Air Leakage Characteristics of Gas Boreholes in Deep Coal Seams and Application of Short-Hole Grouting and Plugging.

Drilling for gas extraction is widely used as the main approach to manage gas in mines. However, gas leakage during borehole extraction reduces the root cause of the effectiveness of gas extraction. Given that forming a normal hole in the prominent coal seam of the Qingdong Coal Mine is impossible and that air leakage leads to difficulties in prepumping gas in the coal seam, we selected coal seam 3# as the object of this study. First, qualitative analysis determined that the air leakage channel restricted effective gas extraction. Second, short-hole grouting and plugging were proposed to increase the concentration and efficiency of gas extraction from the coal wall, forming a barrier by blocking the fissure network in the plastic zone of the surrounding rock of the coal roadway and preventing the air inside the roadway from penetrating into the coal seam and gas extraction drill holes. Finally, evaluation of the gas extraction efficiency between the grouting test and comparison areas indicated that the initial gas extraction concentration of a single hole could reach 89% when the depth of the selected blocking hole was 15 m. Grouting slowly decreased the gas extraction concentration from 72 to 25%, which effectively improved the speed at which the gas content was reduced in the coal body. The study findings provide a field basis for similar mines to improve their gas extraction efficiency and extend their extraction time.

Gas Dispersion Coefficient Test System and Dimensionless Inversion Method for Porous Media.

Due to the complex porous media structure of the longwall gob area, it has been difficult to determine the gas dispersion coefficient of oxygen when studying spontaneous coal combustion in the gob area. In this work, we first designed an experimental device for testing the gas diffusion coefficient of porous media. Then, the distribution law of gas concentration in porous media under different particle size conditions was obtained by experiments. Subsequently, we established a dimensionless mathematical model of gas dispersion in porous media and developed a corresponding numerical simulator based on the finite volume method (FVM). The influence of the dimensionless gas dispersion coefficient on the gas concentration distribution was analyzed, and then a dimensionless inversion method of the gas dispersion coefficient was summarized and put forward. Finally, we obtained the values of the gas dispersion coefficient in the experimental device under different particle size conditions by inversion and discussed its effect on the gas dispersion behavior in porous media. The results show that (1) the distribution of gas concentration obtained from the experimental test and numerical simulation is consistent, which verifies the reliability of our work; (2) the dimensionless gas concentration is the highest near the injection point and gradually decreases along the depth and both sides of the test container; (3) with the increase of the dimensionless gas dispersion coefficient, the distance required for uniform gas mixing in the test container is gradually shortened and the gas dispersion coverage is wider; and (4) the larger pore space facilitates the dispersion behavior of the gas, and the gas dispersion coefficient shows a parabolic trend with the increase of porous medium particle size.

Nondimensional analysis and application of gas desorption and diffusion driven by density gradient in coal particles.

An in-depth understanding of gas diffusion characteristics in coal is of great value to coalbed methane (CBM) production planning and coal mine safety management. However, the mechanism and model of gas diffusion is still unclear, and some methods for determining diffusion coefficients are not accurate enough. Accordingly, a free gas density gradient (FGDG)-driven coal particle gas desorption and diffusion model was established in this work, and numerical solutions were performed via finite difference method (FDM) and dimensionless method. The variation rules of dimensionless gas pressure, gas content, desorption capacity, and desorption rate were obtained. Finally, the application of the dimensionless method in diffusion modeling and diffusion coefficient inversion was discussed. The results show that the dimensionless method can simplify mathematical equation processing and analyze the common phenomena of desorption and diffusion under different parameters. The gas desorption diffusion in coal particles is from the surface to the inside, and there is obvious desorption hysteresis effect. The larger the dimensionless radius or dimensionless time, the smaller the dimensionless gas pressure, gas content, and dimensionless desorption rate. The dimensionless cumulative gas desorption amount increased rapidly first and then tended to flat with dimensionless time. The simulated curve can be easily converted into the variation curves of several different measured parameters, and the diffusion coefficient can be calculated accurately. The prediction curve of the FGDG diffusion model is in good agreement with the experimentally measured data, which verifies its reasonableness. The research content aims to provide some ideas for modeling gas desorption and diffusion behavior.

Numerical simulation and investigation of methane gas distribution and extraction in goaf with U-type ventilation of working face.

The accumulated methane in goaf during coal mining may leak into the working face under the airflow influence, which is possibly causing disasters such as methane gas excessive at the working face and seriously threatening the mine safety. This paper first established a three-dimensional numerical model of the mining area under U-shaped ventilation, introducing the gas state equation, continuity equation, momentum equation, porosity evolution equation, and permeability evolution equation to simulate the airflow field and gas concentration field in the mining area under the natural state. The reliability of the numerical simulations is then verified by the measured air volumes at the working face. The areas in the mining area where gas is likely to accumulate are also delineated. Subsequently, the gas concentration field in goaf under the gas extraction state was theoretically simulated for different locations of large-diameter borehole. The maximum gas concentration in goaf and the gas concentration trend in the upper corner were analyzed in detail, and the critical borehole location (17.8 m from the working face) was determined as the optimum location for gas extraction from the upper corner. Finally, a gas extraction test was carried out on-site to evaluate the application effect. The results show that the measured airflow rate has a small error with the simulated results. The gas concentration in the area without gas extraction is high, with the gas concentration in the upper corner being over 1.2%, which is greater than the critical value of 0.5%. The maximum reduction in gas concentration was 43.9%, effectively reducing the gas concentration in the extraction area after employing a large borehole to extract methane gas. The gas concentration in the upper corner and the distance of the borehole from the working face are expressed as a positive exponential function. The field engineering results show that the implementation of the large borehole at a distance of less than 17.8 m from the working face can control the gas in the upper corner to less than 0.5%, effectively reducing the risk of gas in the upper corner. The numerical simulation work in this paper can provide some basic support for the design of an on-site borehole to extract gas from the mining void and reduce the gas hazard in coal mines.

Estimation of thermal hazards in surrounding rock of subway tunnel under dual periodic temperature boundaries: a case study.

Thermal hazards of the surrounding rock of subway tunnels are becoming apparent, in which the heat transfer in the surrounding rock plays a crucial role. Due to the shallow buried depth, the subway tunnel encounters a more complicated heat exchange under the duplicate effects of periodic temperature fluctuation of ground atmosphere and periodic temperature variation of tunnel wind, but this issue has not been fully addressed. In this work, a transient heat transfer model of tunnel surrounding rock based on dual periodic temperature boundaries was established. A solver was developed to estimate the temperature rise and heat transfer of surrounding rock. The correctness of this model was then verified by comparing with previous empirical values and semi-empirical equations. The results show that the temperatures of the surrounding rock at different depths still fluctuate following the simple harmonic waves, and there are some regions that are heavily affected by the duplicate effects, such as the overlying strata of the tunnel. The surrounding rock generally exhibits heat storage in annual cycle, but the total heat storage decreases year by year until it tends to stabilize. Furthermore, the shallower the tunnel is buried, the greater the influence of ground temperature and the higher the temperature rise in the tunnel surrounding rock. This research provides an alternative approach to determine the heat storage of tunnel surrounding rock and evaluates the process of thermal disaster manifestation of subway.

Metal-organic Framework ZIF-67 Functionalized MXene for Enhancing the Fire Safety of Thermoplastic Polyurethanes.

In this work, a novel functionalization strategy for ZIF-67-modified layered MXene was proposed, aiming at improving the fire safety of thermoplastic polyurethanes (TPU). The ZIF-67@MXene was verified by microscopic morphology, elemental composition, functional group species and crystal structure, and then the successfully prepared ZIF-67@MXene was introduced into the TPU material. When ZIF-67@MXene content was only 0.5 wt%, the peak heat release rate, total heat release rate, peak smoke release rate, total smoke release rate, and CO yield of the TPU/ZIF-67@MXene composites were reduced by 26%, 9%, 50%, and 22%, respectively, compared with the pure TPU. The thermogravimetric tests showed that the residual char of TPU/ZIF-67@MXene composites was the most in all samples. In short, the high-quality carbon layer of TPU/ZIF-67@MXene composites acts as a physical barrier to the transfer of heat and toxic gases, greatly improving the flame retardant properties of the TPU polymer.

Continuous monitoring system of gob temperature and its application.

Due to the concealment of the fire source in the gob, the fire prevention and extinguishing work in the gob is facing great difficulties. This study is made in order to realize the real-time monitoring of gob temperature and the accurate positioning of high temperature area, so that the fire prevention and extinguishing work in gob can be targeted. In this study, the previously developed COMBUSS-3D software was used to predict the high temperature area in the gob of 85001 working face of Yangmeiwu Coal Mine and II830 working face of Zhuxianzhuang Coal Mine in China, and the continuous monitoring system of gob temperature was independently developed to realize the real-time monitoring of gob temperature, achieving the purpose of accurate positioning of high temperature area in gob. The results show that the high temperature area of the gob of 85001 working face of Yangmeiwu Coal Mine was in the range of approximate circle centered on the point (36.6, 30), and the maximum temperature was 31.7 °C. The high temperature area of the gob of II830 working face in Zhuxianzhuang Coal Mine presented an approximate ellipse centered on (28.2, 25), and the long axis was parallel to the working face, and the maximum temperature was 43.9 °C. The research results are expected to provide reference for the early prediction of spontaneous combustion in gob.

A comprehensive method to prevent top-coal spontaneous combustion utilizing dry ice as a fire extinguishing medium: test apparatus development and field application.

There is a high potential for coal spontaneous combustion (CSC) above the roof beams of supports during the mining-stopped period. Early detection of temperature abnormal zones and corresponding measures are necessary to prevent CSC. In this work, a top-coal temperature measurement method was proposed, combining the coal surface temperature detection and the drilling temperature observation. Furthermore, an apparatus was developed that dramatically increases the rate of dry ice sublimation, resulting in the rapid release of cryogenic carbon dioxide gas. The device utilizes water from firefighting pipes in underground coal mines as a heat source for dry ice sublimation without electrical energy and has been applied and validated taking Silaogou Coal Mine in China as a field test site. Specifically, we found that during the stoppage period, the coal above the supports near the air inlet tunnel is more likely to appear hot spots; the carbon dioxide gas generated by the dry ice phase change device can quickly reduce the hot spots temperature, and the coal temperature does not rebound after the gas injection is stopped. Based on the above analysis, this work can effectively prevent the early top-coal spontaneous combustion during the stop mining period.