Humidity activated ultra-selective room temperature gas sensor based on W doped MoS2/RGO composites for trace level ammonia detection.

The lack of highly efficient, cost effective and stable ammonia gas sensors functionable at room temperature even in extreme humid environments poses significant challenge for the future generation gas sensors. The prime factors that impede the development of such next generation gas sensors are the strong interference of humidity and sluggish selectivity. Herein, we fabricated tungsten doped molybdenum disulphide/reduced graphene oxide composite by an in-situ hydrothermal method to exploit the adsorption, dissolution (solubility), ionization and transmission process of ammonia and thereby to effectuate its trace level detection even in indispensable humid environments. The protype based on 5 at.% Tungsten doped MoS2/RGO (W5) gas sensor exhibited 3.8-fold increment in its response to 50 ppm of ammonia when the relative humidity varied from 20 % to 70 % with ultra-high selectivity at room temperature. The as prepared gas sensor revealed a practical detection limit down to 1 ppm with a substantial response and rapid recovery time. Furthermore, W5 gas sensor exhibited a 42-fold increment in response to 50 ppm of ammonia relative to its pristine (MoS2/RGO) MG composite with a RH of 70 %. The proton hopping mechanism accountable for such an enormous enhancement in ammonia sensing and its potential for breath sensor are briefly annotated.

Electronic sensitization enhanced p-type ammonia gas sensing of zinc doped MoS2/RGO composites.

Zinc (Zn) doping induced synergetic effects of defects engineering and heterojunction in Molybdenum disulphide/Reduced graphene oxide (MoS2/RGO) effectively enhances the p-type Volatile organic compounds (VOC) gas sensing traits and helps in tailoring the over dependence on noble metals for surface sensitization. Through this work, we have successfully prepared Zn doped MoS2 grafted on RGO employing an in-situ hydrothermal method. Optimal doping concentration of Zn dopants in the MoS2 lattice triggered more active sites on the basal plane of MoS2 with the aid of defects promoted by the zinc dopants. Effective intercalation of RGO further boost up the exposed surface area of Zn doped MoS2 for further interaction of ammonia gas molecules. Besides, smaller crystallite size brought out by 5% Zn dopants aids in efficient charge transfer across the heterojunctions that further amplifies the ammonia sensing traits with a peak response of 32.40% along with a response time of 21.3 s and recovery time of 44.90 s. The as prepared ammonia gas sensor exhibited excellent selectivity and repeatability. The obtained results reveal that transition metal doping into the host lattice proves to be a promising approach for VOC sensing characteristics of p-type gas sensors and gives insight about the importance of dopants and defects for the development of highly efficient gas sensors in the future.

A radially controlled ZnS interlayer on ultra-long ZnO-Gd2S3 core-shell nanorod arrays for promoting the visible photocatalytic degradation of antibiotics.

Nanorod (NR) arrays offer commendable visible-light-driven photocatalytic performances. Herein, we describe the construction of a ternary ZnO-ZnS-Gd2S3 nanostructural array in which a sulfidation process is used to decorate a Gd2S3 shell layer with a ZnS interface over vapor-phase-grown vertically-aligned ZnO. With control over the shell-wall thickness, the shell layer of ∼25 nm wall thickness on the ultra-long ZnO NR arrays exhibited a higher catalytic efficiency close to 3.3, 2.0, 1.2, and 1.8 times those of the bare ZnO, the ZnO-ZnS, the Gd2S3-decorated (∼10 nm) and Gd2S3 shell-layered (∼40 nm) ZnO-ZnS core-shell structures, respectively. The core-shell geometry and the shell-wall thickness with maximized contact interface afforded increased light absorption in the visible region and effectively retarded the recombination rate of the photoinduced charge carriers by confining electrons and holes separately, thus providing advantages in terms of the degradation of the pharmaceutical residue tetracycline and the industrial pollutant 4-nitrophenol in wastewater.

Recent progress on the synthesis and applications of carbon based nanostructures.

This article reviews the latest developments in the synthesis of Graphene, Carbon nanotubes and graphene/CNT based devices based on patents, patent applications and articles published in the last two years. A brief introduction about CNT and Graphene is presented, followed by the latest techniques and advanced processing for the large scale synthesis of Graphene and CNTs. Furthermore, a brief account of emerging devices based on applications of CNTs and graphene not limited to sensors, high speed electronics, energy harvesting and storage applications are presented.

Nanobits: customizable scanning probe tips.

We present here a proof-of-principle study of scanning probe tips defined by planar nanolithography and integrated with AFM probes using nanomanipulation. The so-called 'nanobits' are 2-4 microm long and 120-150 nm thin flakes of Si(3)N(4) or SiO(2), fabricated by electron beam lithography and standard silicon processing. Using a microgripper they were detached from an array and fixed to a standard pyramidal AFM probe or alternatively inserted into a tipless cantilever equipped with a narrow slit. The nanobit-enhanced probes were used for imaging of deep trenches, without visible deformation, wear or dislocation of the tips of the nanobit after several scans. This approach allows an unprecedented freedom in adapting the shape and size of scanning probe tips to the surface topology or to the specific application.