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1.
Synthesis of the Square-Planar Gallium Species K(2)
Twamley B; Power PP.
Angew Chem Int Ed Engl ; 39(19): 3500-3503, 2000 Oct 02.
Article in English | MEDLINE | ID: mdl-11091402
2.
(2,6-Mes(2)H(3)C(6))(2)BiH, a Stable, Molecular Hydride of a Main Group Element of the Sixth Period, and Its Conversion to the Dibismuthene (2,6-Mes(2)H(3)C(6))BiBi(2,6-Mes(2)C(6)H(3)) This work was supported by the National Science Foundation. The Bruker SMART 1000 difractometer was funded in part by NSF Instrumentation Grant CHE-9808259. Mes=2,4,6-Me(3)C(6)H(2).
Hardman NJ; Twamley B; Power PP.
Angew Chem Int Ed Engl ; 39(15): 2771-2773, 2000 Aug 04.
Article in English | MEDLINE | ID: mdl-10934423
3.
In(8)(C(6)H(3)-2,6-Mes(2))(4) (Mes=C(6)H(2)-2,4,6-Me(3)): A Metal-Rich Main-Group Cluster with a Distorted Cubane Structure.
Eichler BE; Hardman NJ; Power PP.
Angew Chem Int Ed Engl ; 39(2): 383-385, 2000 Jan.
Article in English | MEDLINE | ID: mdl-10649418

ABSTRACT

A distorted In(8) cubane core (see picture) is present in the novel indium cluster In(8)(C(6)H(3)-2,6-Mes(2))(4) (Mes=C(6)H(2)-2,4,6-Me(3)), which was synthesized by the reaction of LiC(6)H(3)-2,6-Mes(2) with InCl. It has an average In-In bond length of 2.92 Å and represents a new addition to the range of heavier Group 13 element clusters.

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