1.
Inorg Chem
; 53(6): 2892-8, 2014 Mar 17.
Article
in English
| MEDLINE
| ID: mdl-24559083
ABSTRACT
A family of virtually isostructural tetra-capped ε-Keggin-type polyoxomolybdate(V) cluster compounds, [Mo12(V)O28(µ(2)OH)10(µ(3)OH)2{M(II)(H2O)3}4]·nH2O ({M4(II)Mo12(V)}, M = Ni, Co), exhibits magnetic-field-dependent optical response in their electronic absorption spectra in the 033 T range. On the basis of Effective Hamiltonian Crystal Field calculations, we find that the observed field-induced decrease in reflectance of these compounds can be related to the formally spin-forbidden on-site dd excitations. We tentatively position the observed effect among other known magneto-optical effects and predict that similar features may be found for other {M49(II)Mo12(V)} analogues.
2.
J Indian Med Assoc
; 50(6): 243-6, 1968 Mar 16.
Article
in English
| MEDLINE
| ID: mdl-5653850