Performance and emission characteristics of a diesel engine fuelled by biodiesel from black soldier fly larvae: Effects of synthesizing catalysts with citric acid.

Biodiesel has several environmental benefits, such as biodegradability, renewability and lower soot emissions. However, biodiesel has undesirable properties such as higher viscosity and density and low calorific value compared to petroleum diesel, resulting in high Brake Specific Fuel Consumption (BSFC), reduced Brake Power (BP) and increased NOX emissions creating an environmental concerns in biodiesel development. This study investigated the effects of synthesizing transesterification catalysts (CaO and NaOH) with Citric Acid (CA) on the quality of biodiesel and biodiesel blends produced from Black Soldier Fly Larvae (BSFL) (Hermetia Illucens). The quality of biodiesel and blends was determined based on fuel properties, engine performance and emission composition characteristics. The tests were performed on a single-cylinder, four-stroke, Compression Ignition (CI) diesel engine at five loads at a constant speed of 1500 rpm. The results showed that synthesizing the catalysts with CA significantly affected the fatty acid profile of the biodiesel compared to physical fuel properties. B100 (pure BSFL biodiesel) exhibited higher BSFC by 10.57-13.97 % and lower BP by 4.21-7.83 % than diesel fuel. However, the Brake Thermal Efficiency (BTE) of biodiesel was higher than that of diesel fuel by 0.82-4.34 % at maximum load. Synthesizing catalysts with CA improved the viscosity of biodiesel by 0.93-2.81 % and effectively reduced NOX, HC and Smoke opacity by 2.23-3.16 %, 4.95-5.83 % and 20.51-41.15 %, respectively.

Enhancement of anaerobic digestion by co-digesting food waste and water hyacinth in improving treatment of organic waste and bio-methane recovery.

In Kenya, 57% of the municipal solid waste generated is Food waste (FW) which has high organic content. However, the treatment and bioconversion of FW to biogas have always been challenging due to its rapid biodegradation, resulting from rapid hydrolysis and accumulation of volatile fatty acids and lowering pH in the bioreactor. In this study, the anaerobic digestibility of FW as a mono substrate was compared to co-digestion of FW with water hyacinth (WH) for improved biogas production and organic matter removal efficiency in a laboratory batch reactor. Different mix proportions of FW and WH were co-digested under mesophilic conditions (37 °C) at a dilution of 6% (w/v) Total Solids (TS) content. The TS of the substrates (Food waste and Water Hyacinth) were pre-processed to have a concentration of TS at 6% (60 g/L) to operate a wet AD which requires the substrate to be less than 15% TS. The proportions of WH: FW (v/v) were 100:0, 85:15, 70:30, 55:45, 30:70, 15:85, and 0:100. In the batch rectors the anaerobic co-digestion was conducted with Substrate to Inoculum (S/I) ratio of 1:1. FW is generally considered to have high volatile solids which hydrolyze rapidly lowering pH arising from excess production of Hydrogen which in presence of CO2 and acetogenic bacteria leads to more production of acetate, formate and other long chain fatty acids which inhibits methanogenesis as a result of rapid acidification. The rapid acidification of the bioreactors that are used to treat FW results in the inhibition of the methanogenesis process. The co-digestion of the substrates could have improved the process parameters by reducing acidity caused by the high C/N ratio, reducing the inhibitory range, and increasing the buffer capacity which enhanced the bio-methane potential and the microbial activity. The batch experiments were set in triplicate for both cases of FW, WH, mixtures, and Inoculum. The results showed that the average gas yields after 81 days for the various mix proportions were 256.27and 357.69 ml/g-VS for mono-digestion of WH and FW respectively. For the mixtures of WH: FW the average reported biogas production were 305.01, 280.27, 548.91,616.01 and 270.87 ml/g-VS for mixtures of 15:85, 30:70, 55:45,70:30 and 85:15 respectively. The modified Gompertz model showed that the digesters with WH and FW alone had lag times of 2.599 and 1.052 days respectively. The mix substrates of WH: FW 85:15, 70:30, 55:45, 30:70 and 15:85 shown lag times of 2.456, 3.777, 2.574, 1.956 and 1.75 days respectively. A mix (WH: FW) of 70:30 had the highest maximum specific biogas production Rmax and the maximum biogas production potential of 18.19 mlCH4/gVS per day and 607.7mlCH4/gVS respectively. The R2 and RSME values ranged from 0.9867 to 0.9963 and 2.663 to 9.359 respectively in all the digesters. The study shows that the co-digestion of WH and FW in the mix ratio of 70:30 improved the volume of biogas produced and organic matter removal efficiency reached 79%.

Heating and emission characteristics from combustion of charcoal and co-combustion of charcoal with faecal char-sawdust char briquettes in a ceramic cook stove.

Over reliance on charcoal has accelerated deforestation in sub-Saharan Africa. Seeking alternative sustainable and environmentally friendly sources of biomass energy to meet the escalating energy demand is therefore vital. However, limited evidence exists on the concentrations of toxic emissions of different biomass fuels. Herein, dried human faeces and sawdust were pyrolyzed at 350 °C to produce biochar and mixed in equal ratio to produce briquettes through densification, with molasses (10 wt.%) used as a binder. A comparative study on the heating properties and emission level of carbon monoxide (CO), nitric oxide (NO), and hydrogen sulphide (H2S) during combustion of charcoal, and co-combustion (50:50 wt. %) of charcoal with briquettes was conducted. The thermal profile of the flue gases indicated rapid combustion of volatile gases followed by slow oxidation of the char. Co-combustion significantly (P < 0.05) enhanced the amount of heat energy released with flue gases temperatures reaching a peak of 475 °C. The briquettes had a gross calorific value of 19.8 MJ/kg which was lower than 25.7 MJ/kg for charcoal. Combustion of charcoal did not emit NO, however the concentration of CO was above the critical short term limits of 35 ppm. The concentration of CO and H2S was above the short term exposure limits of 35 ppm, and 0.005 ppm, respectively, during co-combustion, whereas NO concentration was below dangerous exposure levels of 100 ppm. These results suggest that co-combustion of charcoal with the briquettes is a promising approach to generate safe and sufficient heat energy for cooking and reduce deforestation.

Assessment of hydrological water balance in Lower Nzoia Sub-catchment using SWAT-model: towards improved water governace in Kenya.

Kenya's catchments has both natural and disturbed environments. Within these environments, there has been interaction between hydrological, physical and ecological characteristics. Therefore, impacts of Land Use Land Cover (LULC) change on surface and sub - surface hydrology needs to be well understood due to the increasing population competing for scarce natural resources such as water, trees and forest land. The water balance components' spatial and temporal dynamics in relationship to the LULC change between 2003 and 2018 in the Lower Nzoia Sub - Catchment (LNSC) in Kenya was therefore assessed. Landsat data with 30 m (m) spatial resolution was used in understanding LULC dynamics of the study area using Supervised Classification Approach (Interactive Classification Method) in ArcGIS 10.5. After landsat image classification, key water balance components including; surface runoff (SURFQ), lateral flow (LATQ), groundwater recharge (BASEQ), deep acquifer recharge (DEEPQ), evapotranspiration (ET) and groundwater revap (REVAP) for years 2003 and 2018 were estimated using SWAT model in ArcSWAT. The overall accuracies for 2003 and 2018 classified images were 75.9% and 98.9% respectively which are showing good values. The results of the study showed that agricultural land coverage reduced from 83.1% in 2003 to 78.6% in 2018. Rangeland on the hand increased from 6.3% to 9.8% while urban/built - up area increasing from 10.6% to 11.6%. The annual water balance components from the LULC distribution of the two time periods shows that ET reduced, SURFQ increased, BASEQ reduced, DEEPQ reduced, LATQ reduced and REVAP reduced. At catchment level, results show that 2018 had a higher water balance than 2003 which can partly be explained by land cover decrease. The relationship between rainfall distribution, Land Surface Temperature (LST) and LULC change were further compared. At the same time, the study found out that there is limited focus to date on rural communities climate adaptive capacity. Hence, water institutions in the sub - catchment such as Water Resources Authority (WRA) are yet to fully mainstream adaptive capacity into their organizational structure and policies.

Adsorption and desorption of nutrients from abattoir wastewater: modelling and comparison of rice, coconut and coffee husk biochar.

Enrichment of water bodies with nutrients from wastewater is one of the causes of eutrophication to aquatic ecosystems. This study investigated the use of biochar derived from rice husk, coconut husk, and coffee husk in adsorbing nitrates (NO3-N) and nitrites (NO2-N) from slaughterhouse wastewater. It also explored the desorption efficiencies of the adsorbed nutrients to ascertain the applicability of the enriched biochars as slow-release fertilizers. To characterize the physicochemical properties of the biochars, scanning electron microscopy (SEM) was used. Fourier transforms infrared spectroscopy (FTIR), elemental analysis (CHNO) Langmuir and Freundlich, and the isotherm models were employed to fit the experimental equilibrium adsorption data. It was observed that the Langmuir isotherm model has the best fit of NO3- N and NO2- N on all the biochars. And this was based on the coefficient of correlation values. Also, the coconut husk biochar has the highest adsorption capacities of NO3-N and NO2-N at 12.97 mg/g, and 0.244 mg/g, respectively, attributing to its high porosity as revealed by the SEM images. The adsorption capacities for the rice husk char were 12.315 and 0.233 mg/g, while that for coffee husk char were12.08 mg/g and 0.218 mg/g for NO3-N and NO2-N, respectively. The relatively higher amount of NO3-N adsorbed to that of NO2-N could be attributed to its higher initial concentration in the solution than nitrite concentration. The desorption efficiencies of nitrates were 22.4, 24.39, and 16.79 %, for rice husk char, coconut husk char and coffee husk char, respectively. For the rice husk char, coconut husk char and coffee husk char, the nitrites desorption efficiencies were 80.73, 91.39, and 83.62 %, respectively. These values are good indicators that the studied biochar can be enriched with NO3- N and NO2- N and used as slow-release fertilizers.

Pineapple peel biochar and lateritic soil as adsorbents for recovery of ammonium nitrogen from human urine.

Human urine is a rich source of nitrogen which can be captured to supplement the existing sources of nitrogen fertilizers thus contributing to enhanced crop production. However, urine is the major contributor of macronutrients in municipal wastewater flows resulting into eutrophication of the receiving water bodies. Herein, pineapple peel biochar (PPB), and lateritic soil (LS) adsorbents were prepared for the safe removal of ammonium nitrogen (NH4+-N) from human urine solutions. Physicochemical properties of PPB, and LS were characterized by scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) to investigate the relationship of their properties with NH4+-N adsorption. Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) isotherm models were employed to correlate the experimental equilibrium adsorption data. The effect of contact time and initial concentration of NH4+-N adsorption was also evaluated. The D-R isotherm model best described the behaviour of NH4+-N adsorption on both PPB and LS based on the coefficient of correlation values. This model showed that the adsorption of NH4+-N on both samples was a physical process with PPB and LS having mean surface adsorption energies of 1.826 × 10-2, and 1.622 × 10-2 kJ/mol, respectively. The PPB exhibited a slightly higher adsorption capacity for NH4+-N (13.40 mg/g) than LS (10.73 mg/g) with the difference attributed to its higher surface area and porosity. These values are good indicators for assessing the effectiveness of the materials for adsorption of NH4+-N from human urine.

Occurrence, distribution, and risk assessment of pharmerciuticals in wastewater and open surface drains of peri-urban areas: Case study of Juja town, Kenya.

The occurrence of Active Pharmaceutical Ingredients (APIs) in the environment is becoming a major area of concern due to their undesirable effects on non-target organisms. This study investigated the occurrence and risk of contamination by five antibiotics and three antiretrovirals drugs in a fast-growing peri-urban area in Kenya, with inadequate sewer system coverage. Due to poor sewage connectivity and poorly designed decentralized systems, wastewater is directly released in open drains. Water and sediment samples were collected from open surface water drains, while wastewater samples were collected from centralized wastewater treatment plants (WWTP). Solid-phase extraction and ultrasonic-assisted extraction for the aqueous and sediment samples respectively were carried out and extracts analyzed by liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI-MS/MS) using isotopically labeled internal standards. APIs were observed with the detection frequency ranging from 36% to 100%. High mean concentrations of 48.7 µg L-1, 108 µg L-1, and 532 µg L-1 were observed in surface drains for Lamivudine (3 TC), Sulfamethoxazole (SMX), Ciprofloxacin (CIP) respectively. Drain sediments also showed high concentrations of APIs ranging from 2.1 to 13,100 µg kg-1. APIs in this study exceeded those observed in existing literature studies. JKUAT WWTP removal efficiencies varied from -90.68% to 72.67%. Total APIs emission load of the study area was 3550 mg d-1 with WWTP effluent contributing higher loads (2620 mg d-1) than surface water drains (640 mg d-1). Zidovudine (ZDV), nevirapine (NVP), and trimethoprim (TMP) loads in drains, however, exceeded WWTP effluent. Low to high ecotoxicity risk of the individual APIs were observed to the aquatic environment, with high risks for the development of antibiotic resistance in microbiome as determined by the risk quotient (RQ) approach. Risk management through efficient wastewater collection, conveyance, and treatment is necessary to suppress the measured concentrations.