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Chem Commun (Camb) ; 54(39): 4931-4934, 2018 May 10.
Article in English | MEDLINE | ID: mdl-29697728

ABSTRACT

The redox properties of the µ-η2:η2 peroxo complex [Cu2(H6M4h)(O2)]2+ were elucidated. This study constitutes the first full electrochemical and spectroelectrochemical characterization of a side-on peroxo Cu2:O2 bioinorganic model complex. The peroxo complex is irreversibly reduced in a two-electron process localized on the peroxo ligand triggering the cleavage of the O-O bond.


Subject(s)
Biomimetic Materials/chemistry , Coordination Complexes/chemistry , Copper/chemistry , Hemocyanins/chemistry , Oxygen/chemistry , Electrochemical Techniques/methods , Electrons , Molecular Structure , Oxidation-Reduction , Thermodynamics
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