ABSTRACT
Humic substance (HS) is a main component of dissolved organic matter in the aquatic environment and significantly affects water treatment processes. To investigate the applicability and principle of UV spectrum analysis for coagulation control, laboratory jar tests were conducted with synthetic waters that had varying concentrations of HS and kaolinite. Thus, the influence of water quality conditions on the optimal coagulant dose (OCD) was determined and further correlated to Specific Ultraviolet Absorbance (SUVA254) and the ultraviolet spectral slopes of the coagulated water. Subsequently, the relationship between the UV spectral slopes and organic fractionation was further identified by using size exclusion chromatography (SEC). The results showed that the coagulant demands of the synthetic waters were positively related to dissolved organic carbon (DOC). Consequently, a stoichiometric relationship (0.61 mg·mg-1 calculated as Al/DOC) was found between the coagulant demand and initial DOC of the synthetic water. As the coagulant dose increased, SUVA254 decreased from 8.9 L·(mg·m)-1 to a steady level of 2.0 L·(mg·m)-1 and the removal efficiency of DOC was positively correlated with SUVA254. Spectral slopes in different wavelength ranges had showed similar tendencies, with S275-295 having the best correlation with SUVA254 (R2=0.81). Furthermore, SEC results demonstrated that coagulation preferentially removed humic substances, leading to reduced humification. As a result, S275-295 had the highest correlation with the portion of UVA254 contributed by humic substances in water. Therefore, online measurement of ultraviolet spectral slopes was an important aspect in the control of coagulant dosing.
ABSTRACT
A complex bioflocculant MBF917 was prepared by Rhizopus sp. M9 and M17 using potato starch wastewater (PSW) as nutrilite, and its flocculation characteristics of treating PSW were studied. Culture conditions of the two strains were optimized, and flocculating conditions of the bioflocculant for treating PSW were also investigated. The optimal and economical culture conditions were determined as COD of about 1600 mg/L, 0.3 g/L urea and 0.04 g/L potassium dihydrogen phosphate, with no need of adding carbon sources or adjusting pH. When the bioflocculant was used to flocculate PSW, the optimal dosage was 0.1 mL/L with addition of 5 mL/L 10% CaCl2 as coagulant aid, and there was no need to adjust pH. After flocculation, COD and turbidity removal rates of the PSW could reach 54.09% and 92.11%, respectively, and 1.1g/L proteic substance was recycled from the PSW as a byproduct that could be used for animal feed.
