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1.
Sci Rep ; 12(1): 1017, 2022 Jan 19.
Article in English | MEDLINE | ID: mdl-35046449

ABSTRACT

In the present work, polymeric cages with 18 different pocket geometries are developed to investigate the effects of geometrical parameters and material properties on the amount of roller push-out force. An experimental setup including a specialized injection molding tool is designed and fabricated and three sets of polymeric cages are manufactured using the selected materials (PA46, PA66, PPA). Force measurements are carried out five times on each pocket and three cages for each material are tested. Considering three different materials, a total of 810 force measurements are performed. A theoretical model is developed to predict the roller push-out forces in polymeric cages with different materials and pocket geometries. The model is developed by estimating the deformed region of the cage as a cantilever beam with a parabolic profile. An empirical coefficient is reposed in the model to compensate for the assumptions applied to the model. Experimental results showed that a fixed coefficient gives accurate results for all the geometries and materials, which confirms the validity of the approach adopted in this paper for modeling such problems. Considering the geometrical and material tolerances, force limits predicted by the model cover all the forces measured for a specific pocket with excellent accuracy and consistency.

2.
Polymers (Basel) ; 9(1)2017 Jan 09.
Article in English | MEDLINE | ID: mdl-30970698

ABSTRACT

Bio-based polymer foams have been gaining immense attention in recent years due to their positive contribution towards reducing the global carbon footprint, lightweighting, and enhancing sustainability. Currently, polylactic acid (PLA) remains the most abundant commercially consumed biopolymer, but suffers from major drawbacks such as slow crystallization rate and poor melt processability. However, blending of PLA with a secondary polymer would enhance the crystallization rate and the thermal properties based on their compatibility. This study investigates the physical and compatibilized blends of PLA/poly (butylene succinate-co-adipate) (PBSA) processed via supercritical fluid-assisted (ScF) injection molding technology using nitrogen (N2) as a facile physical blowing agent. Furthermore, this study aims at understanding the effect of blending and ScF foaming of PLA/PBSA on crystallinity, melting, and viscoelastic behavior. Results show that compatibilization, upon addition of triphenyl phosphite (TPP), led to an increase in molecular weight and a shift in melting temperature. Additionally, the glass transition temperature (Tg) obtained from the tanδ curve was observed to be in agreement with the Tg value predicted by the Gordon⁻Taylor equation, further confirming the compatibility of PLA and PBSA. The compatibilization of ScF-foamed PLA⁻PBSA was found to have an increased crystallinity and storage modulus compared to their physically foamed counterparts.

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