Properties of mixture of hemp bast and softwood pulp for filter paper manufacture.

The objective of this study was to investigate the morphological and chemical properties of hemp bast RPF1 variety fiber to be used as a potential raw material for filter paper production. Experimental handsheet samples with basis weight of 20 g/m2 were manufactured using mixture of hemp and softwood pulp at various beating levels. The average fiber length and width of hemp bast fiber were determined as 5.76 mm and 32.53 µm, respectively. It was also found that the hemp bast fiber had rigid thick cell wall with small size of lumen. The overall chemical properties of hemp bast were similar to those fibers from other bast sources as well as softwood fibers. It seems that hemp bast was easily pulped under various soda process conditions yielding pulp ranging from 51.36 % to 52.56 % and Kappa numbers ranging from 2.89 to 8.18. Based on the findings in this study hemp bast fiber could be considered as a potential to manufacture filter paper with accepted characteristics.

Bamboo fiber strengthened poly(lactic acid) composites with enhanced interfacial compatibility through a multi-layered coating of synergistic treatment strategy.

In this study, a mild and eco-friendly synergistic treatment strategy was investigated to improve the interfacial compatibility of bamboo fibers with poly(lactic acid). The characterization results in terms of the chemical structure, surface morphology, thermal properties, and water resistance properties demonstrated a homogeneous dispersion and excellent interfacial compatibility of the treated composites. The excellent interfacial compatibility is due to multi-layered coating of bamboo fibers using synergistic treatment involving dilute alkali pretreatment, polydopamine coating and silane coupling agent modification. The composites obtained using the proposed synergistic treatment strategy exhibited excellent mechanical properties. Optimal mechanical properties were observed for composites with synergistically treated bamboo fiber mass proportion of 20 %. The tensile strength, elongation at break and tensile modulus of the treated composites were increased by 63.06 %, 183.04 % and 259.04 %, respectively, compared to the untreated composites. This synergistic treatment strategy and the remarkable performance of the treated composites have a wide range of applicability in bio-composites (such as industrial packaging, automotive lightweight interiors, and consumer goods).

Morphology, Taxonomy, Culm Internode and Leaf Anatomy, and Palynology of the Giant Reed (Arundo donax L.), Poaceae, Growing in Thailand.

In this paper, we present the morphology, taxonomy, anatomy, and palynology of Arundo donax. A detailed morphological description and illustrations of the species are provided, along with information about the identification, distribution, the specimens examined, habitat and ecology, the International Union for Conservation of Nature (IUCN) conservation assessment, phenology, etymology, vernacular name, and uses. The species can be distinguished by its large, tall rhizomatous perennial reed; cauline leaves; an open, large, plumose panicle inflorescence; subequal glumes as long as the spikelets; glabrous rachilla; all bisexual florets; and a lemma with a straight awn and with long white hairs outside below the middle part. In this study, two names were lectotypified: Arundo bifaria and A. bengalensis, which are synonyms of A. donax. The culm internodes in the transverse section have numerous vascular bundles scattered in the ground tissue, and the parenchyma cells have significantly lignified cell walls. Vascular bundles are composed of phloem and xylem and are enclosed in a continuous sclerenchymatous bundle sheath. The chloroplasts in the transverse section of the leaf blades are found only in the mesophyll cells but are absent in the bundle sheath cells, which indicates that it is a C3 grass. The leaves have stomata on both surfaces and are confined to the intercostal zones. The stomata are typically paracytic, with two lateral subsidiary cells placed parallel to the guard cells. The stomatal density is higher on the abaxial surface [450-839/mm2 (606.83 ± 72.71)] relative to the adaxial surface [286-587/mm2 (441.27 ± 50.72)]. The pollen grains are spheroidal or subspheroidal [polar axis length/equatorial axis length ratio (P/E ratio) = 0.89-1.16 (1.02 ± 0.07)] with a single pore surrounded by a faint annulus, and the exine sculpturing is granular.

Sugarcane leave-derived cellulose nanocrystal/graphene oxide filter membrane for efficient removal of particulate matter.

The goal of this study is to isolate cellulose nanocrystals (CNC) from sugarcane leaves (SCL) and fabricate filter membranes. Filter membranes consisting of the CNC and varying amount graphene oxide (GO) were fabricated using vacuum filtration technique. The α-cellulose content increased from 53.56 ± 0.49 % in untreated SCL to 78.44 ± 0.56 % and 84.99 ± 0.44 % in steam-exploded and bleached fibers, respectively. Atomic force microscopy (AFM) and transmission electron microscope (TEM) of CNC isolated from SCL indicated nanosized particles in the range of 7.3 nm and 150 nm for diameter and length, respectively. Morphologies of the fiber and CNC/GO membranes were determined by scanning electron microscopy (SEM) and crystallinity by X-ray diffraction (XRD) analysis of crystal lattice. The crystallinity index of CNC decreased with the addition of GO into the membranes. The CNC/GO-2 recorded the highest tensile index of 3.001 MPa. The removal efficiency increases with increasing GO content. The highest removal efficiency of 98.08 % was recorded for CNC/GO-2. CNC/GO-2 membrane reduced growth of Escherichia coli to 65 CFU compared to >300 CFU of control sample. SCL is a potential bioresource for isolation of cellulose nanocrystals and fabrication of high-efficiency filter membrane for particulate matter removal and inhibition of bacteria.

Assessment of Electrothermal Pretreatment of Rambutan (Nephelium lappaceum L.) Peels for Producing Cellulose Fibers.

Agroindustrial wastes are renewable sources and the most promising sustainable alternative to lignocellulosic biomass for cellulose production. This study assessed the electrothermal pretreatment of rambutan peel (RP) for producing cellulose fibers. The pretreatment was carried out by Ohmic heating at a solid-to-liquid ratio of 1:10 (w/v) in a water/ethanol (1:1, v/v) mixture as the electrical transmission medium at 60 ± 1 °C for different holding times (15, 30, and 60 min). Ohmic heating did not significantly influence the total fiber yield for the various holding times. However, the compositions of the samples in terms of extractives, lignin, hemicellulose, and α-cellulose content were significantly influenced. In addition, the electrothermal pretreatment method reduced the bleaching time of RP by 25%. The pretreated fibers were thermally stable up to 240 °C. Ohmic heating pretreatment times of 15 and 30 min were found most promising, reducing the required bleaching chemicals and increasing the α-cellulose yield. The pretreated bleached cellulose fibers had similar properties to nontreated bleached fibers and could be efficiently processed into stable gels of strong shear-thinning behavior with potential application as rheology modifiers in food products. Our results demonstrate that rambutan peel could serve as a promising sustainable alternative to woody biomass for cellulose production. Ohmic heating meets the requirements for industrial applications as it is eco-friendly, improves the efficiency and energy consumption in fiber processing, and could as well be included in the processing of similar food wastes.

Development of Nanocomposite Film Comprising of Polyvinyl Alcohol (PVA) Incorporated with Bacterial Cellulose Nanocrystals and Magnetite Nanoparticles.

Nanocomposite film of poly(vinyl alcohol) (PVA) incorporated with bacterial cellulose nanocrystals (BCNCs) and magnetite nanoparticles (Fe3O4) is reported in this study. The BCNC-Fe3O4 nanoparticles and PVA film was prepared by in situ synthesis technique using chemical co-precipitation. Different concentrations of BCNC-Fe3O4 (20%, 40% and 60% w/w) were mechanically dispersed in PVA solution to form the nanocomposite film. Transmission electron microscopy (TEM) analysis of BCNC-Fe3O4 nanoparticles showed irregular particle sizes ranging from 4.93 to 30.44 nm with an average size distribution of 22.94 nm. The presence of characteristic functional groups of PVA, BCNC and Fe3O4 were confirmed by Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) analysis. Scanning electron microscope (SEM) attached energy dispersive spectroscopy (EDS) and vibrating sample magnetometer (VSM) analysis revealed that, the iron content and magnetic property increased with increasing BCNC-Fe3O4 content. The saturation magnetizations (MS) value increased from 5.14 to 11.56 emu/g. The PVA/ BCNC-Fe3O4 at 60% showed the highest Young's modulus value of 2.35 ± 0.16 GPa. The prepared film could be a promising polymeric nanomaterial for various magnetic-based applications and for the design of smart electronic devices.

TEMPO-oxidized cellulose nanofibril film from nano-structured bacterial cellulose derived from the recently developed thermotolerant Komagataeibacter xylinus C30 and Komagataeibacter oboediens R37-9 strains.

Bacterial cellulose (BC), prepared from two recently developed thermotolerant bacterial strains (Komagataeibacter xylinus C30 and Komagataeibacter oboediens R37-9), were used as a raw material to synthesize nanofibril films. Field-emission scanning electron microscope (FE-SEM) observations confirmed the ultrafine nano-structure of BC pellicle (BCP) with average fibril widths between 50 and 60 nm. The BC was directly oxidized in a TEMPO/NaBr/NaClO system at pH of 10 for 2 h. TEMPO-oxidized bacterial cellulose nanofibrils (TOBCN) were obtained by a mild mechanical treatment and the TOBCN films were prepared through heat-drying. The oxidation yielded a recovery ratio between 70 and 80% by weight with an increase in the carboxylate content of 0.9-1.0 mmol g -1. Nanofibrillation yields were more than 90% and the resulting high aspect ratio TOBCNs were ~6 nm in average width with >800 nm in lengths, when observed under transmission electron microscope (TEM). TOBCN film of K. xylinus C30 exhibited high transparency (79%), tensile strength (142 MPa), Young's modulus (7.13 GPa), elongation around failure (3.89%), and work of fracture (2.29 MJ m-3), when compared to the TOBCN films of K. oboediens R37-9 at 23 °C and 50% RH. Coefficients of thermal expansion of both the TOBCN films were low at around 6 ppm K-1.

Basalt-Fiber-Reinforced Polyvinyl Acetate Resin: A Coating for Ductile Plywood Panels.

The aim of this study was to create a reinforced composite wood-based panel that would be leaned towards the environment Plywood was used as a core material and fiber-reinforced polymer was used as a reinforcement. Conventional resin for the fiber-reinforced polymer was substituted with polyvinyl acetate (PVAC), which has several advantages, such as a lower price, easier handling, and better degradability. The second chosen component, basalt fiber, is cost attractive and environmentally friendly. The combination of one and two layers of fabric with three fiber fractions and 4 mm thick plywood was investigated. The best results were achieved with two layers of fabric and the highest fiber fraction. The improvements of the ultimate bending load and bending stiffness of the plywood in the perpendicular direction were 305% and 325%, respectively. The ultimate load and stiffness of the parallel direction were improved by 31% and 35%, respectively. However, specimens always failed in the compressional zone. The highest reinforcing effect was found with the impact test: The energy required to fracture specimens increased by 4213% and 6150% for one and two layers of fabric, respectively. In conclusion, specimens exhibited high ductility due to the PVAC and basalt fiber. The amount of work and energy required to cause fractures was extensive.

Comparative characterization of TEMPO-oxidized cellulose nanofibril films prepared from non-wood resources.

Three non-wood celluloses, hemp bast holocellulose, and commercial bamboo and bagasse bleached kraft pulps, were oxidized by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation in water at pH 10. The water-insoluble TEMPO-oxidized celluloses thus obtained were converted to aqueous dispersions of TEMPO-oxidized cellulose nanofibrils (TOCNs) and then to self-standing TOCN films. Weight recovery ratios of the TEMPO-oxidized celluloses decreased to 70-80% and their carboxylate contents reached 1.5-1.7mmolg(-1) by the TEMPO-mediated oxidation. The viscosity-average degrees of polymerization remarkably decreased from 800-1100 to 200-480 by partial depolymerization occurring during the oxidation, depending on the non-wood celluloses used as the starting materials. The average lengths and widths of the TOCNs were estimated to be 500-650nm and 2.4-2.9nm, respectively, from their atomic force microscopy images. The self-standing TOCN films had high light-transparencies (>87% at 600nm), high tensile strengths (140-230MPa), high Young's moduli (7-11MPa), low coefficients of thermal expansion (4-6ppmK(-1)) in spite of low densities of 1.4-1.7gcm(-3). In particular, the TOCN films prepared from the hemp bast holocellulose had clearly high works of fracture (~30MJm(-3)), whereas those prepared from other two non-wood celluloses had 2-8MJm(-3).