Effect of Graphene Oxide Localization on Morphology Development and Rheological and Mechanical Properties of Poly(lactic acid)/ethylene vinyl Alcohol Copolymer Blend Composites: A Comprehensive Study.

This study investigates the rheological, morphological, and mechanical properties of melt-processed polylactide/ethylene vinyl alcohol (70PLA/30EVOH) blend composites containing 0.25, 0.5, and 1 wt.% of graphene oxide (GO) nanoplates. Thermodynamic-based suggested the localization of nanoparticles in EVOH, SEM studies showed that the introduction of GO to the blend increased dispersed droplet size, which was attributed to the localization of GO within EVOH, as confirmed by TEM. The rheology results indicated a decrease in the elasticity for the composite containing 0.25 wt.% of GO compared to the neat blend, which was attributed to the sliding effect of the added GO nanoplatelets. However, samples containing higher amounts of GO nanoplatelets exhibited more excellent elasticity than the neat blend. The increased elasticity was suggestively attributed to the dominance of hydrodynamic interactions, the physical network of added nanoplatelets, and polymer/GO interactions over the sliding role of the GO nanoplatelets at higher loadings. In addition, the effect of the order of mixing was investigated, and the premixing of PLA and GO exhibited a decrease in the droplet radius compared to the neat blend. It was ascribed to the localization of GO nanosheets in the PLA and interface, which was confirmed by rheological results and mechanical assessments.

Evaluation of Lippia scaberrima Sond. and Aspalathus linearis (Burm.f.) R. Dahlgren extracts on human CYP enzymes and gold nanoparticle synthesis: implications for drug metabolism and cytotoxicity.

BACKGROUND: Metabolism is an important component of the kinetic characteristics of herbal constituents, and it often determines the internal dose and concentration of these effective constituents at the target site. The metabolic profile of plant extracts and pure compounds need to be determined for any possible herb-drug metabolic interactions that might occur. METHODS: Various concentrations of the essential oil of Lippia scaberrima, the ethanolic extract of Lippia scaberrima alone and their combinations with fermented and unfermented Aspalathus linearis extract were used to determine the inhibitory potential on placental, microsomal and recombinant human hepatic Cytochrome P450 enzymes. Furthermore, the study investigated the synthesis and characterization of gold nanoparticles from the ethanolic extract of Lippia scaberrima as a lead sample. Confirmation and characterization of the synthesized gold nanoparticles were conducted through various methods. Additionally, the cytotoxic properties of the ethanolic extract of Lippia scaberrima were compared with the gold nanoparticles synthesized from Lippia scaberrima using gum arabic as a capping agent. RESULTS: All the samples showed varying levels of CYP inhibition. The most potent inhibition took place for CYP2C19 and CYP1B1 with 50% inhibitory concentration (IC50) values of less than 0.05 µg/L for the essential oil tested and IC50-values between 0.05 µg/L-1 µg/L for all the other combinations and extracts tested, respectively. For both CYP1A2 and CYP2D6 the IC50-values for the essential oil, the extracts and combinations were found in the range of 1 - 10 µg/L. The majority of the IC50 values found were higher than 10 µg/L and, therefore, were found to have no inhibition against the CYP enzymes tested. CONCLUSION: Therefore, the essential oil of Lippia scaberrima, the ethanolic extract of Lippia scaberrima alone and their combinations with Aspalathus linearis do not possess any clinically significant CYP interaction potential and may be further investigated for their adjuvant potential for use in the tuberculosis treatment regimen. Furthermore, it was shown that the cytotoxic potential of the Lippia scaberrima gold nanoparticles was reduced by twofold when compared to the ethanolic extract of Lippia scaberrima.

Stability, biofunctional, and antimicrobial characteristics of cannabidiol isolate for the design of topical formulations.

Cannabidiol (CBD) is a high-value natural compound of Cannabis Sativa plant. It is a non-psychotropic phytocannabinoid, attracting significant attention as a multifunctional active ingredient for topical applications. Although it is demonstrated that CBD can be used for specific dermatological ailments, reliable data on functionalities are limited. The present study aimed to investigate the structural stability, biofunctionality, and antimicrobial characteristics of CBD isolate to assist in the design of various topical formulations. The stability of CBD in solid and solubilized states was assessed to establish storage and formulation conditions. The performance of CBD solubilized in organic and aqueous media was evaluated for free radical scavenging, tyrosinase, and collagenase enzyme inhibition, which showed good prospects for the ingredient. The antimicrobial activity of solubilized CBD was evaluated against Gram-negative (E. coli, P. aeruginosa), Gram-positive bacterial strains (S. aureus, S. epidermidis, C. acnes), and fungal strains (C. albicans, M. furfur) using agar well diffusion and broth microdilution methods. Due to the presence of surfactants in CBD aqueous solution, it displayed a lack of antimicrobial activity against all the tested microorganisms. CBD solubilized in an organic medium showed no activity against Gram-negative bacterial strains but higher activity against tested Gram-positive bacterial and fungal strains.

Recent Advances and Outlook in 2D Nanomaterial-Based Flame-Retardant PLA Materials.

Poly (lactic acid) or polylactide (PLA) has gained widespread use in many industries and has become a commodity polymer. Its potential as a perfect replacement for petrochemically made plastics has been constrained by its extreme flammability and propensity to flow in a fire. Traditional flame-retardants (FRs), such as organo-halogen chemicals, can be added to PLA without significantly affecting the material's mechanical properties. However, the restricted usage of these substances causes them to bioaccumulate and endanger plants and animals. Research on PLA flame-retardants has mostly concentrated on organic and inorganic substances for the past few years. Meanwhile, there has been a significant increase in renewed interest in creating environmentally acceptable flame-retardants for PLA to maintain the integrity of the polymer, which is the current trend. This article reviews recent advancements in novel FRs for PLA. The emphasis is on two-dimensional (2D) nanosystems and the composites made from them that have been used to develop PLA nanocomposite (NCP) systems that are flame retarding. The association between FR loadings and efficiency for different FR-PLA systems is also briefly discussed in the paper, as well as their influence on processing and other material attributes. It is unmistakably established from the literature that adding 2D nanoparticles to PLA matrix systems reduces their flammability by forming an intumescent char/carbonized surface layer. This creates a barrier effect that successfully blocks the filtration of volatiles and oxygen, heat and mass transfer, and the release of combustible gases produced during combustion.

Role of Rheology in Morphology Development and Advanced Processing of Thermoplastic Polymer Materials: A Review.

This review presents fundamental knowledge and recent advances pertaining to research on the role of rheology in polymer processing, highlights the knowledge gap between the function of rheology in various processing operations and the importance of rheology in the development, characterization, and assessment of the morphologies of polymeric materials, and offers ideas for enhancing the processabilities of polymeric materials in advanced processing operations. Rheology plays a crucial role in the morphological evolution of polymer blends and composites, influencing the type of morphology in the case of blends and the quality of dispersion in the cases of both blends and composites. The rheological characteristics of multiphase polymeric materials provide valuable information on the morphologies of these materials, thereby rendering rheology an important tool for morphological assessment. Although rheology extensively affects the processabilities of polymeric materials in all processing operations, this review focuses on the roles of rheology in film blowing, electrospinning, centrifugal jet spinning, and the three-dimensional printing of polymeric materials, which are advanced processing operations that have gained significant research interest. This review offers a comprehensive overview of the fundamentals of morphology development and the aforementioned processing techniques; moreover, it covers all vital aspects related to the tailoring of the rheological characteristics of polymeric materials for achieving superior morphologies and high processabilities of these materials in advanced processing operations. Thus, this article provides a direction for future advancements in polymer processing. Furthermore, the superiority of elongational flow over shear flow in enhancing the quality of dispersion in multiphase polymeric materials and the role of extensional rheology in the advanced processing operations of these materials, which have rarely been discussed in previous reviews, have been critically analyzed in this review. In summary, this article offers new insights into the use of rheology in material and product development during advanced polymer-processing operations.

Integration of 3D Printing-Coelectrospinning: Concept Shifting in Biomedical Applications.

Porous structures with sizes between the submicrometer and nanometer scales can be produced using efficient and adaptable electrospinning technology. However, to approximate desirable structures, the construction lacks mechanical sophistication and conformance and requires three-dimensional solitary or multifunctional structures. The diversity of high-performance polymers and blends has enabled the creation of several porous structural conformations for applications in advanced materials science, particularly in biomedicine. Two promising technologies can be combined, such as electrospinning with 3D printing or additive manufacturing, thereby providing a straightforward yet flexible technique for digitally controlled shape-morphing fabrication. The hierarchical integration of configurations is used to imprint complex shapes and patterns onto mesostructured, stimulus-responsive electrospun fabrics. This technique controls the internal stresses caused by the swelling/contraction mismatch in the in-plane and interlayer regions, which, in turn, controls the morphological characteristics of the electrospun membranes. Major innovations in 3D printing, along with additive manufacturing, have led to the production of materials and scaffold systems for tactile and wearable sensors, filtration structures, sensors for structural health monitoring, tissue engineering, biomedical scaffolds, and optical patterning. This review discusses the synergy between 3D printing and electrospinning as a constituent of specific microfabrication methods for quick structural prototypes that are expected to advance into next-generation constructs. Furthermore, individual techniques, their process parameters, and how the fabricated novel structures are applied holistically in the biomedical field have never been discussed in the literature. In summary, this review offers novel insights into the use of electrospinning and 3D printing as well as their integration for cutting-edge applications in the biomedical field.

Prospects of 2D graphdiynes and their applications in desalination and wastewater remediation.

Water is an indispensable part of human life that affects health and food intake. Water pollution caused by rapid industrialization, agriculture, and other human activities affects humanity. Therefore, researchers are prudent and cautious regarding the use of novel materials and technologies for wastewater remediation. Graphdiyne (GDY), an emerging 2D nanomaterial, shows promise in this direction. Graphdiyne has a highly symmetrical π-conjugated structure consisting of uniformly distributed pores; hence, it is favorable for applications such as oil-water separation and organic-pollutant removal. The acetylenic linkage in GDY can strongly interact with metal ions, rendering GDY applicable to heavy-metal adsorption. In addition, GDY membranes that exhibit 100% salt rejection at certain pressures are potential candidates for wastewater treatment and water reuse via desalination. This review provides deep insights into the structure, properties, and synthesis methods of GDY, owing to which it is a unique, promising material. In the latter half of the article, various applications of GDY in desalination and wastewater treatment have been detailed. Finally, the prospects of these materials have been discussed succinctly.

Application of Layered Double Hydroxides as a Slow-Release Phosphate Source: A Comparison of Hydroponic and Soil Systems.

The utilization of slow-release fertilizer materials capable of responding to their environment and releasing nutrient ions efficiently over a prolonged period is an emerging research area in agricultural materials sciences. In this study, two-dimensional layered materials were prepared to release phosphor ions (P) slowly into the soil as well as in the hydroponic system. Various P-intercalated layered double hydroxides (LDHs) (Mg/Al, Zn/Al, and Mg-Zn/Al-LDHs) with a molar ratio of 2:1 were synthesized using an ion-exchange method from corresponding LDHs containing NO3 - ions within the layers. Sodium alginate (SA) was used to encapsulate P-intercalated Mg/Al-LDH to produce bionanocomposite beads (LB) to check the effect of the biopolymer matrix on the release characteristics. The prepared materials were characterized by XRD and FTIR to confirm the incorporation of P in LDHs. TGA, SEM, and elemental analysis were also performed to study the thermal decomposition pattern, surface morphology, and chemical composition of synthesized materials. The P-release experiments were conducted in a soil solution. The performance of the prepared materials was investigated in soil as well as in a hydroponic system for tomato plants under a controlled atmosphere of humidity, temperature, and light. The fertilization ability of the prepared materials was compared with that of a soluble P source (KH2PO4), commercial hydroponic fertilizer (Nutrifeed), and a commercial soil slow-release fertilizer (Wonder plant starter). The prepared materials demonstrated a slow release of P in the soil solution. P-intercalated LDHs were not very effective under hydroponic conditions; however, the LDHs were more effective in the soil system in terms of dry matter production and P content in dry matter. Furthermore, LDHs were able to increase the soil pH value over time.

Investigation of the Effects of Chain Extender on Material Properties of PLA/PCL and PLA/PEG Blends: Comparative Study between Polycaprolactone and Polyethylene Glycol.

This study investigated the effect of the Joncryl concentration on the properties of polylactide/poly(ε-caprolactone) (PLA/PCL) and PLA/poly(ethylene glycol) (PEG) blends. The addition of Joncryl influenced the properties of both PLA-based blends. In the blend of PLA/PCL blends, the addition of Joncryl reduced the size of PCL droplets, which implies the compatibility of the two phases, while PLA/PEG blends showed a co-continuous type of morphology at 0.1% and 0.3 wt.% of Joncryl loading. The crystallinity of PCL and PEG was studied on both PLA/PCL and PLA/PEG blend systems. In both scenarios, the crystallinity of the blends decreased upon the addition of Joncryl. Thermal stabilities were shown to depend on the addition of Joncryl. The toughness increased when 0.5 wt.% of Joncryl was added to both systems. However, the stiffness of PLA/PCL decreased, while the stiffness of PLA/PEG increased with the increasing concentration of Joncryl. This study provides new insight into the effect of chain extenders on the compatibility of PLA-based blends.

Supersensitive metal free in-situ synthesized graphene oxide@cellulose nanocrystals acetone sensitive bioderived sensors.

A series of graphene oxide@cellulose nanocrystal (GO@CNC) nanoparticles (NPs) were synthesized in this study using a room temperature-based simple modified hummers process. The morphological structures, as well as chemical characteristics of these materials, were characterized using transmission electron microscopy (TEM), X-ray diffraction (XRD), and other techniques. The results show that the as-prepared nanoparticles are made up of crystallite grains with an average size of around 7.82, 14.69, 10.77, 7.82, and 12.51 nm for GO, CNC, GO1@CNC1, GO2@CNC3, and GO3@CNC3 respectively, and OH & COOH functionalities on the NPs' surfaces. GO@CNC NPs exhibit significantly better sensing characteristics towards acetone when compared to virgin GO nanoplatelets; specifically, the optimal sensor based on GO3@CNC3 NPs showed the highest response (60.88 at 5 ppm), which was higher than that of the virgin GO sensor at 200 °C operating temperature and including those reported. Furthermore, the sensors have a high sensitivity towards acetone in sub-ppm concentrations as well as a detection limit of 5 ppm, making it a viable candidate for diabetes breath testing.

A Comparison of Nitrate Release from Zn/Al-, Mg/Al-, and Mg-Zn/Al Layered Double Hydroxides and Composite Beads: Utilization as Slow-Release Fertilizers.

Nitrate-loaded Zn/Al, Mg/Al, and Mg-Zn/Al layered double hydroxides (LDHs) were synthesized using the coprecipitation method. The slow-release properties of LDHs were measured in powder form at various pH conditions. Sodium alginate was used to encapsulate Mg/Al LDH to produce composite beads (LB) to further slow down the release of nitrate ions. The prepared LDH samples and LB were characterized by X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analysis, and inductively coupled plasma optical emission spectroscopy. The surface morphologies of LDHs and LB were obtained from scanning electron microscopy analysis. The slow-release properties of the materials were evaluated using a kinetic study of nitrate release in tap water, soil solution, as well as plant growth experiments using coriander (Coriandrum sativum). The nitrate release ability of LDHs and LB was compared with a soluble nitrate source. The plant growth experiments showed that all three LDHs were able to supply an adequate amount of nitrate to the plant similar to the soluble fertilizer while maintaining the availability of nitrate over extended periods. The ability of LDHs to increase soil pH was also demonstrated.

Functional and Structural Facts of Effective Electromagnetic Interference Shielding Materials: A Review.

Electromagnetic interference (EMI) shielding effectiveness (SE) systems have received immense attention from researchers owing to the rapid development in electronics and telecommunications, which is an alarming matter in our modern society. This radiation can damage the performance of EM devices and may harmfully affect animal/human health. The harmonious utilization of magnetic alloys and conducting but nonmagnetic materials (such as carbon/graphene) is a practical approach toward EMI SE. This review is not exhaustive, although it is comprehensive and aimed at all materials for EMI SE especially graphene-based polymeric composites. It encompasses multifunctional and functional structural EMI shields. These materials comprise polymers, carbons, ceramics, metals, cement composites/nanocomposites, and hybrids. The accessibility of abundant categories of carbon-based materials in their microscale, nanoscale, and quantum forms as EMI shields as polymer-carbon, cement-carbon, ceramic-carbon, metal-carbon, and their hybrids, makes them receive much attention, as a result of their unique amalgamation of electrical, magnetic, dielectric, thermal, and/or mechanical properties. Herewith, we have discussed the principles of EMI shields along with their design and state of the art basis and material architecture along with the drawbacks in research on EMI shields.

Applications of MXene-Containing Polypyrrole Nanocomposites in Electrochemical Energy Storage and Conversion.

The atomically thick two-dimensional (2D) materials are at the forefront of revolutionary technologies for energy storage devices. Due to their fascinating physical and chemical features, these materials have gotten a lot of attention. They are particularly appealing for a wide range of applications, including electrochemical storage systems, due to their simplicity of property tuning. The MXene is a type of 2D material that is widely recognized for its exceptional electrochemical characteristics. The use of these materials in conjunction with conducting polymers, notably polypyrrole (PPy), has opened new possibilities for lightweight, flexible, and portable electrodes. Therefore, herein we report a comprehensive review of recent achievements in the production of MXene/PPy nanocomposites. The structural-property relationship of this class of nanocomposites was taken into consideration with an elaborate discussion of the various characterizations employed. As a result, this research gives a narrative explanation of how PPy interacts with distinct MXenes to produce desirable high-performance nanocomposites. The effects of MXene incorporation on the thermal, electrical, and electrochemical characteristics of the resultant nanocomposites were discussed. Finally, it is critically reviewed and presented as an advanced composite material in electrochemical storage devices, energy conversion, electrochemical sensors, and electromagnetic interference shielding.

Graphene-Based Electrospun Fibrous Materials with Enhanced EMI Shielding: Recent Developments and Future Perspectives.

As a result of advancements in electronics/telecommunications, electromagnetic interference (EMI) pollution has gotten worse. Hence, fabrication/investigation of EMI shields having outstanding EMI shielding performance is necessary. Electrospinning (ES) has recently been established in several niches where 1D nanofibers (NFs) fabricated by ES can provide the shielding of EM waves, owing to their exceptional benefits. This review presents the basic correlations of ES technology and EMI shielding. Diverse graphene (GP)-based fibrous materials directly spun via ES as EMI shields are discussed. Electrospun EMI shields as composites through diverse post-treatments are reviewed, and then different factors influencing their EMI shielding characteristics are critically summarized. Finally, deductions and forthcoming outlooks are given. This review provides up to date knowledge on the advancement of the application of graphene-based electrospun fibers/composite materials as EMI shields and the outlook for high-performance electrospun fibers/composite-based EMI shielding materials.

Density Functional Theory Interaction Study of a Polyethylene Glycol-Based Nanocomposite with Cephalexin Drug for the Elimination of Wound Infection.

In this paper, density functional theory (DFT) simulations are used to evaluate the possible use of a graphene oxide-based poly(ethylene glycol) (GO/PEG) nanocomposite as a drug delivery substrate for cephalexin (CEX), an antibiotic drug employed to treat wound infection. First, the stable configuration of the PEGylated system was generated with a binding energy of -25.67 kcal/mol at 1.62 Å through Monte Carlo simulation and DFT calculation for a favorable adsorption site. The most stable configuration shows that PEG interacts with GO through hydrogen bonding of the oxygen atom on the hydroxyl group of PEG with the hydrogen atom of the carboxylic group on GO. Similarly, for the interaction of the CEX drug with the GO/PEG nanocomposite excipient system, the adsorption energies are computed after determining the optimal and thermodynamically favorable configuration. The nitrogen atom from the amine group of the drug binds with a hydrogen atom from the carboxylic group of the GO/PEG nanocomposite at 1.75 Å, with an adsorption energy of -36.17 kcal/mol, in the most stable drug-excipient system. Drug release for tissue regeneration at the predicted target cell is more rapid in moist conditions than in the gas phase. The solubility of the suggested drug in the aqueous media around the open wound is shown by the magnitude of the predicted solvation energy. The findings from this study theoretically validate the potential use of a GO/PEG nanocomposite for wound treatment application as a drug carrier for sustained release of the CEX drug.

Application of DFT Calculations in Designing Polymer-Based Drug Delivery Systems: An Overview.

Drug delivery systems transfer medications to target locations throughout the body. These systems are often made up of biodegradable and bioabsorbable polymers acting as delivery components. The introduction of density functional theory (DFT) has tremendously aided the application of computational material science in the design and development of drug delivery materials. The use of DFT and other computational approaches avoids time-consuming empirical processes. Therefore, this review explored how the DFT computation may be utilized to explain some of the features of polymer-based drug delivery systems. First, we went through the key aspects of DFT and provided some context. Then we looked at the essential characteristics of a polymer-based drug delivery system that DFT simulations could predict. We observed that the Gaussian software had been extensively employed by researchers, particularly with the B3LYP functional and 6-31G(d, p) basic sets for polymer-based drug delivery systems. However, to give researchers a choice of basis set for modelling complicated organic systems, such as polymer-drug complexes, we then offered possible resources and presented the future trend.

Layered Double Hydroxides for Sustainable Agriculture and Environment: An Overview.

Agricultural practices in modern society have a detrimental impact on the health of the ecosystem, environment, and consumers. The significantly high usage rate of chemicals causes serious harm, and the sector demands the development of innovative materials that can foster improved food production and lessen ecological impacts. The majority of layered double hydroxides (LDH) are synthetic. At the same time, some of them occur in the form of natural minerals (hydrotalcite), which have recently emerged as favorable materials and provided advanced and ingenious frontiers in various fields of agriculture through practical application possibilities that can replace conventional agricultural systems. LDH can exchange anions intercalated between the layers in the interlayer structure, and there is evidence that atmospheric carbon dioxide and moisture can completely break down LDH over time. Due to certain unique properties such as tunable structure, specific intercalation chemistry, pH-dependent stability, as well as retention of the guest molecules within interlayers and their subsequent controlled release, LDHs are increasingly investigated as materials to enhance yield, quality of crops, and soil in recent times. This review aims to present the current research progress in the design and development of LDH-based materials as nanoscale agrochemicals to illustrate its relevance in making agro-practices more sustainable and efficient. Specific emphasis is given to the functionality of these materials as effective materials for the slow release of fertilizers and plant growth factors as well as adsorption of toxic agrochemical residues and contaminants. Relevant research efforts have been briefly reviewed, and the potential of LDH as new generation green materials to provide solutions to agricultural problems for improving food productivity and security has been summarized.

Targeting Acne Bacteria and Wound Healing In Vitro Using Plectranthus aliciae, Rosmarinic Acid, and Tetracycline Gold Nanoparticles.

Gold nanoparticles from plant extracts and their bioactive compounds to treat various maladies have become an area of interest to many researchers. Acne vulgaris is an inflammatory disease of the pilosebaceous unit caused by the opportunistic bacteria Cutibacterium acnes and Staphylococcus epidermis. These bacteria are not only associated with inflammatory acne but also with prosthetic-implant-associated infections and wounds. Studies have hypothesised that these bacteria have a mutualistic relationship and act as a multispecies system. It is believed that these bacteria form a multispecies biofilm under various conditions and that these biofilms contribute to increased antibiotic resistance compared to single-species biofilms. This study aimed to investigate the antibacterial and wound healing potential of synthesised gold nanoparticles (AuNPs) from an endemic South African plant, Plectranthus aliciae (AuNPPAE), its major compound rosmarinic acid (AuNPRA) and a widely used antibiotic, tetracycline (AuNPTET). Synthesised gold nanoparticles were successfully formed and characterised using ultraviolet-visible spectroscopy (UV-vis), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), zeta potential (ζ-potential), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED), and they were investigated for stability under various biological conditions. Stable nanoparticles were formed with ζ-potentials of -18.07 ± 0.95 mV (AuNPPAE), -21.5 ± 2.66 mV (AuNPRA), and -39.83 ± 1.6 mV (AuNPTET). The average diameter of the AuNPs was 71.26 ± 0.44 nm, 29.88 ± 3.30 nm, and 132.6 ± 99.5 nm for AuNPPAE, AuNPRA, and AuNPTET, respectively. In vitro, biological studies confirmed that although no antibacterial activity or biofilm inhibition was observed for the nanoparticles tested on the multispecies C. acnes and S. epidermis systems, these samples had potential wound closure activity. Gold nanoparticles formed with rosmarinic acid significantly increased wound closure by 21.4% at 25% v/v (≈29.2 µg/mL) compared to the negative cell control and the rosmarinic acid compound at the highest concentration tested of 500 µg/mL. This study concluded that green synthesised gold nanoparticles of rosmarinic acid could potentially be used for treating wounds.

Polyester-Based Coatings for Corrosion Protection.

The article is the first review encompassing the study and the applications of polyester-based coatings for the corrosion protection of steel. The impact of corrosion and the challenges encountered thus far and the solutions encountered in industry are addressed. Then, the use of polyesters as a promising alternative to current methods, such as phosphating, chromating, galvanization, and inhibitors, are highlighted. The classifications of polyesters and the network structure determine the overall applications and performance of the polymer. The review provides new trends in green chemistry and smart and bio-based polyester-based coatings. Finally, the different applications of polyesters are covered; specifically, the use of polyesters in surface coatings and for other industrial uses is discussed.

Fabrication and Model Characterization of the Electrical Conductivity of PVA/PPy/rGO Nanocomposite.

Owing to the numerous advantages of graphene-based polymer nanocomposite, this study is focused on the fabrication of the hybrid of polyvinyl alcohol (PVA), polypyrrole (PPy), and reduced graphene-oxide. The study primarily carried out the experimentation and the mathematical analysis of the electrical conductivity of PVA/PPy/rGO nanocomposite. The preparation method involves solvent/drying blending method. Scanning electron microscopy was used to observe the morphology of the nanocomposite. The electrical conductivity of the fabricated PVA/PPy/rGO nanocomposite was investigated by varying the content of PPy/rGO on PVA. From the result obtained, it was observed that at about 0.4 (wt%) of the filler content, the nanocomposite experienced continuous conduction. In addition, Ondracek, Dalmas s-shape, dose-response, and Gaussian fitting models were engaged for the analysis of the electrical transport property of the nanocomposite. The models were validated by comparing their predictions with the experimental measurements. The results obtained showed consistency with the experimental data. Moreover, this study confirmed that the electrical conductivity of polymer-composite largely depends on the weight fraction of fillers. By considering the flexibility, simplicity, and versatility of the studied models, this study suggests their deployment for the optimal characterization/simulation tools for the prediction of the electrical conductivity of polymer-composites.