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Chem Commun (Camb)
; 2024 Jul 04.
Article
in English
| MEDLINE
| ID: mdl-38962853
ABSTRACT
A porous three-component hydrogen bonded framework, 1â biphenâ TP, was prepared from a tetra-amidinium component (14+) and two different dianions, benzene-1,4-dicarboxylate (terephthalate, TP2-) and biphenyl-4,4'-dicarboxylate (biphen2-). Interestingly, when the framework was prepared in ethanol/water, 1â biphenâ TP forms even when an excess of either dicarboxylate is present. However, when only water is used as solvent, only two-component frameworks are formed.