ABSTRACT
Escalating emissions of several air pollutants over South Asia could play a detrimental role in the regional and global atmosphere. Therefore, it is necessary to investigate these emissions within the boundary layer and at higher heights utilizing satellite data that are more inclusionary, where limited in situ observations are available. Here, we utilize the Infrared Atmospheric Sounding Interferometer (IASI), Ozone Monitoring Instruments (OMI), TROPOspheric Monitoring Instrument (TROPOMI), and Global Ozone Monitoring Experiment (GOME-2) hyperspectral satellite data to assess the changes in emission sources during Indian lockdown with a primary focus on the tropospheric profiles of ozone and carbon monoxide (CO). A significant reduction (> 20%) in the tropospheric ozone was seen over northern and northeast regions compared to 2018, while a dramatic increase (> 20%) compared to 2019 was seen. The subtropical dynamics mainly contributed to the increased ozone over the northern region. An analysis of the ozone production regime showed mostly NO2 limited regime over the major part of India and VOC limited regime over thermal power plants regions. Unlike in the boundary layer, where CO showed reduction (15-20%), CO profiles showed a consistent increase (as high as 31%) in the free troposphere over the majority of cities and thermal power plants. The CO total column also showed an increase (~ 20%) over central and western India and a slight decrease (5%) over northern India. Similar to CO, an increase (~ 15%) of NO2 column over the western region was observed particularly compared to 2019. However, unlike ozone and CO, reduction of tropospheric NO2 columns was seen over the major part of India, with the highest reduction over northern regions (20-52%). Furthermore, homogeneous yearly differences (> 30%) between OMI and TROPOMI NO2 observations were also seen distinctly over the remote areas. Contrary to surface-based studies, the present study shows an increase in CO, ozone (decrease), and NO2 at several locations and in the free troposphere during the lockdown.
