ABSTRACT
In this study, the effect of salinity on the removal of organic matter and nitrogen concentrations in bioreactor was investigated using a hybrid bench scale down-flow hanging sponge (DHS) system for 145 days of operation. The reactor had three identical sections that were filled to 30% volume with Bio-Bact to serve as attached media. The DHS reactor was fed with domestic wastewater that was mixed with increasing concentration of sodium chloride from 0.5 to 3.0% stepwise. The influent and effluent concentrations of BOD5, CODCr, NH4+-N, and TN were analyzed to evaluate the performance of the DHS reactor during the operational period. Results indicate that when salinity was increased from 0.5 to 3.0%, the removal efficiency gradually decreased from 80.3% to 61.5% for CODCr, 76.4%-65.0% for BOD5, 64.1%-48.4% for NH4+-N, and 50%-36% for TN. Besides, the changes in biofilm characteristics with increasing salinity were observed during the operational period. The results indicate that salinity has a significant influence on the removal of organic matters and nitrogen transformation in the biofilm of the bioreactor. Even so, the DHS reactor revealed a good potential for treating saline wastewater.
Subject(s)
Sewage , Wastewater , Bioreactors , Nitrogen/analysis , Waste Disposal, FluidABSTRACT
Gold nanoparticles (AuNPs) decorated CNTs are promising materials for photocatalytics and biosensors. However, the synthesis of AuNPs chemically linked to the walls of MWCNTs is challenging and toxic products such as thionylchloride (SOCl2) or [1-ethyl-3(dimethyl-amino) propyl] carbodiimide hydrochloride (EDAC) need to be used. This work reports a new approach to prepare gold nanoparticles decorated multiwalled carbon nanotubes (MWCNTs) by using cysteaminium chloride via the formation of a Zwitterionic acide-base bond. The grafting process consists of 3 mains steps: oxidation, thiolation and decoration of AuNPs on the surface of MWCNTs. The completion of each step has been verified out by both spectroscopic (Raman, UV-Vis, FT-IR) and Scanning Electron Miscroscopy (SEM). The chemical bonding states of synthesized products have been proven by X-ray photoelectron spectroscopy (XPS).
