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Aziridinyl anions from a chiral, nonracemic 2-isopropylidineaziridine: surprisingly diastereoselective alkylation reactions.
Hayes, J F; Prévost, N; Prokes, I; Shipman, M; Slawin, A M Z; Twin, H.
Chem Commun (Camb) ; (12): 1344-5, 2003 Jun 21.
Article in English | MEDLINE | ID: mdl-12841233

ABSTRACT

Lithiation and alkylation of a 2-isopropylidineaziridine bearing an (S)-alpha-methylbenzyl group on nitrogen proceeds with high levels of diastereocontrol (80-90% de).

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