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Catalytic conversion of methanol/ethanol to isobutanol--a highly selective route to an advanced biofuel.
Wingad, Richard L; Bergström, Emilie J E; Everett, Matthew; Pellow, Katy J; Wass, Duncan F.
Chem Commun (Camb) ; 52(29): 5202-4, 2016 Apr 14.
Article in English | MEDLINE | ID: mdl-26998669

ABSTRACT

Catalysts based on ruthenium diphosphine complexes convert methanol/ethanol mixtures to the advanced biofuel isobutanol, with extremely high selectivity (>99%) at good (>75%) conversion via a Guerbet-type mechanism.


Subject(s)
Biofuels/analysis , Butanols/chemistry , Ethanol/chemistry , Methanol/chemistry , Phosphines/chemistry , Ruthenium/chemistry , Catalysis , Coordination Complexes/chemistry
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