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1.
Materials (Basel) ; 15(8)2022 Apr 12.
Article in English | MEDLINE | ID: mdl-35454524

ABSTRACT

Over the last decade, there has been increased interest in applying biomass as a raw material for producing biofuels used for thermochemical conversions. Extensive use of biomass could lead to controversial competition for arable land, water, and food; therefore, only waste materials and agricultural by-products and residues should be used to produce biofuels. One suitable by-product of agricultural production is crop residue from the harvest of maize for grain (corn stover). The harvest residues of corn stover consist of four fractions, i.e., husks, leaves, cobs, and stalks, which are structurally and morphologically distinct. The aim of the study was to determine the effect of selected maize cultivars with distinct FAO (Food and Agriculture Organization of the United Nations) earliness classifications on the chemical and energetic properties of their corn cob cores. We determined the chemical properties based on elemental analysis, and the energy properties based on the heat of combustion and calorific values. The content of ash and volatile compounds in the corn cobs were also determined. The results indicated that the heat of combustion of fresh and seasoned corn cob cores ranged from 7.62-10.79 MJ/kg and 16.19-16.53 MJ/kg, respectively. The heat of combustion and calorific value of corn cob cores in the fresh state differed significantly and were strongly correlated with maize cultivars with distinct FAO earliness.

2.
Materials (Basel) ; 14(6)2021 Mar 20.
Article in English | MEDLINE | ID: mdl-33804750

ABSTRACT

In the last decade, an increasingly common method of maize stover management is to use it for energy generation, including anaerobic digestion for biogas production. Therefore, the aim of this study was to provide a chemical and structural characterization of maize stover fractions and, based on these parameters, to evaluate the potential application of these fractions, including for biogas production. In the study, maize stover fractions, including cobs, husks, leaves and stalks, were used. The biomass samples were characterized by infrared spectroscopy (FTIR), X-ray diffraction and analysis of elemental composition. Among all maize stover fractions, stalks showed the highest C:N ratio, degree of crystallinity and cellulose and lignin contents. The high crystallinity index of stalks (38%) is associated with their high cellulose content (44.87%). FTIR analysis showed that the spectrum of maize stalks is characterized by the highest intensity of bands at 1512 cm-1 and 1384 cm-1, which are the characteristic bands of lignin and cellulose. Obtained results indicate that the maize stover fraction has an influence on the chemical and structural parameters. Moreover, presented results indicate that stalks are characterized by the most favorable chemical parameters for biogas production.

3.
Sensors (Basel) ; 19(20)2019 Oct 12.
Article in English | MEDLINE | ID: mdl-31614766

ABSTRACT

The study concentrates on researching possibilities of using computer image analysis and neural modeling in order to assess selected quality discriminants of spray-dried chokeberry powder. The aim of the paper is the quality identification of chokeberry powders on account of their highest dying power, the highest bioactivity, as well as technologically satisfying looseness of the powder. The article presents neural models with vision techniques backed up by devices such as digital cameras, as well as an electron microscope. The reduction in size of input variables with PCA has an influence on improving the processes of learning data sets, thus increasing the effectiveness of identifying chokeberry fruit powders included in digital pictures, which is shown in the results of the conducted research. The effectiveness of image recognition is presented by classifying abilities, as well as low Root Mean Square Error (RMSE), for which the best results are achieved with a typology of network type Multi-Layer Perceptron (MLP). The selected networks type MLP are characterized by the highest degree of classification at 0.99 and RMSE at 0.11 at most at the same time.

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