Determination of threshold values and heavy metal pollution assessment of soils in an industrial area in Ghana.

Industrial activities have the potential to pollute soils with a wide variety of heavy metals (HMs). In Ghana, however, assessment of HM pollution of soils in industrial areas remains limited. Accordingly, HM soil pollution in one of the industrial areas in Accra, Ghana was assessed. Soil samples were taken and analysed for HMs, including Fe, Zr, Zn, Ti, Sr, Rb, Mn, Pb, Cu, and Co, using X-Ray Fluorescence (XRF). HM geochemical threshold values (GTVs) were determined to establish soil HM pollution levels and identify areas needing remediation. Furthermore, risk assessments were conducted to evaluate the potential ecological and human health risks associated with these metals. The mean concentrations of Fe, Zn, Rb, Sr, Zr, Ti, Mn, Co, Cu, and Pb in the soils were: 27133.83, 147.72, 16.30, 95.95, 307.11, 4663.66, 289.85, 418.54, 44.97, and 112.88 mg/kg, respectively. Generally, the concentrations of HMs decreased with depth, although some lower layers exhibited elevated HM levels. Soil pollution levels were categorized as low for Fe, Rb, Zr, Ti, Mn, Co, and Cu; moderate for Sr and Zn; and considerable for Pb. Notably, the northwestern part of the study area displayed a considerable to very high degree of HM contamination. While HMs in the soils posed low ecological risk, the human health risk assessment indicated potential health effects from Co, particularly in children. The presence of HMs in the soils was noted to originate from both natural geological phenomena and human activities, including industrial operations, agricultural practices, landfill activities, and vehicular emissions.

Adsorptive removal of dissolved Iron from groundwater by brown coal - A low-cost adsorbent.

Iron (Fe) contamination in groundwater is a widespread issue, necessitating the implementation of efficient removal methods to ensure the provision of safe drinking water. To contribute to the development of effective and sustainable solutions for addressing Fe contamination problems, this study investigated the potential of natural brown coal (BC) as a cost-effective adsorbent for removing dissolved Fe from groundwater. The study also explored the regeneration and reusability potential, as well as the effects of operational parameters, including pH, temperature, adsorbate concentration, and competitive ions, on the adsorption process. The equilibrium data fitted very well with the Langmuir model (R2 = 0.983), yielding a maximum adsorption capacity of 1.41 mg g-1. The adsorption kinetics were well described by the pseudo-second-order kinetic model. Notably, higher solution pH, Fe concentration, and temperature values led to higher Fe removal. The adsorption process exhibited endothermic behaviour, accompanied by an increase in randomness at the interface between the BC and the Fe. The BC was easily regenerated and maintained good adsorption capacity after four cycles of adsorption and regeneration. However, the presence of high-valent cations could affect its performance. Fourier-transform infrared spectrometry, coupled with structural and aqueous solution elemental analyses, revealed a synergetic adsorption mechanism, comprising ion-exchange with mono and divalent basic cations and complexation with functional groups. Overall, these findings highlight the potential of brown coal as a cost-effective adsorbent for Fe removal from groundwater.