Photocatalytic Activity and Humidity Sensor Studies of Magnetically Reusable FeWO4-WO3 Composite Nanoparticles.

Different mole ratios of (8:2, 6:4, 4:6 and 2:8) iron tungstate-tungsten trioxide (FeWO4-WO3) composite nanoparticles were synthesized by solid state method. The synthesized composite nanoparticles were characterized by powder X-ray diffraction analysis (XRD), field-emission scanning electron microscopy (FE-SEM) with energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM) studies. The crystalline nature and particle size of the samples were characterized by powder X-ray diffraction analysis (XRD). The morphology was confirmed by field-emission scanning electron microscopy (FE-SEM) analysis and transmission electron microscope (TEM). The energy dispersive X-ray spectroscopy (EDX) proved the purity of nanocomposites. Vibrating sample magnetometer reveals that the sample shows paramagnetic property based on the metal present in the prepared nanocomposites at room temperature. The magnetic property is due to the structural defects rather than the impurity phase. Magnetization saturation value (Ms = 398.7 emu/g) of FWWO-46 composite nanoparticles is high enough to be magnetically removed by applying a magnetic field. The composites were subjected to DC conductance measurement as a function of relative humidity in the range of 5-98%, achieved by different water vapour buffers thermostated at room temperature. The sensitivity factor, Sf (R5%/R98%) measured at 25 °C revealed that FWWO-46 shows the highest humidity sensitivity factor Sf = 3956, with a response and recovery time of 45 s and 100 s respectively. Photocatalytic degradation of methylene blue (MB) from aqueous solution has been carried out using FeWO4-WO3 composite nanoparticles as photocatalyst under Ultraviolet radiation.

Structural, Optical, Morphological and Microbial Studies on SnO2 Nanoparticles Prepared by Co-Precipitation Method.

Nanoparticles of tin oxide (SnO2) powders were prepared by co-precipitation method at 500 °C, 700 °C and 900 °C temperature. The sintered SnO2 nanoparticles, structural, optical, magnetic, morphological properties and microbial activity have been studied. XRD studies reveals that sintered powder which exhibits tetragonal crystal structure and both crystallinity as well as crystal size increase with increase in temperature. The morphological studies reveal randomly arranged grains with compact nature grain size increases with sintering temperature. The compositional analyses of SnO2 nanoparticles have been studied using X-ray photoelectron spectroscopy analysis. The optical band gap values of SnO2 nanoparticles were calculated to be about 4.3 eV in the temperature 500 °C, comparing with that of the bulk SnO2 3.78 eV, by optical absorption measurement. Room temperature M-H curve for pure SnO2 nanoparticles exhibits ferromagnetic behaviour. The tin oxide nanoparticles are acted as potential candidate material for bacterial and fungal activity.

Optical, Magnetic and Photocatalytic Activity Studies of Li, Mg and Sr Doped and Undoped Zinc Oxide Nanoparticles.

Nanoparticles of Li, Mg and Sr doped and undoped zinc oxide was prepared by simple precipitation method. The structural, optical, and magnetic properties of the samples were investigated by the Powder X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultra-violet Visible spectroscopy (UV-vis) spectra, Photoluminescence (PL) and Vibrational Sample Magnetometer (VSM). The Powder X-ray diffraction data confirm the formation of hexagonal wurtzite structure of all doped and undoped ZnO. The SEM photograph reveals that the pores availability and particles size in the range of 10 nm-50 nm. FTIR and UV-Visible spectra results confirm the incorporation of the dopant into the ZnO lattice nanostructure. The UV-Visible spectra indicate that the shift of blue region (lower wavelength) due to bandgap widening. Photoluminescence intensity varies with doping due to the increase of oxygen vacancies in prepared ZnO. The pure ZnO exist paramagnetic while doped (Li, Mg and Sr) ZnO exist ferromagnetic property. The photocatalytic activity of the prepared sample also carried out in detail.