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1.
Materials (Basel) ; 16(24)2023 Dec 06.
Article in English | MEDLINE | ID: mdl-38138666

ABSTRACT

Heavy metal contamination, associated with the increase in industrial production and the development of the population in general, poses a significant risk in terms of the contamination of soil, water, and, consequently, industrial plants and human health. The presence of ecotoxic heavy metals (HMs) thus significantly limits the sustainable development of society and contributes to the deterioration of the quality of the environment as a whole. For this reason, the stabilization and immobilization of heavy metals is a very topical issue. This paper deals with the possibility of the simultaneous immobilization of heavy metals (Ba2+, Pb2+, and Zn2+) in mortar based on magnesium potassium phosphate cement (MKPC). The structural, mechanical, and hygric parameters of mortars artificially contaminated with heavy metals in the form of salt solutions were investigated together with the formed hydration products. In the leachates of the prepared samples, the content of HMs was measured and the immobilization ratio of each HM was determined. The immobilization rate of all the investigated HMs was >98.7%, which gave information about the effectiveness of the MKPC-based matrix for HM stabilization. Furthermore, the content of HMs in the leachates was below the prescribed limits for non-hazardous waste that can be safely treated without any environmental risks. Although the presence of heavy metals led to a reduction in the strength of the prepared mortar (46.5% and 57.3% in compressive and flexural strength, respectively), its mechanical resistance remained high enough for many construction applications. Moreover, the low values of the parameters characterizing the water transport (water absorption coefficient Aw = 4.26 × 10-3 kg·m-2·s-1/2 and sorptivity S = 4.0 × 10-6 m·s-1/2) clearly demonstrate the limited possibility of the leaching of heavy metals from the MKPC matrix structure.

2.
Polymers (Basel) ; 15(21)2023 Nov 01.
Article in English | MEDLINE | ID: mdl-37959979

ABSTRACT

The topic of modification of magnesium oxychloride cement (MOC) using specific functional additives is very much pronounced in the research of alternative building materials. This study deals with the co-doping of MOC by 1D and 2D carbon nanomaterials in order to improve its mechanical properties while using tannic acid (TA) as a surfactant. Furthermore, the effect of TA on MOC also improves its water resistance. As a filler, three size fractions of standard quartz sand are used. The proposed types of MOC-based composites show promising results considering their mechanical, macro- and microstructural, chemical, and hygric properties. The use of 1D and 2D nanoadditives and their mixture enables the improvement in the flexural strength and particularly the softening coefficient, which is the durability parameter characterizing the resistance of the prepared materials to water. After immersion in water for 24 h, the compressive strength of all tested specimens of modified composites was higher than that of the reference composite. Quantitatively, the developed co-doped composites show mechanical parameters comparable to or even better than those of commonly used Portland cement-based materials while maintaining high environmental efficiency. This indicates their potential use as an environmentally friendly alternative to Portland cement-based products.

3.
Materials (Basel) ; 15(19)2022 Oct 03.
Article in English | MEDLINE | ID: mdl-36234222

ABSTRACT

The presented research is focused on the complex assessment of three different types of diatomaceous earth and evaluation of their ability for application as pozzolana active admixtures applicable in the concrete industry and the production of repair mortars applicable for historical masonry. The comprehensive experimental campaign comprised chemical, mineralogical, microstructural, and physical testing of raw materials, followed by the analyses and characterization of pozzolanic activity, rheology and heat evolution of fresh blended pastes, and testing of macrostructural and mechanical parameters of the hardened 28-days and 90-days samples. The obtained results gave evidence of the different behavior of researched diatomaceous earth when mixed with water and Portland cement. The differences in heat evolution, initial and final setting time, porosity, density, and mechanical parameters were identified based on chemical and phase composition, particle size, specific surface, and morphology of diatomaceous particles. Nevertheless, the researched mineral admixtures yielded a high strength activity index (92.9% to 113.6%), evinced their pozzolanic activity. Three fundamental factors were identified that affect diatomaceous earth's contribution to the mechanical strength of cement blends. These are the filler effect, the pertinent acceleration of OPC hydration, and the pozzolanic reaction of diatomite with Portland cement hydrates. The optimum replacement level of ordinary Portland cement by diatomaceous earth to give maximum long-term strength enhancement is about 10 wt.%., but it might be further enhanced based on the properties of pozzolan.

4.
Materials (Basel) ; 15(5)2022 Mar 03.
Article in English | MEDLINE | ID: mdl-35269126

ABSTRACT

The presented research is focused on the development and testing of the magnesium potassium phosphate cement-based materials (MKPC-based). Firstly, the fresh state properties of the pastes consisting of dead burned magnesia powder, potassium dihydrogen phosphate, setting retarder borax applied in the range of 0-10 wt.%, and batch water were investigated. The aim of testing was to characterize the hydration process in dependence on the borax content. The properties of raw MgO powder were described by chemical composition and particle size distribution. The properties tested in fresh state included shear stress (viscosity), Young's modulus of elasticity, and temperature; their time dependence was observed. The measurements started immediately after the mixing process. At the age of 14 days, basic structural and mechanical properties of the hardened pastes were obtained. The mixture with 5 wt.% of borax proved to be the most advantageous in terms of setting time, sample integrity, and mechanical strength; therefore, it was chosen as the binder for the following part of the study-MKPC-based mortar development. In the next step, the MKPC paste containing 5 wt.% of borax was supplemented by silica sand aggregate, and the resulting material was marked as a reference. Subsequently, three other mixtures were derived by replacing 100% of quartz sand by lightweight aggregate; namely by expanded glass aggregate, waste rubber from tires, and combination of both in ratio 1:1. The aggregates were characterized by chemical composition (except for the rubber granulate), and loose and compacted powder density. For the resulting hardened composites, basic structural, hygric, strength, and thermal parameters were investigated. The use of lightweight aggregates brought in a considerable decrease in heat transport parameters and low water permeability while maintaining sufficient strength. The favorable obtained material properties are underscored by the fact that magnesia-phosphate is considered to be a low-carbon binder. The combination of magnesia-phosphate binder and recycled aggregate provides a satisfying, environmentally friendly, and thermally efficient alternative to traditional Portland cement-based materials.

5.
Materials (Basel) ; 15(2)2022 Jan 14.
Article in English | MEDLINE | ID: mdl-35057321

ABSTRACT

In this study, the combined effect of graphene oxide (GO) and oxidized multi-walled carbon nanotubes (OMWCNTs) on material properties of the magnesium oxychloride (MOC) phase 5 was analyzed. The selected carbon-based nanoadditives were used in small content in order to obtain higher values of mechanical parameters and higher water resistance while maintaining acceptable price of the final composites. Two sets of samples containing either 0.1 wt. % or 0.2 wt. % of both nanoadditives were prepared, in addition to a set of reference samples without additives. Samples were characterized by X-ray diffraction, scanning electron microscopy, Fourier-transform infrared spectroscopy, and energy dispersive spectroscopy, which were used to obtain the basic information on the phase and chemical composition, as well as the microstructure and morphology. Basic macro- and micro-structural parameters were studied in order to determine the effect of the nanoadditives on the open porosity, bulk and specific density. In addition, the mechanical, hygric and thermal parameters of the prepared nano-doped composites were acquired and compared to the reference sample. An enhancement of all the mentioned types of parameters was observed. This can be assigned to the drop in porosity when GO and OMWCNTs were used. This research shows a pathway of increasing the water resistance of MOC-based composites, which is an important step in the development of the new generation of construction materials.

6.
Materials (Basel) ; 14(16)2021 Aug 15.
Article in English | MEDLINE | ID: mdl-34443099

ABSTRACT

The studies focusing on magnesium oxychloride cement (MOC) composites have recently become fairly widespread because of MOC's excellent mechanical properties and environmental sustainability. Numerous fillers, admixtures and nano-dopants were studied in order to improve the overall performance of MOC-based derivatives. Some of them exhibited specific flaws, such as a tendency to aggregate, increase in porosity, aeration of the composite matrix, depreciation in water resistance and mechanical strength, etc. In this manuscript, MOC-based composites doped by multi-walled carbon nanotubes (MWCNTs) are designed and tested. In order to modify the final properties of composites, diatomite was admixed as partial substitution of MgO, which was used in the composition of the researched material in excess, i.e., the majority of MgO constituted part of MOC and the rest served as fine filler. The composites were subjected to the broad experimental campaign that covered SEM (scanning electron microscopy), EDS (energy dispersive spectroscopy), HR-TEM (high-resolution transmission electron microscopy), XRD (X-ray diffraction), OM (optical microscopy) and STA-MS (simultaneous thermal analysis with mass spectroscopy). For 28 days hardened samples, macrostructural and microstructural parameters, mechanical properties, hygric and thermal characteristics were experimentally assessed. The incorporation of MWCNTs and diatomite resulted in the significant enhancement of composites' compactness, mechanical strength and stiffness and reduction in water absorption and rate of water imbibition. The thermal properties of the enriched MOC composites yielded interesting values and provided information for future modification of thermal performance of MOC composites with respect to their specific use in practice, e.g., in passive moderation of indoor climate. The combination of MWCNTs and diatomite represents a valuable modification of the MOC matrix and can be further exploited in the design and development of advanced building materials and components.

7.
Materials (Basel) ; 14(13)2021 Jul 05.
Article in English | MEDLINE | ID: mdl-34279331

ABSTRACT

Rendering mortars with lightweight zeolite aggregates were designed and tested. The effect of the type of binder used was also researched. For the hardened mortars, macrostructural parameters, mechanical characteristics, hygric and thermal properties were assessed. Specific attention was paid to the analysis of the salt crystallization resistance of the developed rendering mortars. Quartz sand was fully replaced in the composition of mortars with zeolite gave materials with low density, high porosity, sufficient mechanical strength, high water vapor permeability and high water absorption coefficient, which are technical parameters required for repair rendering mortars as prescribed in the WTA directive 2-9-04/D and EN 998-1. Moreover, the zeolite enhanced mortars exhibit good thermal insulation performance and high sorption capacity. The examined rendering mortars were found to be well durable against salt crystallization, which supports their applicability in salt-laden masonry. Based on the compatibility of the repair materials with those originally used, the lime and natural hydraulic lime zeolite mortars can be used as rendering mortars for the repair of historical and heritage buildings. The cement-lime zeolite render is applicable for repair purposes only in the case of the renewal of masonry in which Portland cement-based materials were originally used.

8.
Materials (Basel) ; 14(10)2021 May 17.
Article in English | MEDLINE | ID: mdl-34067857

ABSTRACT

Three types of lightweight plasters for building repair were prepared and tested. The composition of plasters was designed in respect to their compatibility with materials used in the past in historical masonry. For the hardened plasters, detailed testing of microstructural and macrostructural parameters was realized together with the broad experimental campaign focused on the assessment of mechanical, hygric, and thermal properties. As the researched plasters should find use in salt-laden masonry, specific attention was paid to the testing of their durability against salt crystallization. The mechanical resistance, porosity, water vapor transmission properties, and water transport parameters of all the researched plasters safely met criteria of WTA directive 2-9-04/D and standard EN 998-1 imposed on repair mortars. Moreover, the tested materials were ranked as lightweight plasters and due to their low thermal conductivity they can be used for the improvement of thermal performance of repaired masonry. The salt crystallization test caused little or no damage of the plasters, which was due to their high porosity that provided free space for salt crystallization. The developed plasters can be recommended for application in repair of damp and salt masonry and due to their compatible composition also in historical, culture heritage buildings. The added value of plasters is also their good thermal insulation performance.

9.
Materials (Basel) ; 14(6)2021 Mar 16.
Article in English | MEDLINE | ID: mdl-33809728

ABSTRACT

The ongoing tendency to create environmentally friendly building materials is nowadays connected with the use of reactive magnesia-based composites. The aim of the presented research was to develop an ecologically sustainable composite material based on MOC (magnesium oxychloride cement) with excellent mechanical, chemical, and physical properties. The effect of the preparation procedure of MOC pastes doped with graphene nanoplatelets on their fresh and hardened properties was researched. One-step and two-step homogenization techniques were proposed as prospective tools for the production of MOC-based composites of advanced parameters. The conducted experiments and analyses covered X-ray fluorescence, scanning electron microscopy, energy-dispersive spectroscopy, high-resolution transmission electron microscopy, sorption analysis, X-ray diffraction, and optical microscopy. The viscosity of the fresh mixtures was monitored using a rotational viscometer. For the hardened composites, macro- and micro-structural parameters were measured together with the mechanical parameters. These tests were performed after 7 days and 14 days. The use of a carbon-based nanoadditive led to a significant drop in porosity, thus densifying the MOC matrix. Accordingly, the mechanical resistance was greatly improved by graphene nanoplatelets. The two-step homogenization procedure positively affected all researched functional parameters of the developed composites (e.g., the compressive strength increase of approximately 54% after 7 days, and 37% after 14 days, respectively) and can be recommended for the preparation of advanced functional materials reinforced with graphene.

10.
Materials (Basel) ; 14(5)2021 Feb 26.
Article in English | MEDLINE | ID: mdl-33652947

ABSTRACT

Lightweight Sorel's cement composites doped with coal fly ash were produced and tested. Commercially available foam granulate was used as lightening aggregate. For comparison, reference composites made of magnesium oxychloride cement (MOC) and quartz sand were tested as well. The performed experiments included X-ray diffraction, X-ray fluorescence, scanning electron microscopy, light microscopy, and energy dispersive spectroscopy analyses. The macro- and microstructural parameters, mechanical resistance, stiffness, hygric, and thermal parameters of the 28-days matured composites were also researched. The combined use of foam glass and fly ash enabled to get a material of low weight, high porosity, sufficient strength and stiffness, low water imbibition, and greatly improved thermal insulation performance. The developed lightweight composites can be considered as further step in the design and production of alternative and sustainable materials for construction industry.

11.
Materials (Basel) ; 14(3)2021 Jan 20.
Article in English | MEDLINE | ID: mdl-33498565

ABSTRACT

In this contribution, composite materials based on magnesium oxychloride cement (MOC) with multi-walled carbon nanotubes (MWCNTs) used as an additive were prepared and characterized. The prepared composites contained 0.5 and 1 wt.% of MWCNTs, and these samples were compared with the pure MOC Phase 5 reference. The composites were characterized using a broad spectrum of analytical methods to determine the phase and chemical composition, morphology, and thermal behavior. In addition, the basic structural parameters, pore size distribution, mechanical strength, stiffness, and hygrothermal performance of the composites, aged 14 days, were also the subject of investigation. The MWCNT-doped composites showed high compactness, increased mechanical resistance, stiffness, and water resistance, which is crucial for their application in the construction industry and their future use in the design and development of alternative building products.

12.
Materials (Basel) ; 13(24)2020 Dec 14.
Article in English | MEDLINE | ID: mdl-33327587

ABSTRACT

A high-performance magnesium oxychloride cement (MOC) composite composed of silica sand, diatomite powder, and doped with graphene nanoplatelets was prepared and characterized. Diatomite was used as a 10 vol.% replacement for silica sand. The dosage of graphene was 0.5 wt.% of the sum of the MgO and MgCl2·6H2O masses. The broad product characterization included high-resolution transmission electron microscopy, X-ray diffraction, X-ray fluorescence, scanning electron microscopy and energy dispersive spectroscopy analyses. The macrostructural parameters, pore size distribution, mechanical resistance, stiffness, hygric and thermal parameters of the composites matured for 28-days were also the subject of investigation. The combination of diatomite and graphene nanoplatelets greatly reduced the porosity and average pore size in comparison with the reference material composed of MOC and silica sand. In the developed composites, well stable and mechanically resistant phase 5 was the only precipitated compound. Therefore, the developed composite shows high compactness, strength, and low water imbibition which ensure high application potential of this novel type of material in the construction industry.

13.
Materials (Basel) ; 13(21)2020 Oct 28.
Article in English | MEDLINE | ID: mdl-33126738

ABSTRACT

In this paper, light burned magnesia dispersed in the magnesium chloride solution was used for the manufacturing of magnesium oxychloride cement-based composites which were lightened by granulated scrap tires and expanded glass. In a reference composite, silica sand was used only as filler. In the lightened materials, granulated shredded tires were used as 100%, 90%, 80%, and 70% silica sand volumetric replacement. The rest was compensated by the addition of expanded glass granules. The filling materials were characterized by particle size distribution, specific density, dry powder density, and thermal properties that were analyzed for both loose and compacted aggregates. For the hardened air-cured samples, macrostructural parameters, mechanical properties, and hygric and thermal parameters were investigated. Specific attention was paid to the penetration of water and water-damage, which were considered as crucial durability parameters. Therefore, the compressive strength of samples retained after immersion for 24 h in water was tested and the water resistance coefficient was assessed. The use of processed waste rubber and expanded glass granulate enabled the development of lightweight materials with sufficient mechanical strength and stiffness, low permeability for water, enhanced thermal insulation properties, and durability in contact with water. These properties make the produced composites an interesting alternative to Portland cement-based materials. Moreover, the use of low-carbon binder and waste tires can be considered as an eco-efficient added value of these products which could improve the environmental impact of the construction industry.

14.
Materials (Basel) ; 13(11)2020 Jun 03.
Article in English | MEDLINE | ID: mdl-32503182

ABSTRACT

Worldwide, Portland cement-based materials are the most commonly used construction materials. As the Portland cement industry negatively affects the environment due to the excessive emission of carbon dioxide and depletion of natural resources, new alternative materials are being searched. Therefore, the goal of the paper was to design and develop eco-friendly, low-cost, and sustainable magnesium oxychloride cement (MOC)-based building material with a low carbon footprint, which is characterized by reduced porosity, high mechanical resistance, and durability in terms of water damage. To make new material eco-efficient and functional, silica sand which was used in the composition of the control composite mixture was partially replaced with coal fly ash (FA), a byproduct of coal combustion. The chemical and mineralogical composition, morphology, and particle morphology of FA were characterized. For silica sand, FA, and MgO, specific density, loose bulk density, and particle size distribution were measured. Additionally, Blaine specific surface was for FA and MgO powder assessed. The workability of fresh mixtures was characterized by spread diameter. For the hardened MOC composites, basic structural, mechanical, hygric, and thermal properties were measured. Moreover, the phase composition of precipitated MOC phases and their thermal stability were investigated for MOC-FA pastes. The use of FA led to the great decrease in porosity and pore size compared to the control material with silica sand as only filler which was in agreement with the workability of fresh composite mixtures. The compressive strength increased with the replacement of silica sand with FA. On the contrary, the flexural strength slightly decreased with silica sand substitution ratio. It clearly proved the assumption of the filler function of FA, whereas its assumed reactivity with MOC cement components was not proven. The water transport and storage were significantly reduced by the use of FA in composites, which greatly improved their resistance against moisture damage. The heat transport and storage parameters were only slightly affected by FA incorporation in composite mixtures.

15.
Materials (Basel) ; 13(3)2020 Feb 07.
Article in English | MEDLINE | ID: mdl-32046098

ABSTRACT

In this paper, magnesium oxychloride cement with stoichiometry 3Mg(OH)2∙MgCl2∙8H2O (MOC 3-1-8) was prepared and characterized. The phase composition and kinetics of formation were studied by X-ray diffraction (XRD) and Rietveld analysis of obtained diffractograms. The chemical composition was analyzed using X-ray fluorescence (XRF) and energy dispersive spectroscopy (EDS). Furthermore, scanning electron microscopy (SEM) was used to study morphology, and Fourier Transform Infrared (FT-IR) spectroscopy was also used for the analysis of the prepared sample. In addition, thermal stability was tested using simultaneous thermal analysis (STA) combined with mass spectroscopy (MS). The obtained data gave evidence of the fast formation of MOC 3-1-8, which started to precipitate rapidly. As the length of the time of ripening increased, the amount of MgO decreased, while the amount of MOC 3-1-8 increased. The fast formation of the MOC 3-1-8 phase at an ambient temperature is important for its application in the production of low-energy construction materials, which corresponds with the challenges of a sustainable building industry.

16.
Materials (Basel) ; 12(21)2019 Oct 30.
Article in English | MEDLINE | ID: mdl-31671520

ABSTRACT

In this paper, crushed lava granulate was used as full silica sand replacement in composition of repair mortars based on hydrated lime, natural hydraulic lime, or cement-lime binder. Lava granules were analyzed by X-ray fluorescence analysis (XRF), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Particle size distribution of both silica and lava aggregates was assessed using standard sieve analysis. Hygrothermal function of the developed lightweight materials was characterized by the measurement of complete set of hygric, thermal, and structural parameters of the hardened mortar samples that were tested for both 28 days and 90 days cured specimens. As the repair mortars must also meet requirements on mechanical performance, their compressive strength, flexural strength, and dynamic Young's modulus were tested. The newly developed mortars composed of lava aggregate and hydrated lime or natural hydraulic lime met technical, functional, compatibility, and performance criteria on masonry and rendering materials, and were found well applicable for repair of historically valuable buildings.

17.
Materials (Basel) ; 12(14)2019 Jul 10.
Article in English | MEDLINE | ID: mdl-31295888

ABSTRACT

Mechanically-activated wood-based biomass ash (WBA) was studied as a potential active admixture for design of a novel lime-pozzolan-based mortar for renovation purposes. The replacement ratio of lime hydrate in a mortar mix composition was 5%, 10%, and 15% by mass. The water/binder ratio and the sand/binder ratio were kept constant for all examined mortar mixes. Both binder constituents were characterized by their powder density, specific density, BET (Brunauer-Emmett-Teller), and Blaine specific surfaces. Their chemical composition was measured by X-ray fluorescence analysis (XRF) and mineralogical analysis was performed using X-ray diffraction (XRD). Morphology of WBA was investigated by scanning electron microscopy (SEM) and element mapping was performed using an energy dispersive spectroscopy (EDS) analyzer. The pozzolanic activity of WBA was tested by the Chapelle test and assessment of the Portlandite content used simultaneous thermal analysis (STA). For the hardened mortar samples, a complete set of structural, mechanical, hygric, and thermal parameters was experimentally determined. The mortars with WBA admixing yielded similar or better functional properties than those obtained for traditional pure lime-based plaster, pointing to their presumed application as rendering and walling renovation mortars. As the Chapelle test, STA, and mechanical test proved high pozzolanity of WBA, it was classified as an alternative eco-efficient low-cost pozzolan for use in lime blend-based building materials. The savings in CO2 emissions and energy by the use of WBA as a partial lime hydrate substitute in mortar composition were also highly appreciated with respect to the sustainability of the construction industry.

18.
Materials (Basel) ; 12(10)2019 May 21.
Article in English | MEDLINE | ID: mdl-31117225

ABSTRACT

Two waste fired brick powders coming from brick factories located in Argentine and Czech Republic were examined as alternative mineral admixtures for the production of blended cements. In pastes composition, local Portland cements (Argentine and Czech) were substituted with 8-40%, by mass, with powdered ceramic waste. For the ceramic waste-Portland cement system, workability, the heat released, pozzolanity, specific density, compressive strength, hydrated phases, porosity, and pore size distribution were tested. The relevance of the dilution effect, filler effect, and pozzolanic activity was analyzed to describe the general behavior of the pozzolan/cement system. The properties and performance of cement blends made with finely ground brick powder depended on the composition of ceramic waste and its reactivity, the plain cement used, and the replacement level. Results showed that the initial mini-slump was not affected by a low ceramic waste replacement (8% and 16%), and then it was decreased with an increase in the ceramic waste content. Brick powder behaved as a filler at early ages, but when the hydration proceeded, its pozzolanic activity consumed partially the calcium hydroxide and promoted the formation of hydrated calcium aluminates depending on the age and present carbonates. Finally, blended cements with fired brick powder had low compressive strength at early ages but comparable strength-class at later age.

19.
Materials (Basel) ; 12(6)2019 Mar 26.
Article in English | MEDLINE | ID: mdl-30917584

ABSTRACT

The goal of the paper was development and testing of a novel type of ternary blended binder based on lime hydrate, metakaolin, and biomass ash that was studied as a binding material for production of lightweight mortar for renovation purposes. The biomass ash used as one of binder components was coming from wood chips ash combustion in a biomass heating plant. The raw ash was mechanically activated by grinding. In mortar composition, wood chips ash and metakaolin were used as partial substitutes of lime hydrate. Silica sand of particle size fraction 0⁻2 mm was mixed from three normalized sand fractions. For the evaluation of the effect of biomass ash and metakaolin incorporation in mortar mix on material properties, reference lime mortar was tested as well. Among the basic physical characterization of biomass ash, metakaolin and lime hydrate, specific density, specific surface, and particle size distribution were assessed. Their chemical composition was measured by X-Ray fluorescence analysis (XRF), morphology was examined using scanning electron microscopy (SEM), elements mapping was performed using energy dispersive spectroscopy (EDS) analyser, and mineralogical composition was tested using X-Ray diffraction (XRD). For the developed mortars, set of structural, mechanical, hygric, and thermal properties was assessed. The mortars with ternary blended binder exhibited improved mechanical resistance, lower thermal conductivity, and increased water vapor permeability compared to the reference lime mortar. Based on good functional performance of the produced mortar, the tested biomass ash could potentially represent a novel sustainable alternative to other pozzolans commonly used in construction industry. Moreover, reuse of biomass ash in production of building materials is highly beneficial both from the environmental and economic reasons especially taking into account circular economy principles. The ternary blended binder examined in this paper can find use in both rendering and walling repair mortars meeting the requirements of culture heritage authorities and technical standards.

20.
Waste Manag ; 80: 89-100, 2018 Oct.
Article in English | MEDLINE | ID: mdl-30455031

ABSTRACT

Wood chips ash coming from biomass heating plant is studied as an eco-friendly mineral admixture in mortar mix design. The raw material was mechanically activated by milling in a vibratory disc mill to a degree of fineness comparable to cement. For the mortars with ash dosage, basic physical, mechanical, hygric, and thermal properties is accessed. The mortars with partial Portland cement replacement with wood chips ash exhibited good functional properties for all studied ash dosages. With increasing amount of the ash used, the average pore diameter decreased due to the partial filler effect of WCHA in mortar mix. The strength activity index was very high for all studied mortars and gave evidence of the wood chips ash pozzolanity. The pozzolan effectiveness coefficient varied from 1.52 to 0.59, which proved the pozzolanity of the studied ash and synergic effects in the Portland cement-ash-water system. The results of leaching tests showed, the chlorides contained in ash were safely immobilized in the silicate matrix. The environmental evaluation revealed decrease in both carbon dioxide production and energy consumption by the use of wood chips ash in mortar mix. For the mortar with 20% substitution of Portland cement with wood chips ash, it represents 15% of CO2 and 16% of energy, as compared with the reference mortar mix. As the developed mortars possess good functional and environmental parameters the analyzed wood chips ash can be considered as an eco-efficient low-cost alternative to other pozzolans for production of blended binders.


Subject(s)
Coal Ash , Wood , Biomass , Construction Materials , Minerals
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