resulted in the appearance of cellulose II in flax bundles. The extraction of pectin and hemicelluloses led to the disappearance of the middle lamella concomitant with a decrease in the tensile Young's modulus and maximum strength. Finally, the fibre bundle composition, ultrastructure and mechanical properties are discussed together in view of the thin middle lamella.

Influence of Water Absorption on the Low Velocity Falling Weight Impact Damage Behaviour of Flax/Glass Reinforced Vinyl Ester Hybrid Composites.

Due to rigorous new environmental legislations, automotive, marine, aerospace, and construction sectors have redirected their focus into using more recyclable, sustainable, and environmentally friendly lightweight materials driven by strengthening resource efficiency drive. In this study, the influence of moisture absorption on flax and flax/glass hybrid laminates is presented with the aim to investigating their low velocity impact behaviour. Three different types of composite laminates namely, flax fibre reinforced vinyl ester, flax fibre hybridised glass fibre and glass fibre reinforced vinyl ester composites were fabricated using resin infusion technique. The moisture immersion tests were undertaken by immersing the different specimens in sea water bath at room temperature and 70 °C at different time durations. The low velocity falling weight impact testing was performed at 25 Joules of incident energy level and impact damage behaviour was evaluated at both ageing conditions using scanning electron microscopy (SEM) and X-ray microcomputed tomography (micro CT). The percentage of moisture uptake was decreased for flax vinyl ester specimens with glass fibre hybridisation. The maximum percentage of weight gain for flax fibre, flax/glass hybrid and glass fibre reinforced composites immersed at room temperature for 696 h is recorded at 3.97%, 1.93%, and 0.431%, respectively. The hybrid composite exhibited higher load and energy when compared flax/vinyl ester composite without hybridisation, indicating the hybrid system as a valid strategy towards achieving improved structural performance of natural fibre composites. The moisture absorption behaviour of these composites at room was observed to follow Fickian behaviour.