Performance Evaluation for Ultra-Lightweight Epoxy-Based Bipolar Plate Production with Cycle Time Reduction of Reactive Molding Process.

The commercial viability of fuel cells for vehicle application has been examined in the context of lightweight material options, as well as in combination with improvements in fuel cell powertrain. Investigation into ultra-lightweight bipolar plates (BPs), the main component in terms of the weight effect, is of great importance to enhance energy efficiency. This research aims to fabricate a layered carbon fiber/epoxy composite structure for BPs. Two types of carbon fillers (COOH-MWCNT and COOH-GNP) reinforced with woven carbon fiber sheets (WCFS) have been utilized. The conceptual idea is to reduce molding cycle time by improving the structural, electrical, and mechanical properties of BPs. Reducing the reactive molding cycle time is required for commercial production possibility. The desired crosslink density of 97%, observed at reactive molding time, was reduced by 83% at 140 °C processing temperature. The as-fabricated BPs demonstrate excellent electrical conductivity and mechanical strength that achieved the DOE standard. Under actual fuel cell operation, the as-fabricated BPs show superior performance to commercial furan-based composite BPs in terms of the cell potential and maximum power. This research demonstrates the practical and straightforward way to produce high-performance and reliable BPs with a rapid production rate for actual PEMFC utilization.

A highly responsive methanol sensor based on graphene oxide/polyindole composites.

Graphene-based materials, namely commercial graphene (cm-G), commercial graphene oxide (cm-GO), reduced graphene oxide (rGO), and synthesized graphene oxide (OIHM-GO), and their composites with polyindole (PIn) were used as sensing materials for methanol vapor. The synthesized graphene oxide was prepared by the optimized improved Hummers' method. rGO was prepared from cm-GO by two different methods: thermally mild reduction at 120 °C to yield T-rGO and chemical reduction by ascorbic acid to yield C-rGO. Graphene-based material/polyindole composites were prepared by in situ polymerization. In this report, the sensing responses were evaluated from the responsive electrical currents at room temperature. cm-GO showed the highest methanol response because it possessed the highest number of oxygen species, which act as the active sites. The relative electrical conductivity response of the in situ cm-GO/dPIn composite to methanol was the highest amongst the composites. The in situ OIHM-GO/dPIn composite possessed the high relative conductivity response of 81.89 ± 2.12 at 11.36 ppm, a sensitivity of 7.37 ppm-1 with R 2 of 0.9967 in the methanol concentration range of 1.14-11.36 ppm, a theoretical LOD of 0.015 ppm, and repeatability of at least 4 cycles with good selectivity. This work represents the first report of the preparation and testing of graphene-based materials/polyindole composites as methanol sensors.

Effects of crosslinking ratio, model drugs, and electric field strength on electrically controlled release for alginate-based hydrogel.

The drug release characteristics of calcium alginate hydrogels, (Ca-Alg), under an electric field assisted transdermal drug delivery system were systematically investigated. The Ca-Alg hydrogels were prepared by the solution-casting using CaCl(2) as a crosslinking agent. The diffusion coefficients and the release mechanism of the anionic model drugs, benzoic acid and tannic acid, and a cationic model drug, folic acid on the Ca-Alg hydrogels were determined and investigated using a modified Franz-Diffusion cell in an MES buffer solution of pH 5.5, at a temperature of 37°C, for 48 h. The influences of the crosslinking ratio, -the mole of the crosslinking agent to the mole of the alginate monomer-mesh size, model drug size, drug charge, electric field strength, and electrode polarity were systematically studied. The drug diffusion coefficient decreased with an increasing crosslinking ratio and drug size for all of the model drugs. The drug diffusion coefficient is precisely controlled by an applied electric field and the electrode polarity depending on the drug charge, suitable for a tailor-made transdermal drug delivery system.

Electrical conductivity response of poly(phenylene-vinylene)/zeolite composites exposed to ammonium nitrate.

Poly(p-phenylenevinylene) (PPV) was chemically synthesized via the polymerization of p-xylene-bis(tetrahydrothiophenium chloride) monomer and doped with H(2)SO(4). To improve the electrical conductivity sensitivity of the conductive polymer, Zeolites Y (Si/Al = 5.1, 30, 60, 80) were added into the conductive polymer matrix. All composite samples show definite positive responses towards NH(4)NO(3). The electrical conductivity sensitivities of the composite sensors increase linearly with increasing Si/Al ratio: with values of 0.201, 1.37, 2.80 and 3.18, respectively. The interactions between NH(4)NO(3) molecules and the PPV/zeolite composites with respect to the electrical conductivity sensitivity were investigated through the infrared spectroscopy.