ABSTRACT
With the increased demand for biobased epoxy thermosets as an alternative to petroleum-based materials in various fields, developing environment-friendly and high-performance natural fiber-biobased epoxy nanocomposites is crucial for industrial applications. Herein, an environment-friendly nanocomposite is reported by introducing cellulose nanofiber (CNF) in situ interaction with lignin-derived vanillin epoxy (VE) monomer and 4, 4´-diaminodiphenyl methane (DDM) hardener that serves as a multifunctional platform. The CNF-VE nanocomposite is fabricated by simply dispersing the CNF suspension to the VE and DDM hardener solution through the in-situ reaction, and its mechanical properties and thermal insulation behavior, wettability, chemical resistance, and optical properties are evaluated with the CNF weight percent variation. The well-dispersed CNF-VE nanocomposite exhibited high tensile strength (â¼127.78 ± 3.99 MPa) and strain-at-break (â¼16.49 ± 0.61 %), haziness (â¼50 %) and UV-shielding properties. The in situ loading of CNF forms covalent crosslinking with the VE and favors improving the mechanical properties along with the homogeneous dispersion of CNF. The CNF-VE nanocomposite also shows lower thermal conductivity (0.26 Wm-1K-1) than glass. The environment-friendly and high-performance nanocomposite provides multiple platforms and can be used for building materials.
ABSTRACT
Single-use plastics such as straws have caused intricate environmental challenges since they are not readily assimilated into nature at the end of life. Paper straws, on the contrary, become soggy and collapse in drinks resulting in an obnoxious user experience. Here, all-natural, biocompatible, degradable straws and thermoset films are engineered by integrating economical natural resources-lignin and citric acid-into edible starch and poly(vinyl alcohol), making them the casting slurry. The slurries were cast on a glass substrate, partially dried, and rolled on a Teflon rod to fabricate the straws. The straws are perfectly adhered at the edges by the strong hydrogen bonds from the crosslinker-citric acid-during drying, thus eliminating the need for adhesives and binders. Further, curing the straws and films in a vacuum oven at 180 °C results in enhanced hydrostability and endows the films with excellent tensile strength, toughness, and ultraviolet radiation shielding. The functionality of the straws and films surpassed paper and plastic straws, making them quintessential candidates for all-natural sustainable development.
ABSTRACT
This paper reports on multiple stage bleaching and its effect on the mechanical and swelling properties of compressed wood (CW). The natural wood specimen was bleached with NaClO2 in five steps and three hot-pressing conditions. Their effects were investigated in morphologies: lignin content, alpha-cellulose content, compression ratio, mechanical properties, swelling and, water contact angle. After compression, the wood specimens became dense and the most porous structures collapsed. The lignin content decreased as the bleaching steps progressed, and the highest alpha-cellulose content was observed at the third bleaching step. This CW showed the best mechanical properties: bending strength was 240.1 ± 35.7 MPa, and Young's modulus was 23.08 ± 0.89 Gpa. The CW swelling decreased as the bleaching step progressed, and was associated with the density decrease and the compression ratio increase with the bleaching step. The B3 is an optimum bleaching step that accounts for the best mechanical properties, which might be associated with the highest alpha-cellulose content.
ABSTRACT
A chitosan-based nanocomposite film with tannic acid (TA) as a cross-linker and titanium dioxide nanoparticles (TiO2) as a reinforcing agent was developed with a solution casting technique. TA and TiO2 are biocompatible with chitosan, and this paper studied the synergistic effect of the cross-linker and the reinforcing agent. The addition of TA enhanced the ultraviolet blocking and mechanical properties of the chitosan-based nanocomposite film. The reinforcement of TiO2 in chitosan/TA further improved the nanocomposite film's mechanical properties compared to the neat chitosan or chitosan/TA film. The thermal stability of the chitosan-based nanocomposite film was slightly enhanced, whereas the swelling ratio decreased. Interestingly, its water vapor barrier property was also significantly increased. The developed chitosan-based nanocomposite film showed potent antioxidant activity, and it is promising for active food packaging.
ABSTRACT
This paper reports that, by simply blending two heterogeneous polysaccharide nanofibers, namely chitosan nanofiber (ChNF) and cellulose nanofiber (CNF), a ChNF-CNF composite was prepared, which exhibited improved mechanical properties and antioxidant activity. ChNF was isolated using the aqueous counter collision (ACC) method, while CNF was isolated using the combination of TEMPO oxidation and the ACC method, which resulted in smaller size of CNF than that of ChNF. The prepared composite was characterized in terms of morphologies, FT-IR, UV visible, thermal stability, mechanical properties, hygroscopic behaviors, and antioxidant activity. The composite was flexible enough to be bent without cracking. Better UV-light protection was shown at higher content of ChNF in the composite. The high ChNF content showed the highest antioxidant activity in the composite. It is the first time that a simple combination of ChNF-CNF composites fabrication showed good mechanical properties and antioxidant activities. In this study, the reinforcement effect of the composite was addressed. The ChNF-CNF composite is promising for active food packaging application.
