ABSTRACT
Biobased epoxy vitrimers have reached intense interest in recent decades. The triggerable reverse bonds can be introduced into these crosslinked epoxy vitrimers through epoxy resins or hardeners. This study synthesized two imine hardeners, such as vanillin-butanediamine (V-BDA) and vanillin-hexanediamine (V-HDA), using biobased vanillin, butanediamine, and hexanediamine and their chemical structures were ensured by FTIR, 1HNMR, 13CNMR, and TOF-MS. The two novel hardeners were used to cure epoxy resins, rendering vitrimers with good reprocessability, self-healing, recyclability, and solvent resistance due to the reversible imine bonds. The flexural strengths and modulus of these cured resins were consistent with those of epoxy resins that were hardened with traditional amine-based hardeners. The cured resins maintained 100% of their Tg and flexural properties after being reprocessed up to three times. It was revealed that the cured epoxy vitrimers could be degraded entirely in a particular acidic solution capable of bond-exchanging reactions within 12 h at 50 áµC, allowing the thermoset matrix to be chemically recycled and the monomers regenerated. This versatile recyclability, combined with the use of fully biobased feedstocks to prepare the hardeners, provides an attractive approach to help achieve a sustainable circular composite economy.
ABSTRACT
Water is the ultimate and mostly used media during textile materials processing, especially in colouration. This study investigated the possibilities of using seawater for cotton and polyester fabrics dyeing. Single jersey fabrics made of 100 percent cotton and polyester were dyed using a standard recipe and two separate water source as dyeing mediums. It has been focused on the assessment of colour fastness to wash, perspiration, saliva, rubbing, water, light and colour difference value due to compare the efficiency of dyeing media. The results revealed that the cotton fabric dyed with seawater showed lighter shade than that of ground water sample. But for polyester fabric darker shade was obtained compared to ground water. The cotton sample dyed with sea water carried about 15% higher colour strength than ground water dyed sample but for polyester it was very negligible, only 3%. Moreover, the results of colour fastness to wash, perspiration, saliva, rubbing, water and light for seawater dyed samples of cotton and polyester were shown satisfactory outcomes having the grading of 4-5 in most of the cases. This exploration established that commercial dyeing processes were robust and can be practically transferable into the seawater medium for cotton and polyester fabrics.
ABSTRACT
OBJECTIVE: The objectives of this study were to investigate the genetic diversity, population structure and relatedness among the five chicken populations of Bangladesh using microsatellite markers. METHODS: A total of 161 individuals representing 5 chicken populations (non-descript Deshi [ND], naked neck [NN], hilly [HI], Aseel [AS], and red jungle fowl [JF]) were included in this study to investigate genetic diversity measures, population structure, genetic distance and phylogenetic relationships. Genotyping was performed using 16 selected polymorphic microsatellite markers distributed across 10 chromosomes. RESULTS: The average observed and expected heterozygosity, mean number of alleles and polymorphic information content were found to be 0.67±0.01, 0.70±0.01, 10.7 and 0.748, respectively in the studied populations. The estimated overall fixation index across the loci (F), heterozygote deficiency within (FIS) and among (FIT) chicken populations were 0.04±0.02, 0.05 and 0.16, respectively. Analysis of molecular variance analysis revealed 88.07% of the total genetic diversity was accounted for within population variation and the rest 11.93% was incurred with population differentiation (FST). The highest pairwise genetic distance (0.154) was found between ND and AS while the lowest distance was between JF and AS (0.084). Structure analysis depicted that the studied samples can be categorized into four distinct types or varieties (ΔK = 3.74) such as ND, NN, and HI where AS and JF clustered together as an admixed population. The Neighbor-Joining phylogenetic tree and discriminant analysis of principal component also showed close relatedness among three chicken varieties namely AS, HI, and JF. CONCLUSION: The results reflected that indigenous chicken of Bangladesh still possess rich genetic diversity but weak differentiation among the studied populations. This finding provides some important insight on genetic diversity measures that could support the designing and implementing of future breeding plans for indigenous chickens of Bangladesh.
