Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle.

Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties. In order to optimize their stretching, a strategy based on the time/temperature principle is used. The building of master curves, in the linear visco-elastic domain, allows the identification of the experimental conditions for which the two materials are in the same physical state. The initial physical state of the materials is important as, to fit with the industrial constrains, the polymers must reach high level of deformation, and develop strain induced crystallization (SIC). In this paper, the screening of the forming range is described, as well as the mechanical response depending on the stretching settings. Moreover, the same mechanical response can exist for PEF and PET if the same gap from the α-relaxation exists.

Effect of the Strain Rate on Damage in Filled EPDM during Single and Cyclic Loadings.

The effect of the strain rate on damage in carbon black filled Ethylene Propylene Diene Monomer rubber (EPDM)stretched during single and multiple uniaxial loading is investigated. This has been performed by analyzing the stress-strain response, the evolution of damage by Digital Image Correlation (DIC), the associated dissipative heat source by InfraRed thermography (IR), and the chains network damage by swelling. The strain rates were selected to cover the transition from quasi-static to medium strain rate conditions. In single loading conditions, the increase of the strain rate yields in a preferential damage of the filler network while the rubber network is preserved. Such damage is accompanied by a stress softening and an adiabatic heat source rise. Conversely, increasing the strain rate in cyclic loading conditions yields in a filler network accommodation and a high self-heating whose combined effect is proposed as a possible cause of the ability of filled EPDM to limit damage by reducing cavities opening during loading, and favoring cavities closing upon unloading.

Mechanical characterization and identification of material parameters of porcine aortic valve leaflets.

The ideal artificial heart valve does not exist yet. Understanding of mechanical and structural properties of natural tissues is necessary to improve the design of biomimetic aortic valve. Besides these properties are needed for the finite element modeling as input parameters. In this study we propose a new method combining biaxial tests and digital image correlation. These tests are carried out on porcine aortic valves. In this work, we use a modified version of the HGO (Holzapfel-Gasser-Ogden) model which is classically used for hyper-elastic and anisotropic soft tissues. This model can include fiber orientation. The identification of HGO model parameters can be determined using experimental data and two different protocols. One protocol is based on the identification of collagen fibers orientation as well as the mechanical parameters. The second one, is based on a complementary experiment to determine orientation (confocal laser scanning microscope). Both lead to determine different sets of material parameters. We show that the model is more likely to reproduce the actual mechanical behavior of the heart valves in the second case and that a minimum of three different loading conditions for the biaxial tensile tests is required to obtain a relevant set of parameters.

Mechanical properties of cellulose aerogels and cryogels.

Highly porous and lightweight cellulose materials were prepared via dissolution-coagulation and different drying routes. Cellulose of three different molecular weights was dissolved in an ionic liquid/dimethyl sulfoxide mixture. Drying was performed either with supercritical CO2 resulting in "aerogels", or via freeze-drying resulting in "cryogels". The influence of cellulose molecular weight, concentration and drying method on the morphology, density, porosity and specific surface area was determined. The mechanical properties of cellulose cryogels and aerogels under uniaxial compression were studied in detail and analyzed in the view of existing models developed for porous materials. It was demonstrated that the Poisson's ratio of cellulose aerogels is not equal to zero, contrary to what is usually reported in the literature, but decreases with an increase in density. Compressive modulus and yield stress of cryogels turned out to be higher than those of aerogels taken at the same density. This was interpreted by the different morphology of the porous materials studied.