Modification strategies of lead halide perovskite nanocrystals for efficient and stable LEDs.

Lead halide perovskite nanocrystals (PNCs) hold immense promise in high-performance light-emitting diodes (LEDs) for future high-definition displays. Their adjustable bandgaps, vivid colors, and good carrier mobility are key factors that make them a potential game-changer. However, to fully harness their potential, the efficiency and long-term stability of PNCs-based light-emitting diodes (PNC-LEDs) must be enhanced. Recent material research results have shed light on the leading cause of performance decline in PNC-LEDs, which is ionic migration linked to surface defects and grain boundary imperfections. This review aims to present recent advancements in the modification strategies of PNCs, focusing on obtaining high-quality PNCs for LEDs. The PNC modification strategies are first summarized, including crystal structure regulation, nanocrystal size tuning, ligand exchange, and surface passivation. Then, the effects of these material design aspects on LED device performances, such as efficiency, brightness, and stability, are presented. Based on the efficient modification strategies, we propose promising material design insights for efficient and stable PNC-LEDs.

Do natural resources affect environmental quality in MINT Economies? The role of tourism and financial development.

With the growing nature of the ecological footprint, research studies focus on exploring new determinants of environmental degradation. Moreover, the role of natural resources and energy consumption in environmental quality has gained much attention in the literature. However, tourism raises the demand for energy consumption and extraction of natural resources. This research study investigates the influence of natural resources, tourism, and renewable energy in MINT countries, using novel Cross-Sectional Auto Regressive Distributive Lag (CS-ARDL) methodological techniques and employing yearly data from 1995 to 2018. The study also applied recently developed Kónya (Econ Model 23:978-992, 2006) causality to identify the causal relationship between the variables of the heterogenous panel. The result shows that tourism, natural resources, and economic growth are positively associated with the ecological footprint in the long-run. However, renewable energy consumption negatively impacts ecological footprint in both in short-run and the long-run. Further, the study explored a bidirectional causality between economic growth and ecological footprint in MINT countries. Finally, based on the empirical results, the study recommends that the authorities in MINT countries revisit their tourism, natural resources, and economic activities policies to enhance the environmental quality and reduce the ecological footprint.

Investigating the financial market development and shadow economy nexus in the presence of country risk in an emerging economy.

This research study examined the influence of financial market development on the shadow economy and the moderating effect of country risk (political, economic, and financial) in this nexus in Pakistan. Using data from 1995 to 2018, the study applied the Augmented Dickey-Fuller (ADF) and Phillips-Perron (PP) unit root tests, followed by the F-bounds test to investigate stationarity and cointegration in the series, respectively. The study utilized the Autoregressive Distributed Lag (ARDL) approach to estimate the long-run relationship, and to examine the possible causal relationship among the variables, the study employed Breitung and Candelon's (2006) spectral test. The study identified that financial market development is negative, and the country's risk determinants are positively associated with the shadow economy's size. Moreover, the study found that country risk positively moderates the influence of financial market development on the shadow economy. The results also highlighted a unidirectional relationship from economic and financial risk towards the shadow economy. Finally, based on the empirical findings, the study recommends some policy implications to the regulators of financial markets and the shadow economy.

Bibliometric analysis of finance and natural resources: past trend, current development, and future prospects.

The finance and natural resources revenue nexus play a critical role in an economy. The recent development and significant increase in academic literature regarding the resource-finance nexus are the primary motivations for conducting this study. This study aims to conduct a bibliometric analysis of 363 documents published between 1976 and 2021 collected from the Scopus database. The results have been demonstrated via graphs, tables, knowledge maps about the past trends, growth, and prospects using co-occurrence, co-authorship, and co-citation analysis via the VOSviewer tool. This study has identified prolific authors, journals, countries, academic institutions, and future pathways. The findings indicate that China has the highest share of publications (88, 24.2%), followed by Pakistan (58, 15.9%) and Turkey (37, 10.2%). The most productive academic institution is the Beijing Institute of Technology in China (13, 3.6%). This study proposes new avenues for further research concerning the resource-finance nexus, such as ecological footprint, sustainability, fiscal decentralization, green investment, energy prices, environmental quality, technological innovation, financial resource curse (especially the stock market resource curse), human capital, and renewable energy in policy development and sustainability towards the achievement of the SDGs.

Do health expenditure and human development index matter in the carbon emission function for ensuring sustainable development? Evidence from the heterogeneous panel.

This study is an attempt to explain the nexus between health expenditures, GDP, human development index (HDI), CO2 emissions (COEM), renewable energy (RENE), financial development (FD) and electricity consumption (EC) using data from 2000Q1 to 2014Q4 for Brazil, India, China and South Africa. The study applies CIPS and CADF to determine the integration order. The tests confirmed the unique order of integration. The study further uses the Westerlund panel cointegration, which suggests the existence of a long-run relationship. Moreover, the panels dynamic ordinary least squares (DOLS) and fully modified ordinary least squares (FMOLS) are applied to ascertain the long-run elasticity. The health expenditure and electricity consumption affect the COEM positively. Moreover, HDI and RE affect COEM negatively. The study further confirms the existence of an N-shaped EKC in the long run. The pairwise Dumitrescu and Hurlin, Econ Model 29:1450-1460, (2012) test is used to uncover the direction of the association between the variables. The findings obtained from DH confirm a bidirectional causality between HDI and FD. Likewise, another bidirectional causal relationship has also been found between FD and EC. The findings of our study advocate policies in the direction of HDI and health expenditure by adopting RENE. This study highlights the importance of RENE, which can facilitate a reduction in carbon emissions and decreasing health expenditures. Moreover, the financial sector needs to be improved to create entrepreneurship opportunities for the public in improving the HDI in ensuring sustainable development.

Chemical mismanagement and skin burns among hospitalized and outpatient department patients.

Purpose. This article attempts to elucidate the nature of chemicals causing major and minor skin burns, and their associated characterization across different industries, using Fujian provincial hospitals' admission and outpatient department records. Materials and methods. Data were collected from the provincial hospitals of Fujian through a questionnaire, sent via email, from June 1, 2017 to November 30, 2017. The collected responses were statistically analyzed using SPSS version 19 through the interquartile range, median, Mann-Whitney U test and Fisher's exact test with two-tailed significance. Results and conclusions. The results of 306 collected responses reveal that the majority of skin burn cases are due to a lack of technical education and professional training among workers handling chemicals. This study suggests that management's effective supervision and governmental regulations may help to prevent chemical skin burns at work, and can further be controlled by hiring professional workers alongside providing training to them in chemical handling as well as using protective equipment and developing appropriate management policies to improve victims' well-being and quality of life. Findings will help workers, doctors, hospitals, industries, government and other stakeholders to understand and control chemical hazards on site to minimize the risks of chemical skin burn incidents.

Synthesis and Characterization of Polyaniline-Chitosan Patches with Enhanced Stability in Physiological Conditions.

Electroconductive polymeric patches are being developed in the hope to interface with the electroresponsive tissues. For these constructs, conjugated polymers are considered as conductive components for their electroactive nature. Conversely, the clinical applications of these conductive polymeric patches are limited due to their short operational time-a decrease in their electroactivity occurs with the passage of time. This paper reports on the polymerization of aniline on prefabricated chitosan films on microscopic glass slides in the presence of sodium phytate. The strong chelation among sodium phytate, aniline and chitosan led to the formation of electoconductive polymeric patch. We assume that immobilization of sodium phytate in the polymeric patch helps to prevent electric deterioration, extend its electronic stability and reduce sheet resistance. The patch oxidized after three weeks (21 days) of incubation in phosphate buffer (pH 7.4 as physiological medium). This feasible fabrication technique set the foundation to design electronically stable, conjugated polymer-based patches, by providing a robust system of conduction that could be used with electroactive tissues such as cardiac muscles at the interface.

3D Polyaniline Nanofibers Anchored on Carbon Paper for High-Performance and Light-Weight Supercapacitors.

In the field of advanced energy storage, nanostructured Polyaniline (PANI) based materials hold a special place. Extensive studies have been done on the application of PANI in supercapacitors, however, the structure-property relationship of these materials is still not understood. This paper presents a detailed characterization of the novel sodium phytate doped 3D PANI nanofibers anchored on different types of carbon paper for application in supercapacitors. An excellent relationship between the structures and properties of the synthesized samples was found. Remarkable energy storage characteristics with low values of solution, charge transfer and polarization resistance and a specific capacitance of 1106.9 ± 1.5 F g-1 and 779 ± 2.6 F g-1 at current density 0.5 and 10 Ag-1, respectively, was achieved at optimized conditions. The symmetric supercapacitor assembly showed significant enhancement in both energy density and power density. It delivered an energy density of 95 Wh kg-1 at a power of 846 W kg-1. At a high-power density of 16.9 kW kg-1, the energy density can still be kept at 13 Wh kg-1. Cyclic stability was also checked for 1000 cycles at a current density of 10 Ag-1 having excellent retention, i.e., 96%.

Coastline extraction and land use change analysis using remote sensing (RS) and geographic information system (GIS) technology - A review of the literature.

Coastlines mapping techniques or the coastline automated analyses have been sought after. In practice, various sorts of seacoasts, for example, biological, silty, arenaceous, artificial, and bedrock coasts, have their own attributes, which force various degrees of intricacy on coastline mapping. As an extraordinary kind of complex artificial coast, aquaculture coast is shaped by the farming of aquatic organisms on silt tidal flats. With the rapid growth of coastal aquaculture in recent years, aquaculture coasts have increased in some developing countries. It has been estimated that aquaculture coasts constitute about 30% of all coastlines in mainland China. In order to identify, monitor, model, and manage the vast expanse of coastal aquaculture, effective methods of extracting aquaculture coastlines from remotely sensed imagery are desired. Secondly, with the rapid economic development in coastal areas, the development of coastal zone resources is also increasing day by day, which benefits the development of island coastal zone. Using oneself has become an important link in the development of marine economy. Due to the limited coastal resources and low environmental carrying capacity, the overexploitation and utilization of coastal resources will lead to a series of problems, such as coastal erosion, coastal migration and accumulation, island area reduction, etc., Both man-made activities and natural factors will lead to coastline changes, which will lead to corresponding changes in coastal ecological environment, thus affecting the coordinated development of coastal economy and the survival of coastal residents. Therefore, efficient, accurate and timely acquisition of coastline information and research on the spatial-temporal changes of coastline are of great significance to the protection of the living environment of coastal residents, the effective development of island and coastal resources, the coordination of sustainable economic development in coastal areas and the mitigation of marine disasters. This paper presents a review of those papers reporting coastline extraction and land use and land cover (LULC) change analysis using remote sensing (RS) and geographic information system (GIS) technology.

Potassium Bromide Surface Passivation on CsPbI3-xBrx Nanocrystals for Efficient and Stable Pure Red Perovskite Light-Emitting Diodes.

All-inorganic lead halide perovskite nanocrystals (NCs) are potential candidates for fabricating high-performance light-emitting diodes (LEDs) owing to their precisely tunable bandgaps, high photoluminescence (PL) efficiency, and excellent color purities. However, the performance of pure red (630-640 nm) all-inorganic perovskite LEDs is still limited by the halide segregation-induced instability of the electroluminescence (EL) of mixed halide CsPbI3-xBrx NCs. Herein, we report an effective approach to improving the EL stability of pure red all-inorganic CsPbI3-xBrx NC-based LEDs via the passivation of potassium bromide on NCs. By adding potassium oleate to the reaction system, we obtained potassium bromide surface-passivated (KBr-passivated) CsPbI3-xBrx NCs with pure red PL emission and a photoluminescence quantum yield (PLQY) exceeding 90%. We determine that most potassium ions present on the surface of NCs bind with bromide ions and thus demonstrate that potassium bromide surface passivation of NCs can both improve the PL stability and inhibit the halide segregation of NCs. Using KBr-passivated CsPbI3-xBrx NCs as an emitting layer, we fabricated stable and pure red perovskite LEDs with emission at 637 nm, showing a maximum brightness of 2671 cd m-2, maximum external quantum efficiency of 3.55%, and good EL stability. The proposed KBr-passivated NC strategy will open a new avenue for fabricating efficient, stable, and tunable pure color perovskite NC LEDs.

Challenges and Solutions in Multimodal Medical Image Subregion Detection and Registration.

BACKGROUND: The automatic detection of common subregions and registration in multimodal functional and structural images is challenging. This article gives an overview of multimodal image registration and the developments and technical issues with automatic detection and registration of subregions of interest in multimodal images. DISCUSSION: The available knowledge about subregion detection and registration in multimodal images are described in detail. Besides the provision of compact knowledge on subregion detection and registration, the challenges and proposed solutions are also discussed. CONCLUSION: This article provides research guidelines for the development of automatic detection and registration of subregions of interest in functional and structural images with high accuracy and efficiency.

Evaluation of Medical Image Registration Techniques Based on Nature and Domain of the Transformation.

A lot of research has been done during the past 20 years in the area of medical image registration for obtaining detailed, important, and complementary information from two or more images and aligning them into a single, more informative image. Nature of the transformation and domain of the transformation are two important medical image registration techniques that deal with characters of objects (motions) in images. This article presents a detailed survey of the registration techniques that belong to both categories with detailed elaboration on their features, issues, and challenges. An investigation estimating similarity and dissimilarity measures and performance evaluation is the main objective of this work. This article also provides reference knowledge in a compact form for researchers and clinicians looking for the proper registration technique for a particular application.