ABSTRACT
Surfaces with nanostructure patterning are broadly encountered in nature, and they play a significant role in regulating various phenomena such as phase transition at the liquid/solid interface. Here, we designed two kinds of template substrates with periodic nanostructure patterns [i.e., nanotrench (NT) and nanopore (NP)]. Surface nanodroplets produced on these nanostructure surfaces were characterized to acquire their morphology and wetting properties. We show that nanostructure patterning could effectively regulate the shape, contact radius, and nucleate site of nanodroplets. While nanodroplets on the NT structure are constrained in one dimension, nanodroplets on the NP structure have enhanced the wetting property with constraints from two dimensions. Further numerical analysis indicates that the morphology and contact angles of nanodroplets on the NT structure depend on the substrate wettability and the droplet volume. These observations demonstrate how physical geometry and chemical heterogeneity of a substrate surface affect the growth and spreading of surface nanodroplets, which deepens our understanding on nanoscale phase separation.
ABSTRACT
The existence of bulk nanobubbles is still controversial in spite of their significance in a large range of applications. Here, we developed a new method of compression-decompression to produce controllably bulk nanobubbles. Then, we further investigated the generation of bulk nanobubbles in pure water, acid, alkaline, and salt solutions using nanoparticle tracking analysis. The results indicated that the concentration of bulk nanobubbles depends on the decompression time and would reach a maximum value when the decompression time is about 30 min for the pure water system. More importantly, we gave a relatively direct evidence of the existence of bulk nanobubbles by measuring the X-ray fluorescence intensity of Kr in acid, alkaline, and salt solutions. It is shown that the decrease tendency in intensity of Kr in alkaline solution is similar to that in the concentration of bulk nanobubbles with the deposited time, indicating that the bulk nanobubbles produced indeed have gas inside. Furthermore, the concentration and stability of bulk nanobubbles in an alkaline solution are greatest compared with other two solutions regardless of gas types. The concentration of bulk nanobubbles will decrease in the order alkaline > acid/pure water > salt solutions. We believe that our results should be very helpful in understanding the formation and stability of bulk nanobubbles in different solutions.
ABSTRACT
Dissolved air flotation (DAF) is broadly applied in wastewater treatment, especially for the recovery of organic pollution with low concentration. However, the mechanism of interaction between nanoscale gas bubbles and nanoparticles in the process of DAF remains unclear. Here, we investigated the role of nanobubbles in the precipitation of styryl phosphoric acid (SPA)-Pb particles and recovering organic phosphine containined in beneficiation wastewater by UV-vis (ultraviolet-visible) spectra, microflotation tests, nanoparticle tracking analysis, dynamic light scattering, and atomic force microscopy measurements. As suggested from the results, nanobubbles can inhibit the crystallization of SPA-Pb precipitation, which makes the sediment flotation recovery below 20%. After the precipitation crystallization is completed, nanobubbles can flocculate precipitated particles, which can promote the flotation recovery of precipitated particles to 90%. On the basis of the results, we proposed a model to explain the different roles of nanobubbles in the process of precipitation and flotation of SPA-Pb particles. This study will be helpful to understand the interaction between nanobubbles and nanoparticles in the application of flotation.
ABSTRACT
BACKGROUND: High order modulation and demodulation technology can solve the frequency requirement between the wireless energy transmission and data communication. In order to achieve reliable wireless data communication based on high order modulation technology for visual prosthesis, this work proposed a Reed-Solomon (RS) error correcting code (ECC) circuit on the basis of differential amplitude and phase shift keying (DAPSK) soft demodulation. Firstly, recognizing the weakness of the traditional DAPSK soft demodulation algorithm based on division that is complex for hardware implementation, an improved phase soft demodulation algorithm for visual prosthesis to reduce the hardware complexity is put forward. Based on this new algorithm, an improved RS soft decoding method is hence proposed. In this new decoding method, the combination of Chase algorithm and hard decoding algorithms is used to achieve soft decoding. In order to meet the requirements of implantable visual prosthesis, the method to calculate reliability of symbol-level based on multiplication of bit reliability is derived, which reduces the testing vectors number of Chase algorithm. The proposed algorithms are verified by MATLAB simulation and FPGA experimental results. During MATLAB simulation, the biological channel attenuation property model is added into the ECC circuit. RESULTS: The data rate is 8 Mbps in the MATLAB simulation and FPGA experiments. MATLAB simulation results show that the improved phase soft demodulation algorithm proposed in this paper saves hardware resources without losing bit error rate (BER) performance. Compared with the traditional demodulation circuit, the coding gain of the ECC circuit has been improved by about 3 dB under the same BER of [Formula: see text]. The FPGA experimental results show that under the condition of data demodulation error with wireless coils 3 cm away, the system can correct it. The greater the distance, the higher the BER. Then we use a bit error rate analyzer to measure BER of the demodulation circuit and the RS ECC circuit with different distance of two coils. And the experimental results show that the RS ECC circuit has about an order of magnitude lower BER than the demodulation circuit when under the same coils distance. Therefore, the RS ECC circuit has more higher reliability of the communication in the system. CONCLUSIONS: The improved phase soft demodulation algorithm and soft decoding algorithm proposed in this paper enables data communication that is more reliable than other demodulation system, which also provide a significant reference for further study to the visual prosthesis system.
