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Acta Crystallogr E Crystallogr Commun
; 75(Pt 10): 1540-1543, 2019 Oct 01.
Article
in English
| MEDLINE
| ID: mdl-31636990
ABSTRACT
The title phospho-nate-based organic-inorganic hybrid framework, poly[bis(dimethylammonium) [(µ4-2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C2H8N)2[Zn(C6H4O8P2)]} n , was formed unexpectedly when di-methyl-ammonium cations were formed from the in situ deca-rbonylation of the N,N-di-methyl-formamide solvent. The framework is built up from ZnO4 tetra-hedra and bridging di-phospho-nate tetra-anions to generate a three-dimensional network comprising [100] channels occupied by the (CH3)2NH2 + cations. Within the channels, an array of N-Hâ¯O hydrogen bonds help to establish the structure. In addition, intra-molecular O-Hâ¯O hydrogen bonds between the appended -OH groups of the phenyl ring and adjacent PO3 2- groups are observed.