1.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 3): o518, 2010 Feb 03.
Article
in English
| MEDLINE
| ID: mdl-21580292
ABSTRACT
In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia-zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08â (2)°] because the N-C-C-N-C chain that links the two rings is folded [N-C-C-N torsion angle = 12.0â (2)°] rather than fully extended. An intra-molecular N-Hâ¯N inter-action occurs. In the crystal, weak inter-molecular N-Hâ¯N and C-Hâ¯O inter-actions are present and π-π inter-actions are indicated by the short distances [3.507â (3)-3.665â (2)â Å] between the centroids of the thia-zole and benzene rings.