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Chem Commun (Camb)
; 60(55): 7029-7032, 2024 Jul 04.
Article
in English
| MEDLINE
| ID: mdl-38894651
ABSTRACT
The synthesis of the organochromium(II) complexes [POCOPtBu]Cr(R) (R = p-Tol, Bn) is reported. Exposure of [POCOPtBu]Cr(Bn) to visible light promoted homolytic Cr-CBn bond cleavage and formed {[POCOPtBu]Cr}2(η1:η1µ-N2) via a putative [POCOPtBu]Cr(I) species.
