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Dalton Trans ; 40(28): 7442-5, 2011 Jul 28.
Article in English | MEDLINE | ID: mdl-21691650

ABSTRACT

The aqueous one-step reaction of Re(CO)(3)(H(2)O)(3)(+) with pyridine-2-carboxyaldehyde and glycine or alanine produces a new class of cyclic dimeric products. The ligands of the chiral C(2)-symmetric products are bound via the diimine at one rhenium centre and via the pendant carboxylate to a second rhenium center.


Subject(s)
Amino Acids/chemistry , Polycyclic Compounds/chemistry , Polycyclic Compounds/chemical synthesis , Rhenium/chemistry , Aldehydes/chemistry , Crystallography, X-Ray , Molecular Sequence Data , Molecular Structure , Stereoisomerism
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