Algal mediated intervention for the retrieval of emerging pollutants from aqueous media.

Water is a crucial elemental contributor for all sectors; however, the agricultural sector alone accounts for 70% of the world's total water withdrawal. The anthropogenic activity from various industries including agriculture, textiles, plastics, leather, and defence has resulted in the release of contaminants into water systems, resulting harm to the ecosystem and biotic community. Algae-based organic pollutant removal uses several methods, such as biosorption, bioaccumulation, biotransformation, and biodegradation. The adsorption of methylene blue by algal species Chlamydomonas sp. showed a maximum adsorption capacity of 2744.5 mg/g with 96.13% removal efficiency; on the other hand, Isochrysis galbana demonstrated a maximum of 707 µg/g nonylphenol accumulation in the cell with 77% removal efficiency indicating the potential of algal systems as efficient retrieval system for organic contaminants. This paper is a compilation of detailed information about biosorption, bioaccumulation, biotransformation, biodegradation, and their mechanism, along with the genetic alteration of algal biomass. Where the genetic engineering and mutations on algae can be advantageously utilized for the enhancement of removal efficiency without any secondary toxicity.

Application of MXenes for water treatment and energy-efficient desalination: A review.

MXenes are a new type of two-dimensional (2D) material which are rapidly gaining traction for a range of environmental, chemical and medical applications. MXenes and MXene-composites exhibit high surface area, superlative chemical stability, thermal conductivity, hydrophilicity and are environmentally compatible. Consequently, MXenes have been successfully employed for hydrogen storage, semiconductor manufacture and lithium ion batteries. In recent years, MXenes have been utilized in numerous environmental applications for treating contaminated surface waters, ground and industrial/ municipal wastewaters and for desalination, often outperforming conventional materials in each field. MXene-composites can adsorb multiple organic and inorganic contaminants, and undergo Faradaic capacitive deionization (CDI) when utilized for electrochemical applications. This approach allows for a significant decrease in the energy demand by overcoming the concentration polarization limitation of conventional CDI electrodes, offering a solution for low-energy desalination of brackish waters. This article presents a state-of-the-art review on water treatment and desalination applications of MXenes and MXene-composites. An investigation into the kinetics and isotherms is presented, as well as the impact of water constituents and operating conditions are also discussed. The applications of MXenes for CDI, pervaporation desalination and solar thermal desalination are also examined based on the reviewed literature. The effects of the water composition and operational protocols on the regeneration efficacy and long-term usage are also highlighted.

Silk Fibroin As an Immobilization Matrix for Sensing Applications.

The development of flexible, biocompatible, and environment-friendly sensors has attracted a significant amount of scientific interest for the past few decades. Among all the natural materials, silk fibroin (SF), due to its tunable biodegradability, biocompatibility, ease of processing, presence of functional groups, and controllable dimensions, has opened up opportunities for immobilizing multitudinous biomolecules and conformability to the skin, among other attractive opportunities. The silk fibroins also offer good physical properties, such as superior toughness and tensile strength. The sensors made of SF as an immobilization matrix have demonstrated excellent analytical performance, sensing even at low concentrations. The significant advantage of silk fibroins is the presence of functional groups along with a controllable conformation transition that enables immobilization of receptor molecules using silk fibroins as an immobilization matrix enables us to entrap the receptor molecules without using any chemical reagents. This review encompasses a detailed discussion on sensors, the advantages of using silk fibroins as an immobilization matrix for various receptors, their applications, and the future research scope in this state-of-the-art technology based upon the explorable applications for silk fibroin-based sensors.