ABSTRACT
The development of stable and selective electrocatalysts for converting CO2 to value-added chemicals or fuels has gained much interest in terms of their potential to mitigate anthropogenic carbon emissions. Most of the electrocatalysts are tested under pure CO2; however, industrial outlet flue gas contains numerous impurities, such as NO and SO2, which poison the electrocatalysts and alter the product selectivity. Developing electrocatalysts that are resistant to such impurities is essential for commercial implementation. Herein, we prepared bilayer porous electrocatalysts, namely, Sn, Bi, and In, on porous Cu foam mesh (Sn/Cu-f, Bi/Cu-f, and In/Cu-f) by a two-step electrodeposition process and employed these electrodes for the electrochemical reduction of CO2 to formate. It was observed that the bilayer porous electrocatalysts exhibited high CO2 reduction activity compared to catalysts coated on a Cu mesh. Among bilayer porous electrocatalysts, Sn/Cu-f and Bi/Cu-f electrocatalysts showed more than 80% faradaic efficiency (FE) toward formate production, with a formate partial current density of around -16 and -10.4 mA cm-2, respectively, at -1.02 V vs RHE. In/Cu-f electrocatalyst showed nearly 40% formate FE with formate partial current density of -15 mA cm-2 at -1.22 V vs RHE. We investigated the effect of NO and SO2 impurities (500 ppm of NO, 800 ppm of SO2, and 500 ppm of NO + 800 ppm of SO2) on these electrocatalysts' selectivity and stability toward formate. It was observed that the Bi/Cu-f electrocatalyst showed 50 h stability with 80 ± 5% formate FE, and Sn/Cu-f showed 18 h stability with above 80 ± 5% efficiency in the presence of NO and SO2 mixed with CO2. Furthermore, we studied the effect of CO2 concentration with Sn/Cu-f and Bi/Cu-f catalysts in the range of 15-100% CO2, for which formate FEs of 45-80% were observed.
