Magnetic Application of Gadolinium Orthoferrite Nanoparticles Synthesized by Sol-Gel Auto-Combustion Method.

In this manuscript, we present the synthesis of gadolinium orthoferrite nanoparticles using the sol-gel auto-combustion technique. The obtained gadolinium orthoferrite nanoparticles were annealed at various temperatures, such as 800 °C, 900 °C, 1000 °C, and 1100 °C. The synthesized materials were analyzed by various instrumental characterizations. The vibrational characteristics of the synthesized samples were verified by FTIR. The surface morphology of the gadolinium orthoferrite nanoparticles was analyzed by FE-SEM and HR-TEM, revealing their spherical structural morphology and uniform particle structure. The presence of the elemental features was analyzed in the gadolinium orthoferrite nanoparticles by EDAX. The surface analysis of the core ranges of the XPS-recorded spectra were obtained for the elemental states of the Gd, Fe, and O factors in the samples, and it additionally characterized the different levels of oxidative states by fitting the levels of the high-resolution parameters of Gd 4d, Fe 2p, and O 1s. The magnetic properties of the samples were investigated by VSM. The measurement of the magnetic parameters revealed that gadolinium orthoferrite nanoparticles exhibit a ferromagnetic nature.

Extraction and characterization of chitin from sea snail Conus inscriptus (Reeve, 1843).

The chitin was extracted from C. inscriptus and the structure was elucidated. The yield of the C. inscriptus shell chitin was 21.65% on dry weight basis. The ash and moisture content of the chitin was 1.2 and 6.50%. The result of the molecular analysis of the chitin revealed low molecular weight (25 kDa). The crystalline structure (XRD), functional group (FT-IR), elemental analysis (EDAX), surface morphology (SEM) and thermal stability (TG/DTA) results confirmed conus chitin was in α-crystalline form. The crystalline index value (CrI) of the conus chitin was 82.13%. The FT-IR analysis of the conus chitin displayed two bands at around 1730 and 1628 cm-1. SEM investigation of the commercial chitin and C. inscriptus chitin exposed that it was composed of nanopore and nanofibre structures. Further, the thermal stability of the conus chitin was close to the thermal stability of the commercial chitin. The results show that processing of C. inscriptus shell can lead to a high quality chitin, useful for a broad range of applications.