ABSTRACT
The experimental study evaluated the factors (temperature, mass of n polymer, time of sorption et al.) influencing coal and rock dust sorption of carbamide-formaldehyde, penopolyurethane monomers. The atmosphere of coal mines was proved to be contaminated during the extraction by multiple-component mixture, where the volatile monomers are gaseous, vaporous or absorbed by the dust particles.
Subject(s)
Air Pollutants, Occupational/analysis , Coal Mining , Dust , Air Pollutants, Occupational/adverse effects , Dust/adverse effects , Environmental Monitoring , Formaldehyde/adverse effects , Formaldehyde/analysis , Humans , Polyurethanes/adverse effects , Polyurethanes/analysis , Resins, Synthetic/adverse effects , Resins, Synthetic/analysis , Urea/adverse effects , Urea/analysisABSTRACT
A reaction of chlorides with trivalent iron and mercuric rhodanide was suggested to be conducted in nonaqueous solvents so as to increase its sensitivity. After some trials the following medium was suggested: 60-70 vol.% acetic acid and 7-15 vol.% hydrochloric acid. Measurements limit -2.5 mg/m, measurements range -2.5-25.0 mg/m.
Subject(s)
Air Pollutants/analysis , Chlorides/analysis , Photometry/methods , Acetates , Acetic Acid , Filtration , Hydrochloric AcidABSTRACT
The article contains a hygienic and chemical assessment of the KH-96 polymethane foam plastic material used in air hermetization in coal mines. A set of measures is proposed to ensure safety in working with the material.
Subject(s)
Air Pollutants, Occupational/toxicity , Coal Mining , Construction Materials , Polyurethanes/toxicity , Ventilation , Evaluation Studies as Topic , Maximum Allowable ConcentrationABSTRACT
The article contains a description of a new photometric technique of measuring caustic alkali content in the working zone air. The technique proved to be sensitive in the presence of carbonic acid gas (the lowest degree of measurements at 0.25 mg/m3 in 100 dm3 air sample).
Subject(s)
Air Pollutants, Occupational/analysis , Alkalies/analysis , Photometry/methods , Coal Mining , Photometry/instrumentation , UkraineSubject(s)
Air Pollutants, Occupational/toxicity , Chemical Industry/methods , Coal , Hydrocarbons/toxicity , Indicators and Reagents/toxicity , Occupational Medicine/methods , Acetates/pharmacology , Acetic Acid , Air Pollutants, Occupational/analysis , Humans , Hydrocarbons/analysis , Indicators and Reagents/analysis , Maximum Allowable Concentration , Photometry/methods , UkraineABSTRACT
Out of a set of tested stabilizers used in the photometric detection of sulphur dioxide by fuchs in formaldehyde reactions, trilon B solution was chosen in concentrations 2.5.10(-4)-1.10(-2) M as an absorbent solution and stabilizer. The proposed substitution of natrium tetrachlormercurate by trilon B provided greater stability of sulphur dioxide solution for 7 days and a higher absorbing activity (99.6-100%), avoiding working with highly poisonous substance which would require much time for synthesis.
Subject(s)
Air Pollutants, Occupational/analysis , Chemical Industry/standards , Sulfur Dioxide/analysis , Formaldehyde/pharmacology , Indicators and Reagents/pharmacology , Photometry/methods , Rosaniline Dyes/pharmacology , Sulfur Dioxide/standards , UkraineABSTRACT
The contributors proposed a new highly sensitive selective technique of magnesium oxide detection, based on the Congo red and salicylic acid reaction. The minimal detection level is 0.25 mg of magnesium oxide in the analyzed sample volume. The range of measured concentrations varies from 0.01 to 0.4 mcg/ml. The express technique is simple and selective with Ca (II), Fe (III), AI (III).
Subject(s)
Air Pollutants, Occupational/analysis , Magnesium Oxide/analysis , Caustics , Coal Mining , Dust , Indicators and Reagents , Magnesium Chloride , PhotometryABSTRACT
In a set of reactions used in photometric lead detection, the arcenaso III and sodium molibdate reaction was chosen for lead control, the measurement level being 0.1 micrograms/cm2 and the measurement range of 0.1-3 micrograms/cm2. The technique is applicable in presence of Fe+2, Fe+3, Al+3, Sn+4, Ni+2, Cr+2, Cr+6, Cd+2, Co+2, Zn+2.
Subject(s)
Air Pollutants, Occupational/analysis , Lead/analysis , Humans , Photometry , Polarography , Skin/analysisSubject(s)
Air Pollutants, Occupational/toxicity , Coal Mining/standards , Construction Materials/standards , Formaldehyde/toxicity , Phenols/toxicity , Polymers/toxicity , Air Pollutants, Occupational/analysis , Formaldehyde/chemistry , Formaldehyde/standards , Humans , Maximum Allowable Concentration , Phenol , Phenols/chemistry , Phenols/standards , Polymers/chemistry , Polymers/standards , UkraineABSTRACT
Photometric procedure of methanol determination based on its reaction with phenyl hydrazin and dinitride sulfanilic acid was developed. The procedure was highly sensitive (0.1 microgram in the analyzed volume) and selective in the presence of phenol, furyl alcohol, methanol and furfurol.