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An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes.
Bortolini, O; Chiappe, C; Fogagnolo, M; Giovannini, P P; Massi, A; Pomelli, C S; Ragno, D.
Chem Commun (Camb) ; 50(16): 2008-11, 2014 Feb 25.
Article in English | MEDLINE | ID: mdl-24413829

ABSTRACT

N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy.


Subject(s)
Aldehydes/chemistry , Carboxylic Acids/chemical synthesis , Heterocyclic Compounds/chemistry , Methane/analogs & derivatives , Carboxylic Acids/chemistry , Catalysis , Methane/chemistry , Molecular Structure , Oxidation-Reduction
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