The magmatic evolution of South-East Crater (Mt. Etna) during the February-April 2021 sequence of lava fountains from a mineral chemistry perspective.

The South-East Crater (SEC) at Mt. Etna started a period of lava fountaining in December 2020, producing over 60 paroxysms until February 2022. The activity had an intense sequence from February 16 to April 1, 2021, totaling 17 paroxysmal events separated by repose times varying from 1 to 7 days. The eruptive sequence was extensively monitored, providing a unique opportunity to relate the chemistry and texture of the erupted products to eruption dynamics. We investigate the temporal evolution of the magmatic system through this eruptive sequence by quantifying variations in the composition and texture of clinopyroxene. Clinopyroxene major element transects across crystals from five representative lava fountains allow us to determine the relative proportions of deep versus shallow-stored magmas that fed these events. We use hierarchical clustering (HC), an unsupervised machine learning technique, to objectively identify clinopyroxene compositional clusters and their variations during this intense eruptive phase. Our results show that variations of monitoring parameters and eruption intensity are expressed in the mineral record both as changes in cluster proportions and the chemical complexity of single crystals. We also apply random forest thermobarometry to relate each cluster to P-T conditions of formation. We suggest that the February-April 2021 eruptive sequence was sustained by the injection of a hotter and deeper magma into a storage area at 1-3 kbar, where it mixed with a slightly more evolved magma. The February 28 episode emitted the most mafic magma, in association with the highest mean lava fountain height and highest time-averaged discharge rate, which make it the peak of the analyzed eruptive interval. Our results show that after this episode, the deep magma supply decreased and the erupted magma become gradually more chemically evolved, with a lower time-average discharge rate and fountain height. We propose this approach as a means to rapidly, objectively, and effectively link petrological and geophysical/geochemical monitoring during ongoing eruptions. We anticipate that the systematic application of this approach will serve to shed light on the magmatic processes controlling the evolution of ongoing eruptions. Supplementary Information: The online version contains supplementary material available at 10.1007/s00445-023-01643-2.

Shallow conduit dynamics fuel the unexpected paroxysms of Stromboli volcano during the summer 2019.

Open conduit basaltic volcanoes can be potentially hazardous as the eruptive activity may turn suddenly from a steady state to highly explosive. Unexpected changes in explosion intensity are recurrent at Stromboli volcano, where major explosions and large-scale paroxysms sometimes break off the ordinary, Strombolian activity with little or no warning. Two powerful paroxysmal eruptions took place at Stromboli volcano during the summer 2019, causing widespread fires, consistent damages across the island, injuries and one fatality. Prediction of similar events is really challenging for the modern volcanology, though models propaedeutic to early-warning monitoring systems are not properly assessed yet in many volcanoes worldwide. Here, we present a multi-parametric study that combines petrological and geophysical data to investigate processes generating the two paroxysms. The time information derived by Li enrichments in plagioclase crystals correlates with tilt time series derived by seismometers installed on the island, highlighting the dominant role of shallow conduit processes in triggering the 2019 paroxysmal activity. Our dataset conceives a mechanism of gas slug formation and fast upward migration that finally triggered the eruptions in very limited times. The proposed model questions our capability to forecast such kind of paroxysms in times that are rapid enough to allow mitigation of the associated risk.

Gradual and selective trace-element enrichment in slab-released fluids at sub-arc depths.

The geochemical signature of magmas generated at convergent margins greatly depends on the nature of fluids and melts released during subduction. While major- and trace-elements transport capacity of ultrahigh pressure (UHP) hydrous-silicate melts has been investigated, little is known about solute enrichment and fractionation in UHP (>3.5-4 GPa) solute-rich aqueous fluids released along colder geothermal gradients. Here, we performed in situ LA-ICP-MS trace-element analyses on selected UHP prograde-to-peak fluid inclusions trapped in a kyanite-bearing quartzite from Sulu (China). The alkali-aluminosilicate-rich aqueous fluid released from the meta-sediments by dehydration reactions is enriched in LILE, U, Th, Sr, and REE. Inclusions trapped at increasing temperature (and pressure) preserve a gradual and selective trace-element enrichment resulting from the progressive dissolution of phengite and carbonate and the partial dissolution of allanite/monazite. We show that, at the investigated P-T conditions, aqueous fluids generated by dissolution of volatile-bearing minerals fractionate trace-element distinctly from hydrous-silicate melts, regardless of the source lithology. The orogenic/post-orogenic magmas generated in a mantle enriched by metasomatic processes involving either solute-rich aqueous fluids or hydrous-silicate melts released by the slab at UHP conditions can preserve evidence of the nature of these agents.

First marine cryptotephra in Antarctica found in sediments of the western Ross Sea correlates with englacial tephras and climate records.

We report the discovery of an important new cryptotephra within marine sediments close to Cape Hallett (northern Victoria Land), in the western Ross Sea, Antarctica. The cryptotephra is fully characterized for its texture, mineralogy and major- and trace-element data obtained on single glass shards. On the basis of geochemical composition, the cryptotephra is unequivocally correlated with the proximal deposits of an explosive eruption of the poorly known Mount Rittmann volcano, situated in northern Victoria Land. The cryptotephra is also correlated with a widespread tephra layer, which was erupted in 1254 C.E. and is present in numerous ice-cores and blue ice fields across East and West Antarctica. The characteristics of the tephra indicate that it was produced by a prolonged, moderate energy, mostly hydromagmatic eruption. This is the first time that a cryptotephra has been identified in marine sediments of the Ross Sea and in ice cores. It provides an important new and widespread stratigraphical datum with which the continental cryosphere and marine sedimentological records in Antarctica can be correlated. Moreover, from a purely volcanological point of view, the discovery further confirms the occurrence of a long-lasting, significant explosive eruption from Mount Rittmann in historical times that produced abundant widely dispersed fine ash. The study also highlights the inadequacy of current hazard assessments for poorly known volcanoes such as Mount Rittmann, located at high southern latitudes.

Determination of changes in the concentration and distribution of elements within olive drupes (cv. Leccino) from Se biofortified plants, using laser ablation inductively coupled plasma mass spectrometry.

BACKGROUND: Biofortification of food crops has been used to increase the intake of Se in the human diet, even though this may change the concentration of other elements and modify the nutritional properties of the enriched food. Selenium biofortification programs should include routine assessment of the overall mineral composition of enriched plants. RESULTS: Laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) was used for the assessment of mineral composition of table olives. Olive trees were fertilized with sodium selenate before flowering. At harvest, the edible parts of drupes proved to be significantly enriched in Se, delivering 6.1 µg g-1 (39% of the RDA for five olives). Such enrichment was followed by significant changes in the concentrations of B, Mg, K, Cr, Mn, Fe and Cu in edible parts, which are discussed for their impact on food quality. CONCLUSION: The biofortification of olive plants has allowed the enrichment of fruits with selenium. Enrichment with selenium has caused an increase in the concentration of other elements, which can change the nutritional quality of the drupes. The analytical technique used well as a valuable tool for routinely determining the chemical composition of all fruit parts. © 2018 Society of Chemical Industry.

The characterization of natural gemstones using non-invasive FT-IR spectroscopy: New data on tourmalines.

Fourteen samples of tourmaline from the Real Museo Mineralogico of Federico II University (Naples) have been characterized through multi-methodological investigations (EMPA-WDS, SEM-EDS, LA-ICP-MS, and FT-IR spectroscopy). The samples show different size, morphology and color, and are often associated with other minerals. Data on major and minor elements allowed to identify and classify tourmalines as follows: elbaites, tsilaisite, schorl, dravites, uvites and rossmanite. Non-invasive, non-destructive FT-IR and in-situ analyses were carried out on the same samples to validate this chemically-based identification and classification. The results of this research show that a complete characterization of this mineral species, usually time-consuming and expensive, can be successfully achieved through non-destructive FT-IR technique, thus representing a reliable tool for a fast classification extremely useful to plan further analytical strategies, as well as to support gemological appraisals.

Enhancement of eruption explosivity by heterogeneous bubble nucleation triggered by magma mingling.

We present new evidence that shows magma mingling can be a key process during highly explosive eruptions. Using fractal analysis of the size distribution of trachybasaltic fragments found on the inner walls of bubbles in trachytic pumices, we show that the more mafic component underwent fracturing during quenching against the trachyte. We propose a new mechanism for how this magmatic interaction at depth triggered rapid heterogeneous bubble nucleation and growth and could have enhanced eruption explosivity. We argue that the data support a further, and hitherto unreported contribution of magma mingling to highly explosive eruptions. This has implications for hazard assessment for those volcanoes in which evidence of magma mingling exists.

Concentration variance decay during magma mixing: a volcanic chronometer.

The mixing of magmas is a common phenomenon in explosive eruptions. Concentration variance is a useful metric of this process and its decay (CVD) with time is an inevitable consequence during the progress of magma mixing. In order to calibrate this petrological/volcanological clock we have performed a time-series of high temperature experiments of magma mixing. The results of these experiments demonstrate that compositional variance decays exponentially with time. With this calibration the CVD rate (CVD-R) becomes a new geochronometer for the time lapse from initiation of mixing to eruption. The resultant novel technique is fully independent of the typically unknown advective history of mixing - a notorious uncertainty which plagues the application of many diffusional analyses of magmatic history. Using the calibrated CVD-R technique we have obtained mingling-to-eruption times for three explosive volcanic eruptions from Campi Flegrei (Italy) in the range of tens of minutes. These in turn imply ascent velocities of 5-8 meters per second. We anticipate the routine application of the CVD-R geochronometer to the eruptive products of active volcanoes in future in order to constrain typical "mixing to eruption" time lapses such that monitoring activities can be targeted at relevant timescales and signals during volcanic unrest.