ABSTRACT
Nickel, a prevalent metal in the ecosystem, is released into the environment through various anthropogenic activities, leading to adverse effects. This research explored utilizing zeolite scony mobile-5 (ZSM-5) nanoparticles encapsulated in sodium alginate (SA) for nickel (II) removal from aqueous solutions. The adsorption characteristics of SA/ZSM-5 were examined concerning contact duration, initial metal ion concentration, pH level, temperature, and sorbent dosage. The findings revealed that a rising pH reduced Ni (II) uptake by the sorbent while increasing the Ni (II) concentration from 25 to 100 mg L-1 led to a decrease in removal percentage from 91 to 80% under optimal conditions. Furthermore, as sorbent dosage increased from 4 to 16 g L-1, uptake capacity declined from 9.972 to 1.55 mg g-1. Concurrently, SA/ZSM-5 beads' Ni (II) sorption capacity decreased from 96.12 to 59.14% with a temperature increase ranging from 25 to 55 °C. The Ni (II) sorption data on SA/ZSM-5 beads are aptly represented by Langmuir and Freundlich equilibrium isotherm models. Moreover, a second-order kinetic model characterizes the adsorption kinetics of Ni (II) on the SA/ZSM-5 beads. A negative free energy change (ΔG°) demonstrates that the process is both viable and spontaneous. The negative enthalpy values indicate an exothermic nature at the solid-liquid interface while negative entropy values suggest a decrease in randomness. In conclusion, this novel adsorbent exhibits promise for removing nickel from aqueous solutions and could potentially be employed in small-scale industries under similar conditions.
ABSTRACT
The aim of the present study is to explore the variation of heat on MHD Williamson hybrid nanofluid (Ag-TiO2/H2O) model for steady two-dimensional and incompressible flow with a convective boundary condition in a curved coordinate porous system with Ohmic heating. Nusselt number is distinguished by the process of thermal radiation. The partial differential equations are controlled by the curved coordinate's porous system, which depicts the flow paradigm. Employing similarity transformations, the acquired equations were turned into coupled non-linear ordinary differential equations. The governing equations were disbanded by RKF45 via shooting methodology. The focus is on examining physical characteristics such as heat flux at the wall, temperature distribution, velocity of flow, and surface friction coefficient for a variety of related factors. The analysis explained that increasing permeability, Biot and Eckert numbers enhance temperature profile and slowdown heat transfer. Moreover, convective boundary condition and thermal radiation enhance the friction of the surface. The model is prepared as an implementation for solar energy in processes of thermal engineering. Morever, this research has enormous applications in the industries of polymer and glass, also in the field of heat exchangers styling, cooling operations of metallic plates, etc.
ABSTRACT
In the present paper, recent advances in the application of nanofluids in heat transfer in porous materials are reviewed. Efforts have been made to take a positive step in this field by scrutinizing the top papers published between 2018 and 2020. For that purpose, the various analytical methods used to describe the flow and heat transfer in different types of porous media are first thoroughly reviewed. In addition, the various models used to model nanofluids are described in detail. After reviewing these analysis methods, papers concerned with the natural convection heat transfer of nanofluids in porous media are evaluated first, followed by papers on the subject of forced convection heat transfer. Finally, we discuss articles related to mixed convection. Statistical results from the reviewed research regarding the representation of various parameters, such as the nanofluid type and the flow domain geometry, are analyzed, and directions for future research are finally suggested. The results reveal some precious facts. For instance, a change in the height of the solid and porous medium results in a change in the flow regime within the chamber; as a dimensionless permeability, the effect of Darcy's number on heat transfer is direct; and the effect of the porosity coefficient has a direct relationship with heat transfer: when the porosity coefficient is increased or decreased, the heat transfer will also increase or decrease. Additionally, a comprehensive review of nanofluid heat transfer in porous media and the relevant statical analysis are presented for the first time. The results show that Al2O3 nanoparticles in a base fluid of water with a proportion of 33.9% have the highest representation in the papers. Regarding the geometries studied, a square geometry accounted for 54% of the studies.
ABSTRACT
Nanofluids receive recognition from researchers and scientists because of their high thermal transfer rates. They have impactful industrial and technological modules in daily activities. In recent times, the heat transfer rate has been strengthened even more by a certain type of nanofluid known as "carbon nanotubes". The water-based magnetohydrodynamic flow with the nanoparticles MWCNT and SWCNT over an axially rotating stretching disk is highlighted in this article. In addition, the perspectives of viscous dissipation and MHD were taken into consideration. In order to formulate the physical problem, Xue's model is considered with the thermophysical properties and characteristics of carbon nanofluid. The current modeled system of partial differential equations is transformed into an ordinary differential equation system by the suggesting of the best similarity technique. Later, the transformed system of ordinary differential equations is solved numerically by using the Keller box method and the shooting method. Figures and charts are used to study and elaborate the physical behavior of the key subjective flow field parameters. The saturation in the base fluid is considered in both kinds of carbon nanotubes, the single-wall (SWCNTs) and the multiwall (MWCNTs). It is noted that the heat transfer mechanism shows some delaying behavior due to the increase in the Eckert number and the volume fraction elevation values. For the larger volume fraction values and the magnetic parameter, the skin friction increases. In addition, while the temperature profile increases with the Biot numbers, it falls for the increasing values of the Prandtl number. Furthermore, it is noted that the irreversibility of the thermal energy is influenced by the Biot number, temperature difference, Brinkmann number, and magnetic field, which all have dynamic effects on the entropy and the Bejan number.
ABSTRACT
The present problem addressed the transient behavior of convective heat and mass transfer characteristics across a curved surface under the influence of exothermic catalytic chemical reactions. The governing non-linear mathematical model wastransformed into a convenient form with the help of a primitive variable formulation. The final primitive formed model wassolved numerically by applying the finite difference method. The analysis of the above said computed numerical data in terms of oscillatory heat transfer, skin friction, and oscillatory mass transfer for various emerging parameters, such as the mixed convection parameter λT, modified mixed convection parameter λc, index parameter n, activation energy parameter E, exothermicparameter ß, temperature relative parameter γ, chemical reaction parameter λ, and Schmidt number Sc is plotted in graphical form. An excellent agreement is depicted for oscillatory heat transfer behavior at the large value of activation energy E. The amplitude of heat transfer and prominent fluctuating response in mass transfer with a certain height is found at each value of the index parameter n with a good alteration. An increase in the activation energy led to an increase in the surface temperature, which yielded more transient heat transfer in the above-said mechanism. The main novelty of the current study is that first, we ensured the numerical results for the steady state heat and fluid flow and then these obtained results wereused in the unsteady part to obtain numerical results for the transient behavior of the heat and mass transfer mechanism.
